Abstract
This chapter provides the Coriolis coupling constants for the (021) and (120) vibrational states of 16O3 measured using Fourier transform spectroscopy.
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Natural isotopic abundance: 0.992728.
Reference | [95Bar1] |
Method | Fourier transform spectroscopy. |
Equations | Equations 6 and 18 in chapter “Introduction”. |
Statistical errors | One standard deviation. |
Remarks | All values are given in cm−1. Calculated constants are purposely given with two supplementary digits in order to reproduce the energy levels to experimental accuracy. Molecular constants determined in the same fit are given in chapter “16O3 Vibrational Energy, Rotational and Centrifugal Distortion Constants for the (021) and (120) States”. Constant without SE, fixed in the fit has been proposed in chapter “16O3 Coriolis Coupling Constants for the (100) and (001) Vibrational States”. The isotopic composition of the elements used for the calculation of the natural isotopic abundance is taken from [2007Coh]. |
Abbreviation | SE: Statistical error. |
Coefficient | Coupling constant | SE | |
|---|---|---|---|
\( {h}_{\left(\mathrm{021,120}\right)}^C \) | −0.1007004 | 0.00061 | × 10−1 |
\( {h}_{\left(\mathrm{021,120}\right)}^{ \prime C} \) | −0.470 | ||
\( {h}_{\left(\mathrm{021,120}\right)}^{ \prime \prime C} \) | 0.12226 | 0.039 | × 10−5 |
\( {h}_{\left(\mathrm{021,120}\right)}^{ \prime \prime \prime C} \) | −0.8046 | 0.12 | × 10−7 |
Symbols and abbreviations
Short form | Full form |
|---|---|
\( {h}_{\left(021,120\right)}^C,{h}_{\left(021,120\right)}^{{ \prime }C},{h}_{\left(021,120\right)}^{{ \prime }{ \prime }C},{h}_{\left(021,120\right)}^{{ \prime }{ \prime }{ \prime }C} \) | Coriolis coupling constant for the (021) and (120) states |
SE | Statistical error |
References
Barbe, A., Sulakshina, O., Plateaux, J.J., Hamdouni, A., and Bouazza, S.: High-Resolution Infrared Spectra of Ozone in the 2300–2600 cm−1 Region. J. Mol. Spectrosc. 170 (1995) 244–250.
Cohen, E.R., Cvitaš, T., Frey, J.G., Holmström, B., Kuchitsu, K., Marquardt, R., Mills, I., Pavese, F., Quack, M., Stohner, J., Strauss, H.L., Takami, M., Thor, A.J.: Quantities, Units and Symbols in Physical Chemistry. The IUPAC Green Book, 3rd Ed., Cambridge: RSC Publishing, 2007.
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Guelachvili, G., Picqué, N. (2019). 16O3 Coriolis Coupling Constants for the (021) and (120) Vibrational States. In: Guelachvili, G. (eds) Molecular Constants Mostly from Infrared Spectroscopy. Molecules and Radicals, vol 20C2. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-57960-2_15
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DOI: https://doi.org/10.1007/978-3-662-57960-2_15
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-662-57959-6
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