Abstract
This chapter provides the Coriolis type coupling parameters of the (601), and dark (252) or ((530)) interacting states of 16O3 measured using continuous wave–cavity ring down spectroscopy.
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Natural isotopic abundance: 0.992728.
Reference | [2012Deb] |
Method | Continous wave – cavity ring down spectroscopy. |
Equations | Equations 10 and 23 in chapter “Introduction”. |
Statistical errors | One standard deviation in units of the least significant full size digits. |
Remarks | All values are given in cm−1. Calculated constants are purposely given with a supplementary digit, in index form, in order to reproduce the energy levels to experimental accuracy. The perturbing (252), (or (530)) vibrational state is supposed to be a dark state. Molecular constants determined in the same fit are given in chapter “16O3 Vibrational Energy and Rotational and Centrifugal Distortion Constants for the (601) State, and for the (252), (or (530)) Vibrational Dark States”. The isotopic composition of the elements used for the calculation of the natural isotopic abundance is taken from [2007Coh]. |
Abbreviation | SE: Statistical error. |
Coriolis type coupling parameter | ||
|---|---|---|
<601|H|dark 252 or 530> | ||
Value | SE | |
C 011 | −0.0085857 | 94 |
Symbols and abbreviations
Short form | Full form |
|---|---|
C y , C yz | Coriolis coupling parameter |
SE | Statistical error |
References
Cohen, E.R., Cvitaš, T., Frey, J.G., Holmström, B., Kuchitsu, K., Marquardt, R., Mills, I., Pavese, F., Quack, M., Stohner, J., Strauss, H.L., Takami, M., Thor, A.J.: Quantities, Units and Symbols in Physical Chemistry. The IUPAC Green Book, 3rd Ed., Cambridge: RSC Publishing, 2007.
De Backer, M.R., Barbe, A., Starikova, E., Tyuterev, V.G., Kassi, S., and Campargue, A.: Detection and analysis of four new bands in CRDS 16O3 spectra between 7300 and 7600 cm−1. J. Mol. Spectrosc. 272 (2012) 43−50.
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Guelachvili, G., Picqué, N. (2019). 16O3 Coriolis Type Coupling Parameters of the (601), and Dark (252) or ((530)) Interacting States. In: Guelachvili, G. (eds) Molecular Constants Mostly from Infrared Spectroscopy. Molecules and Radicals, vol 20C2. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-57960-2_84
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DOI: https://doi.org/10.1007/978-3-662-57960-2_84
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-662-57959-6
Online ISBN: 978-3-662-57960-2