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Gashydrate – Eine Einführung in Grundlagenforschung und Anwendung pp 119–137Cite as

Analysenmethoden zur Charakterisierung von Gashydraten

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Zusammenfassung

In Kap. 9 werden verschiedene Methoden zur Analyse und Charakterisierung von Gashydraten vorgestellt. Dazu gehört neben der Raman-Spektroskopie, der Röntgendiffraktometrie und Neutronendiffraktometrie auch die magnetische Kernresonanzspektroskopie, Elektronenmikroskopie und Differenzkalorimetrie. Es werden jeweils die allgemeinen Grundlagen erklärt und Beispiele für die Anwendungen in der Gashydratforschung gegeben.

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Literatur

  • Alavi S, Susilo R, Ripmeester JA (2009) Linking microscopic guest properties to macroscopic observable in clathrate hydrates: guest-host hydrogen bonding. The Journal of Chemical Physics 130:174501

    CrossRef  Google Scholar 

  • Banwell CN, McCash EM (1999) Molekülspektroskopie – Ein Grundkurs. Oldenbourg, München

    Google Scholar 

  • Brewer PG, Malby G, Pateris JD, White SN, Peltzer ET, Wopenka B, Freeman J, Brown MO (2004) Development of a laser Raman spectrometer for deep-ocean science. Deep-Sea Rese 51:739–753

    CrossRef  Google Scholar 

  • Celli M, Zoppi M, Zaghloul MAS, Ulivi L (2012) High pressure optical cell for synthesis and in situ Raman spectroscopy of hydrogen clathrate hydrates. Review of Scientific Instruments 83:113101

    CrossRef  Google Scholar 

  • Chou I-M, Sharma A, Burruss RC, Shu J, Mao H-K, Hemley RJ, Goncharov AF, Stern LA, Kirby SH (2000) Transformations in methane hydrates. Proceedings of the National Academy of Sciences 97(25):13484–13487

    CrossRef  Google Scholar 

  • Dalmazzone D, Clausse D, Dalmazzone C, Herzhaft B (2004) The stability of methane hydrates in highly concentrated electrolyte solutions by differential scanning calorimetry and theoretical computation. American Mineralogist 89:1183–1191

    CrossRef  Google Scholar 

  • Dec SF (2009) Clathrate hydrate formation: dependence on aqueous hydration number. Journal Phys Chemistry C 113:12355–11236

    CrossRef  Google Scholar 

  • Flegler SL, Heckman JW, Klomparens KL (1995) Elektronenmikroskopie. Spektrum Akademischer, Heidelberg

    Google Scholar 

  • Handa YP (1986) Compositions, enthalpies of dissociation, and heat capacities in the range 85 to 270 K for clathrate hydrates of methane, ethane, and propane, and enthalpy of dissociation of isobutane hydrate, as determined by a heat-flow calorimeter. Journal Chem Thermody 18:915–921

    CrossRef  Google Scholar 

  • Hester KC, Dunk RM, White SN, Brewer PG, Peltzer ET, Sloan ED (2007) Gas hydrate measurements at hydrate ridge using raman spectroscopy. Geochimica et Cosmochimica Acta 71:2947–2959

    CrossRef  Google Scholar 

  • Kleber W, Bautsch H-J, Bohm J, Klimm D (2010) Einführung in die Kristallographie, 19. Aufl. Oldenbourg, München

    CrossRef  Google Scholar 

  • Kuhs WF, Genov G, Goreshnik E, Zeller A, Techmer KS, Bohrmann G (2004) The impact of porous microstructures of gas hydrates on their macroscopic properties. International Journal of Offshore and Polar Engineering 14(4):305–309

    Google Scholar 

  • Kuhs WF, Hansen TC (2006) Time-resolved neutron diffraction studies with emphasis on water ices and gas hydrates. Reviews in Mineralogy & Geochemistry 63:171–204

    CrossRef  Google Scholar 

  • Lee L, Seo Y, Seo Y-T, Moudrakovski IL, Ripmeester JA (2003) Recovering methane from solid methane hydrate with carbon dioxide. Angewandte Chemie International Edition 42:5048–5051

    CrossRef  Google Scholar 

  • Luzi M (2006) Die Rolle molekülspezifischer Eigenschaften von Gasen bei deren Einbau in den Hydratkäfig. Diplomarbeit, Universität Potsdam

    Google Scholar 

  • Luzi M, Girod M, Naumann R, Schicks JM, Erzinger J (2010) A high-pressure cell for kinetic studies on gas hydrates by powder x-ray diffraction. Review of Scientific Instruments 81:125105

    CrossRef  Google Scholar 

  • Luzi M, Schicks JM, Naumann R, Erzinger J (2012) Systematic kinetic studies on mixed gas hydrates by Raman spectroscopy and powder X-ray diffraction. Journal Chem Thermody 48:28–35

    CrossRef  Google Scholar 

  • Moudrakovski IL, Sanchez AA, Ratcliffe CI, Ripmeester JA (2001) Nucleation and growth of hydrates on ice surfaces: new insights from 129Xe NMR experiments with hyperpolarized xenon. Journal Phys Chemistry B 105:12338–12347

    CrossRef  Google Scholar 

  • Ohno H, Strobel TA, Dec SF, Sloan ED, Koh CA (2009) Raman studies of methane-ethane hydrate metastability. Journal Phys Chemistry A 113:1711–1716

    CrossRef  Google Scholar 

  • Pimentel GC, Charles SW (1963) Infrared spectral pertubations in matrix experiments. Pure and Applied Chemistry 7:111–123

    CrossRef  Google Scholar 

  • Qin J, Kuhs WF (2013) Quantitative analysis of gas hydrates using raman spectroscopy. AIChE Journal 59(6):2155–2167

    CrossRef  Google Scholar 

  • Ripmeester JA, Ratcliffe CI (1988) Low-temperature cross-polarization/magic-angle spinning 13C NMR of solid state methane hydrates: structure, cage occupancy, and hydration number. Journal Phys Chemistry 92(2):337–339

    CrossRef  Google Scholar 

  • Ripmeester JA, Ratcliffe CI (1990) Xenon-129 NMR studies of clathrate hydrates: new guests for structure II and structure H. Journal Phys Chemistry 94(25):8773–8776

    CrossRef  Google Scholar 

  • Rydzy MB, Schicks JM, Naumann R, Erzinger J (2007) Dissociation enthalpies of synthesized multicomponent gas hydrates with respect to the guest composition and cage occupancy. Journal Phys Chemistry B 111:9539–9545

    CrossRef  Google Scholar 

  • Schicks J, Luzi M, Beeskow-Strauch B (2011) The conversion process of hydrocarbon hydrates into CO2 hydrates and vice versa: thermodynamic considerations. Journal Phys Chemistry A 115(46):13324–13331

    CrossRef  Google Scholar 

  • Schicks J, Pan M, Giese R, Poser M, Ismail NA, Luzi-Helbing M, Bleisteiner B, Lenz C (2020) A new high-pressure cell for systematic in situ investigations of micro-scale processes in gas hydrates using confocal micro-Raman spectroscopy. Review of Scientific Instruments 91(11):115103

    CrossRef  Google Scholar 

  • Schwedt G (2008) Analytische Chemie – Grundlagen, Methoden und Praxis, 2. Aufl. Wiley-VCH Verlag GmbH &Co, KGaA, Weinheim

    Google Scholar 

  • Spieß L, Teichert G, Schwarzer R, Behnken H, Genzel C (2009) Moderne Röntgenbeugung. Röntgendiffraktometrie für Materialwissenschaftler, Physiker und Chemiker, 2. Aufl. Vieweg und Teubner, Wiesbaden

    Google Scholar 

  • Staykova DK, Kuhs WF, Salamatin AN, Hansen T (2003) Formation of porous gas hydrates from ice powders: diffraction experiments and multistage model. Journal Phys Chemistry B 107:10299–10311

    CrossRef  Google Scholar 

  • Stern LA, Kirby SH, Durham WB (1996) Peculiarities of methane clathrate hydrate formation and solid state deformation, including possible superheating of water ice. Science 273:1843–1848

    CrossRef  Google Scholar 

  • Stern LA, Kirby SH, Circone S, Durham WB (2004) Scanning Electron Microscopy investigations of laboratory-grown gas clathrate hydrates formed from melting ice, and comparison to natural hydrates. American Mineralogist 89:1162–1175

    CrossRef  Google Scholar 

  • Subramanian S, Sloan ED (1999) Molecular measurements of methane hydrate formation. Fluid Phase Equilibria 158–160:813–820

    CrossRef  Google Scholar 

  • Subramanian S, Kini RA, Dec SF, Sloan ED (2000) Chemical Engineering Science 55:1981–1999

    CrossRef  Google Scholar 

  • Subramanian S, Sloan ED (2002) Trends in vibrational frequencies of guests trapped in clathrate hydrate cages. Journal Phys Chemistry B 106:4348–4355

    CrossRef  Google Scholar 

  • Yousuf M, Qadri SB, Knies DL, Grabowski KS, Coffin RB, Pohlman JW (2004) Novel results on structural investigations of natural minerals of clathrate hydrates. Applied Phys A 78:925–939

    CrossRef  Google Scholar 

  • Wang Z, He D, Zhang W, Li W, Li W, Qin J, Lei L, Zou Y, Yang X (2010) Portable high pressure sapphire anvil cell for gas hydrates research. Review of Scientific Instruments 81:085102

    CrossRef  Google Scholar 

  • Wedler G, Freund H-J (2012) Lehrbuch der Physikalischen Chemie, Sechste, vollständig überarbeitete und aktualisierte Auflage, Wiley-VCH, Weinheim

    Google Scholar 

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  1. GFZ Deutsches GeoForschungsZentrum, Helmholtz-Zentrum Potsdam, Potsdam, Deutschland

    Judith M. Schicks

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  1. Judith M. Schicks
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Correspondence to Judith M. Schicks .

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Schicks, J.M. (2021). Analysenmethoden zur Charakterisierung von Gashydraten. In: Gashydrate – Eine Einführung in Grundlagenforschung und Anwendung. Springer Spektrum, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-62778-5_9

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