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Diffusion coefficient of 2,2-dichloro-propane into 1,1,1-trichloro-ethane and 1,1,1-trichloro-ethane

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of 2,2-dichloro-propane into 1,1,1-trichloro-ethane and 1,1,1-trichloro-ethane at different concentrations measured using diaphragm cell.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.3. Diffusion in Ternary Mixtures

C3 H6 Cl2

(1)

2,2-dichloro-propane

594-20-7

C2 H3 Cl3

(2)

1,1,1-trichloro-ethane

71-55-6

C2 H3 Cl3

(3)

1,1,1-trichloro-ethane

71-55-6

Mutual Diffusion Coefficient Matrix: Dij (xi, xj); Method: DIA

Ref.: [1976M7]

T = 313.15 K; p = 101.325 kPa

x 1

x 2

D11 ⋅ 109 [m2/s]

D12 ⋅ 109 [m2/s]

D21 ⋅ 109 [m2/s]

D22 ⋅ 109 [m2/s]

0.101

0.152

1.75 ± 0.07

−0.06 ± 0.07

−0.01 ± 0.04

1.81 ± 0.04

0.2381

0.7002

1.75 ± 0.13

0.02 ± 0.25

−0.11 ± 0.09

1.88 ± 0.18

0.1915

0.4569

1.79 ± 0.05

−0.12 ± 0.09

−0.05 ± 0.08

1.74 ± 0.15

Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

x i

mole fraction

DIA

diaphragm cell

References

  1. [1976M7]
    Mortimer R. G., Hicks, B. C.: J. Phys. Chem. 80 (1976) 1376–1380.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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