Abstract
Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) is becoming a versatile and mature analytical technique for quantitative major, minor, and trace element analysis and isotope ratio determinations. A wide variety of solid and liquid samples can be analyzed. Besides the fast growing application of this method as an imaging technique, geology still is and has been the major driving force for the development of LA-ICP-MS. In this review, the method, instrumentation, fundamental observations and quantification procedures are explained. In addition, pros and cons of the technique are discussed and some trends and new sampling strategies, with special focus on archaeological applications, are summarized.
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References
Aeschliman DB, Bajic SJ, Baldwin DP, Houk RS (2003) High-speed digital photographic study of an inductively coupled plasma during laser ablation: comparison of dried solution aerosols from a microconcentric nebulizer and solid particles from laser ablation. J Anal Atom Spectrom 18:1008–1014
Arnold DE, Bohor BF, Neff H, Feinman GM, Williams PR, Dussubieux L, Bishop R (2012) The first direct evidence of pre-columbian sources of palygorskite for Maya Blue. J Archaeol Sci 39:2252–2260
Arrowsmith P (1987) Laser ablation of solids for elemental analysis by inductively coupled plasma mass spectrometry. Anal Chem 59:1437–1444
Arrowsmith P, Hughes SK (1988) Entrainment and transport of laser ablated plumes for subsequent elemental analysis. Appl Specstroc 42:1231–1239
Asogan D, Sharp BL, Connor CJPO, Green DA, Hutchinson RW (2009) An open, non-contact cell for laser ablation-inductively coupled plasma-mass spectrometry. J Anal Atom Spectrom 24:917–923
Barca D, de Francesco AM, Mirocle Crisci G (2007) Application of Laser Ablation ICP-MS for characterization of obsidian fragments from peri-Tyrrhenian area. J Cult Herit 8:141–150
Becker JS, Zoriy MV, Pickhardt C, Palomero-Gallagher N, Zilles K (2005) Imaging of copper, zinc, and other elements in thin section of human brain samples (hippocampus) by laser ablation inductively coupled plasma mass spectrometry. Anal Chem 77:3208–3216
Becker JS, Dietrich RC, Matusch A, Pozebon D, Dressler VL (2008) Quantitative images of metals in plant tissues measured by laser ablation inductively coupled plasma mass spectrometry. Spectrochim Acta B 63:1248–1252
Bi M, Ruiz AM, Gornushkin I, Smith BW, Winefordner JD (2000) Profiling of patterned metal layers by laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS). Appl Surf Sci 158:197–204
Bian QZ, Koch J, Lindner H, Berndt H, Hergenröder R, Niemax K (2005) Non-matrix matched calibration using near-IR femtosecond laser ablation inductively coupled plasma optical emission spectrometry. J Anal Atom Spectrom 20:736–740
Bian Q, Garcia CC, Koch J, Niemax K (2006) Non-matrix matched calibration of major and minor concentrations of Zn and Cu in brass, aluminium and silicate glass using NIR femtosecond laser ablation inductively coupled plasma mass spectrometry. J Anal Atom Spectrom 21:187–191
Birbaum K (2011) Capabilities and limitations of inductively coupled plasma mass spectrometry-analyses on engineered and laser-generated nanoparticles. Ph.D. Dissertation, ETH Zurich
Bleiner D, Altorfer H (2005) A novel gas inlet system for improved aerosol entrainment in laser ablation inductively coupled plasma mass spectrometry. J Anal Atom Spectrom 20:754–756
Bleiner D, Günther D (2001) Theoretical description and experimental observation of aerosol transport processes in laser ablation inductively coupled plasma mass spectrometry. J Anal Atom Spectrom 16:449–456
Borovinskaya O, Hattendorf B, Tanner M, Gschwind S, Günther D (2013) A prototype of a new inductively coupled plasma time-of-flight mass spectrometer providing temporally resolved, multi-element detection of short signals generated by single particles and droplets. J Anal Atom Spectrom 28:226–233
Campbell AJ, Humayun M (1999) Trace element microanalysis in iron meteorites by laser ablation ICPMS. Anal Chem 71:939–946
Carr JW, Horlick G (1982) Laser vaporization of solid metal samples into an inductively coupled plasma. Spectrochim Acta B 37:1–15
Chen Z (1999) Inter-element fractionation and correction in laser ablation inductively coupled plasma mass spectrometry. J Anal Atom Spectrom 14:1823–1828
Cottle JM, Horstwood MSA, Parrish RR (2009) A new approach to single shot laser ablation analysis and its application to in situ Pb/U geochronology. J Anal Atom Spectrom 24:1355–1363
Cromwell EF, Arrowsmith P (1996) Novel multichannel plasma-source mass spectrometer. J Am Soc Mass Spectrom 7:458–466
Devos W, Moor C, Lienemann P (1999) Determination of impurities in antique silver objects for authentication by laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS). J Anal Atom Spectrom 14:621–626
Dorta L, Kovacs R, Koch J, Nishiguchi K, Utani K, Günther D (2013) Determining isotope ratios using laser ablation sampling in air with MC-ICPMS. J Anal Atom Spectrom 28:1513–1521
Durrant SF (1999) Laser ablation inductively coupled plasma mass spectrometry: achievements, problems, prospects. J Anal Atom Spectrom 14:1385–1403
Dussubieux L, Golitko M, Williams PR, Speakman RJ (2007) LA-ICP-MS analysis applied to the characterization of Peruvian Wari ceramics. In: Glascock MD, Speakman RJ, Popelka-Filcoff RS (eds) Archaeological chemistry: analytical technique and archaeological interpretation. American Chemical Society, Washington, DC, pp 349–363
Dussubieux L, Deraisme A, Frot G, Stevenson C, Creech A, Bienvenu Y (2008) LA-ICP-MS, SEM-EDS and EPMA analysis of eastern north american copper-based artefacts: impact of corrosion and heterogeneity on the reliability of the LA-ICP-MS compositional results. Archaeometry 50:643–657
Eggins SM, Shelley JMG (2002) Compositional heterogeneity in NIST SRM 610-617 glasses. Geostandard Newslett 26:269–286
Eggins SM, Kinsley LPJ, Shelley JMG (1998) Deposition and element fractionation processes during atmospheric pressure laser sampling for analysis by ICP-MS. Appl Surf Sci 127–129:278–286
Feldmann J, Kindness A, Ek P (2002) Laser ablation of soft tissue using a cryogenically cooled ablation cell. J Anal Atom Spectrom 17:813–818
Felton JA, Schilling GD, Ray SJ, Sperline RP, Denton MB, Barinaga CJ, Koppenaal DW, Hieftje GM (2011) Evaluation of a fourth-generation focal plane camera for use in plasma-source mass spectrometry. J Anal Atom Spectrom 26:300–304
Figg DJ, Cross JB, Brink C (1998) More investigations into elemental fractionation resulting from laser ablation–inductively coupled plasma–mass spectrometry on glass samples. Appl Surf Sci 127–129:287–291
Fontaine G, Hametner K, Peretti A, Günther D (2010) Authenticity and provenance studies of copper-bearing andesines using Cu isotope ratios and element analysis by fs-LA-MC-ICPMS and ns-LA-ICPMS. Anal Bioanal Chem 398(7–8):2915–2928
Frick DA, Günther D (2012) Fundamental studies on the ablation behaviour of carbon in LA-ICPMS with respect to the suitability as internal standard. J Anal Atom Spectrom 27:1294–1303
Fricker MB (2012) Design of ablation cells for LA-ICPMS: from modeling to high spatial resolution analysis applications. Ph.D. Dissertation, ETH Zurich
Fryer BJ, Jackson SE, Longerich HP (1995) The design, operation and role of the laser-ablation microprobe coupled with an inductively coupled plasma; mass spectrometer (LAM-ICPMS) in the earth sciences. Can Mineral 33:303–312
Garcia CC, Lindner H, Niemax K (2007) Transport efficiency in femtosecond laser ablation inductively coupled plasma mass spectrometry applying ablation cells with short and long washout times. Spectrochim Acta B 62:13–19
Garcia CC, Wälle M, Lindner H, Koch J, Niemax K, Günther D (2008) Femtosecond laser ablation inductively coupled plasma mass spectrometry: transport efficiencies of aerosols released under argon atmosphere and the importance of the focus position. Spectrochim Acta B 63:271–276
Geertsen C, Briand A, Chartier F, Lacour J-L, Mauchien P, Sjöström S, Mermet J-M (1994) Comparison between infrared and ultraviolet laser ablation at atmospheric pressure—implications for solid sampling inductively coupled plasma spectrometry. J Anal Atom Spectrom 9:17–22
Glaus R, Kaegi R, Krumeich F, Günther D (2010) Phenomenological studies on structure and elemental composition of nanosecond and femtosecond laser-generated aerosols with implications on laser ablation inductively coupled plasma mass spectrometry. Spectrochim Acta B 65:812–822
Glaus R, Koch J, Günther D (2012) A portable laser ablation sampling device for elemental fingerprinting of objects outside the laboratory with laser ablation inductively coupled plasma mass spectrometry. Anal Chem 84:5358–5364
Glaus R, Dorta L, Zhang Z, Ma Q, Berke H, Günther D (2013) Isotope ratio determination of objects in the field by portable laser ablation sampling and subsequent multicollector ICPMS. J Anal Atom Spectrom 28:801–809
Gonzalez J, Oropeza DD, Mao X, Longerich HP, Russo RE (2012) Rapid bulk analysis using femtosecond laser ablation inductively coupled plasma Time-of-Flight mass spectrometry. J Anal Atom Spectrom 27:1405–1412
Gratuze B (1999) Obsidian characterization by laser ablation ICP-MS and its application to prehistoric trade in the Mediterranean and the Near East: sources and distribution of Obsidian within the Aegean and Anatolia. J Archaeol Sci 26:869–881
Gray AL (1985) Solid sample introduction by laser ablation for inductively coupled plasma source mass spectrometry. Analyst 110:551–556
Guilhaus M (2000) Essential elements of time-of-flight mass spectrometry in combination with the inductively coupled plasma ion source. Spectrochim Acta B 55:1511–1525
Guillong M, Günther D (2002) Effect of particle size distribution on ICP-induced elemental fractionation in laser ablation-inductively coupled plasma-mass spectrometry. J Anal Atom Spectrom 17:831–837
Guillong M, Heinrich CA (2007) Sensitivity enhancement in laser ablation ICP-MS using small amounts of hydrogen in the carrier gas. J Anal Atom Spectrom 22:1488–1494
Guillong M, Horn I, Günther D (2003) A comparison of 266 nm, 213 nm and 193 nm produced from a single solid state Nd:YAG laser for laser ablation ICP-MS. J Anal Atom Spectrom 18:1224–1230
Günther D, Gäckle M (1988) Laser-Mikro-ICP-Spektrometrie – Integrale Messungen an verschiedenen Matrizes. Z Chem 28:227–228
Günther D, Heinrich CA (1999) Enhanced sensitivity in laser ablation-ICP mass spectrometry using helium-argon mixtures as aerosol carrier. J Anal Atom Spectrom 14:1363–1368
Günther D, Frischknecht R, Heinrich CA, Kahlert HJ (1997) Capabilities of an argon fluoride 193 nm excimer laser for laser ablation inductively coupled plasma mass spectrometry microanalysis of geological materials. J Anal Atom Spectrom 12:939–944
Günther D, Audétat A, Frischknecht R, Heinrich CA (1998) Quantitative analysis of major, minor and trace elements in fluid inclusions using laser ablation–inductively coupled plasma mass spectrometry. J Anal Atom Spectrom 13:263–270
Günther D, Jackson SE, Longerich HP (1999) Laser ablation and arc/spark solid sample introduction into inductively coupled plasma mass spectrometers. Spectrochim Acta B 54:381–409
Gurevich EL, Hergenröder R (2007) A simple laser ICPMS ablation cell with wash-out time less than 100 ms. J Anal Atom Spectrom 22:1043–1050
Halliday AN, Lee D-C, Christensen JN, Rehkämper M, Yi W, Luo X, Hall CM, Ballentine CJ, Pettke T, Stirling C (1998) Applications of multiple collector-ICPMS to cosmochemistry, geochemistry, and paleoceanography. Geochim Cosmochim Acta 62:919–940
Hattendorf B, Günther D (2001) Experimental evidence for the formation of doubly charged polyatomic ions in inductively coupled plasma mass spectrometry. Fresenius J Anal Chem 370(5):483–487
Hattendorf B, Latkoczy C, Günther D (2003) Laser ablation-ICPMS. Anal Chem 75:341A–347A
Heinrich CA, Pettke T, Halter W, Aigner M, Audetat A, Günther D, Hattendorf B, Bleiner D, Guillong M, Horn I (2003) Quantitative multi-element analysis of minerals, fluid and melt inclusions by Laser Ablation Inductively Coupled Plasma Mass Spectrometry. Geochim Cosmochim Acta 67:3473–3497
Horn I, von Blanckenburg F, Schoenberg R, Steinhoefel G, Markl G (2006) In situ iron isotope ratio determination using UV-femtosecond laser ablation with application to hydrothermal ore formation processes. Geochim Cosmochim Acta 70:3677–3688
Horstwood MSA, Foster GL, Parrish RR, Noble SR, Nowell GM (2003) Common-Pb corrected in situ U–Pb accessory mineral geochronology by LA-MC-ICPMS. J Anal Atom Spectrom 18:837–846
Houk RS, Fassel VA, Flesch GD, Svec HJ, Gray AL, Taylor CE (1980) Inductively coupled argon plasma as an ion source for mass spectrometric determination of trace elements. Anal Chem 52:2283–2289
Ishizuka T, Uwamino Y (1983) Inductively coupled plasma emission spectrometry of solid samples by laser ablation. Spectrochim Acta B 38:519–527
Jackson SE, Günther D (2003) The nature and sources of laser induced isotopic fractionation in laser ablation-multicollector-inductively coupled plasma-mass spectrometry. J Anal Atom Spectrom 18:205–212
Jackson SE, Longerich HP, Dunning GR, Fryer BJ (1992) The application of laser-ablation microprobe; inductively coupled plasma-mass spectrometry (LAM-ICPMS) to in situ trace-element determinations in minerals. Can Mineral 30:1049–1064
Jeffries TE, Perkins WT, Pearce NJG (1995) Comparisons of infrared and ultraviolet laser probe microanalysis inductively coupled plasma mass spectrometry in mineral analysis. Analyst 120:1365–1371
Jeffries TE, Jackson SE, Longerich HP (1998) Application of a frequency quintupled Nd:YAG source (lambda = 213 nm) for laser ablation inductively coupled plasma mass spectrometric analysis of minerals. J Anal Atom Spectrom 13:935–940
Jenner GA, Longerich HP, Jackson SE, Fryer BJ (1990) ICPMS-A powerful tool for high-precision trace-element analysis in Earth sciences: evidence from analysis of selected U.S.G.S. reference samples. Chem Geol 83:133–148
Jochum KP, Weis U, Stoll B, Kuzmin D, Yang Q, Raczek I, Jacob DE, Stracke A, Birbaum K, Frick DA, Günther D, Enzweiler J (2011) Determination of reference values for NIST SRM 610-617 glasses following ISO guidelines. Geostand Geoanal Res 35:397–429
Koch J, Günther D (2011) Review of the state-of-the-art of laser ablation inductively coupled plasma mass spectrometry. Appl Spectrosc 65:155A–162A
Koch J, von Bohlen A, Hergenröder R, Niemax K (2004) Particle size distributions and compositions of aerosols produced by near-IR-femto- and nanosecond laser ablation of brass. J Anal Atom Spectrom 19:267–272
Koch J, Schlamp S, Rösgen T, Fliegel D, Günther D (2007) Visualization of aerosol particles generated by near infrared nano- and femtosecond laser ablation. Spectrochim Acta B 62:20–29
Koch J, Wälle M, Dietiker R, Günther D (2008a) Analysis of laser-produced aerosols by inductively coupled plasma mass spectrometry: transport phenomena and elemental fractionation. Anal Chem 80:915–921
Koch J, Wälle M, Schlamp S, Rösgen T, Günther D (2008b) Expansion phenomena of aerosols generated by laser ablation under helium and argon atmosphere. Spectrochim Acta B 63:37–41
Koch J, Heiroth S, Lippert T, Günther D (2010) Femtosecond laser ablation: visualization of the aerosol formation process by light scattering and shadow graphic imaging. Spectrochim Acta B 65:943–949
Košler J, Wiedenbeck M, Wirth R, Hovorka J, Sylvester P, Míková J (2005) Chemical and phase composition of particles produced by laser ablation of silicate glass and zircon—implications for elemental fractionation during ICPMS analysis. J Anal Atom Spectrom 20:402–409
Kovacs R, Günther D (2008) Influence of transport tube materials on signal response and drift in laser ablation-inductively coupled plasma-mass spectrometry. J Anal Atom Spectrom 23:1247–1252
Kovacs R, Nishiguchi K, Utani K, Günther D (2010) Development of direct atmospheric sampling for laser ablation-inductively coupled plasma-mass spectrometry. J Anal Atom Spectrom 25:142–147
Kroslakova I, Günther D (2007) Elemental fractionation in laser ablation-inductively coupled plasma-mass spectrometry: evidence for mass load induced matrix effects in the ICP during ablation of a silicate glass. J Anal Atom Spectrom 22:51–62
Kuhn H-R, Günther D (2003) Elemental fractionation studies in laser ablation inductively coupled plasma mass spectrometry on laser-induced brass aerosols. Anal Chem 75:747–753
Liu Y, Hu Z, Yuan H, Hu S, Cheng H (2007) Volume-optional and low-memory (VOLM) chamber for laser ablation-ICPMS: application to fiber analyses. J Anal Atom Spectrom 22:582–585
Longerich HP (2012) Inductively coupled plasma-mass spectrometry (ICPMS): a personal Odyssey III. J Anal Atom Spectrom 27:1181–1184
Longerich HP, Günther D, Jackson SE (1996a) Elemental fractionation in laser ablation inductively coupled plasma mass spectrometry. Anal Bioanal Chem 355:538–542
Longerich HP, Jackson SE, Günther D (1996b) Inter-laboratory note. Laser ablation inductively coupled plasma mass spectrometric transient signal data acquisition and analyte concentration calculation. J Anal Atom Spectrom 11:899–904
Mahoney PP, Li G, Hieftje GM (1996) Laser ablation inductively coupled plasma mass spectrometry with a time-of-flight mass analyser. J Anal Atom Spectrom 11:401–405
Mank AJG, Mason PRD (1999) A critical assessment of laser ablation ICPMS as an analytical tool for depth analysis in silica-based glass samples. J Anal Atom Spectrom 14:1143–1153
Margetic V, Pakulev A, Stockhaus A, Bolshov M, Niemax K, Hergenröder R (2000) A comparison of nanosecond and femtosecond laser-induced plasma spectroscopy of brass samples. Spectrochim Acta B 55:1771–1785
Mattauch J, Herzog R (1934) About a new mass spectrograph. Z Phys 89:786–795
Mattey D, Lowry D, Duffet J, Fisher R, Hodge E, Frisia S (2008) A 53 year seasonally resolved oxygen and carbon isotope record from a modern Gibraltar speleothem: Reconstructed drip water and relationship to local precipitation. Earth Planet Sci Lett 269:80–95
Monticelli D, Gurevich EL, Hergenroder R (2009) Design and performances of a cyclonic flux cell for laser ablation. J Anal Atom Spectrom 24:328–335
Mozna V, Pisonero J, Hola M, Kanicky V, Günther D (2006) Quantitative analysis of Fe-based samples using ultraviolet nanosecond and femtosecond laser ablation-ICP-MS. J Anal Atom Spectrom 21:1194–1201
Müller W, Shelley M, Miller P, Broude S (2009) Initial performance metrics of a new custom-designed ArF excimer LA-ICP-MS system coupled to a two-volume laser-ablation cell. J Anal Atom Spectrom 24:209–214
Müller W, Shelley JMG, Rasmussen SO (2011) Direct chemical analysis of frozen ice cores by UV-laser ablation ICPMS. J Anal Atom Spectrom 26:2391–2395
Myers DP, Hieftje GM (1993) Preliminary design considerations and characteristics of an inductively coupled plasma-time-of-flight mass spectrometer. Microchem J 48:259–277
Outridge PM, Doherty W, Gregoire DC (1996) The formation of trace element-enriched particulates during laser ablation of refractory materials. Spectrochim Acta B 51:1451–1462
Pettke T, Oberli F, Audétat A, Guillong M, Simon AC, Hanley JJ, Klemm LM (2012) Recent developments in element concentration and isotope ratio analysis of individual fluid inclusion by laser ablation single and multiple collector ICPMS. Ore Geol Rev 44:10–38
Pisonero J, Fliegel D, Gunther D (2006) High efficiency aerosol dispersion cell for laser ablation-ICPMS. J Anal Atom Spectrom 21:922–931
Pisonero J, Koch J, Wälle M, Hartung W, Spencer ND, Günther D (2007) Capabilities of femtosecond laser ablation inductively coupled plasma mass spectrometry for depth profiling of thin metal coatings. Anal Chem 79:2325–2333
Plotnikov A, Vogt C, Hoffmann V, Taschner C, Wetzig K (2001) Application of laser ablation inductively coupled plasma quadrupole mass spectrometry (LA-ICP-QMS) for depth profile analysis. J Anal Atom Spectrom 16:1290–1295
Plotnikov A, Vogt C, Wetzig K, Kyriakopoulos A (2008) A theoretical approach to the interpretation of the transient data in scanning laser ablation inductively coupled plasma mass spectrometry: consideration of the geometry of the scanning area. Spectrochim Acta B 63:474–483
Raab A, Ploselli B, Munro C, Thomas-Oates J, Feldmann J (2009) Evaluation of gel electrophoresis conditions for the separation of metal-tagged proteins with subsequent laser ablation ICP-MS detection. Electrophoresis 30:303–314
Reinhardt H, Kriews M, Miller H, Schrems O, Lüdke C, Hoffmann E, Skole J (2001) Laser ablation inductively coupled plasma mass spectrometry: a new tool for trace element analysis in ice cores. Fresen J Anal Chem 370:629–636
Reinhardt H, Kriews M, Miller H, Lüdke C, Hoffmann E, Skole J (2003) Application of LA-ICP-MS in polar ice core studies. Anal Bioanal Chem 375:1265–1275
Resano M, McIntosh KS, Vanhaecke F (2012) Laser ablation-inductively coupled plasma-mass spectrometry using a double-focusing sector field mass spectrometer of Mattauch–Herzog geometry and an array detector for the determination of platinum group metals and gold in NiS buttons obtained by fire assay of platiniferous ores. J Anal Atom Spectrom 27:165–173
Russo RE, Mao XL, Borisov OV, Liu H (2000) Influence of wavelength on fractionation in laser ablation ICP-MS. J Anal Atom Spectrom 15:1115–1120
Russo RE, Mao X, Gonzalez JJ, Mao SS (2002a) Femtosecond laser ablation ICP-MS. J Anal Atom Spectrom 7:1072–1075
Russo RE, Mao X, Liu H, Gonzalez J, Mao SS (2002b) Laser ablation in analytical chemistry-a review. Talanta 57:425–451
Schilling GD, Ray SJ, Rubinshtein AA, Felton JA, Sperline RP, Denton MB, Barinaga CJ, Koppenaal DW, Hieftje GM (2009) Evaluation of a 512-channel Faraday-strip array detector coupled to an inductively coupled plasma Mattauch−Herzog mass spectrograph. Anal Chem 81:5467–5473
Schrön W, Bombach G, Beuge P (1983) Schnellverfahren zur flammenlosen AAS-Bestimmung von Spurenelementen in geologischen Proben. Spectrochim Acta B 38:1269–1276
Shuttleworth S (1996) Optimisation of laser wavelength in the ablation sampling of glass materials. Appl Surf Sci 96–98:513–517
Sinclair DJ, Kinsley LPJ, McCulloch MT (1998) High resolution analysis of trace elements in corals by laser ablation ICP-MS. Geochim Cosmochim Acta 62:1889–1901
Tabersky D, Nishiguchi K, Utani K, Ohata M, Dietiker R, Fricker MB, de Maddalena IM, Koch J, Günther D (2013) Aerosol entrainment and a large-capacity gas exchange device (Q-GED) for laser ablation inductively coupled plasma mass spectrometry in atmospheric pressure air. J Anal Atom Spectrom 28:831–842
Tanner M (2007) Fundamental studies on fast signal generation without an aerosol transport system for Laser Ablation Inductively Coupled Plasma Mass Spectrometry, Ph.D. Dissertation, ETH Zurich
Tanner M, Günther D (2005) In torch laser ablation sampling for inductively coupled plasma mass spectrometry. J Anal Atom Spectrom 20:987–989
Tanner M, Günther D (2006) In torch laser ablation sampling for inductively coupled plasma time of flight mass spectrometry. J Anal Atom Spectrom 21:941–947
Thompson M, Goulter JE, Sieper F (1981) Laser ablation for the introduction of solid samples into an inductively coupled plasma for atomic-emission spectrometry. Analyst 106:32–39
Treble P, Shelley JMG, Chappell J (2003) Comparison of high resolution sub-annual records of trace elements in a modern (1911–1992) speleothem with instrumental climate data from southwest Australia. Earth Planet Sci Lett 216:141–153
Treble PC, Chappell J, Shelley JMG (2005) Complex speleothem growth processes revealed by trace element mapping and scanning electron microscopy of annual layers. Geochim Cosmochim Acta 69:4855–4863
Vaughn KJ, Dussubieux L, Williams RR (2011) A pilot compositional analysis of Nasca ceramics from the Kroeber collection. J Archaeol Sci 38:3560–3567
Wagner B, Jędral W (2011) Open ablation cell for LA-ICP-MS investigations of historic objects. J Anal Atom Spectrom 26:2058–2063
Wälle M, Koch J, Flamigni L, Heirot S, Lippert T, Hartung W, Günther D (2009) Detection efficiencies in nano- and femtosecond laser ablation inductively coupled plasma mass spectrometry. Spectrochim Acta B 64:109–112
Wang HAO, Grolimund D, Giesen C, Borca CN, Shaw-Stewart JRH, Bodenmiller B, Günther D (2013) Fast chemical imaging at high spatial resolution by laser ablation inductively coupled plasma mass spectrometry. Anal Chem 85:10107–10116
Wiltsche H, Günther D (2010) Capabilities of femtosecond laser ablation ICP-MS for the major, minor and trace element analysis of high alloyed steels and super alloys. Anal Bioanal Chem 399:2167–2174
Wirth J, Poletti S, Aeschlimann B, Yakandawala N, Drosse B, Osorio S, Tohge T, Fernie AR, Günther D, Gruissem W, Sautter C (2009) Rice endosperm iron biofortification by targeted and synergistic action of nicotianamine synthase and ferritin. Plant Biotechnol J 7:631–644
Woodhead JD, Hellstrom J, Hergt JM, Greig A, Maas R (2007) Isotopic and elemental imaging of geological materials by laser ablation inductively coupled plasma-mass spectrometry. Geostand Geoanalyt Res 31:331–343
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The authors would like to thank Henry Longerich for fruitful discussion and comments on this manuscript.
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Fricker, M.B., Günther, D. (2016). Instrumentation, Fundamentals, and Application of Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry. In: Dussubieux, L., Golitko, M., Gratuze, B. (eds) Recent Advances in Laser Ablation ICP-MS for Archaeology. Natural Science in Archaeology. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-49894-1_1
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