Porphyrins pp 491-492 | Cite as

Spectral data of nickel complex of porphyrin derivative C100H76N4NiO8

  • R. Gupta
Chapter
Part of the Molecules and Radicals book series (volume 32C2)

Abstract

This chapter contains a tabular compilation of nuclear magnetic resonance data and UV-visible spectral data of nickel complex of porphyrin derivative C100H76N4NiO8.

Spectral Studies

2.1 Spectral Data of Porphyrins: Tetraphenyl and Analogous Porphyrins

Structure formula

NMR

IR

UV-visible

Remarks

Ref.

Solvent

Peaks δ [ppm]/nJ [Hz]

Peaks

Wave number

\( \tilde{v} \)[cm−1]

Solvent

Peaks

λ [nm]/(ε [M−1 cm−1]/log ε)

  

CD2Cl2

1 H NMR

3.45 (s, 24H, OCH3),

6.2-6.4 (br, 16H, aryl-H2 and H6),

6.29 (d, 8H, aryl-H4),

6.61 (br, 16H, phenyl-Hmeta and aryl-H5),

6.72 (t, 4H, phenyl-Hpara),

7.04 (br, 8H, phenyl-Hortho)

 

CH2Cl2

448 (203000),

568 (16500),

612 (17800)

 

[03Med]

Symbols and abbreviations

Short Form

Full Form

NMR

nuclear magnetic resonance

IR

infrared

UV-Visible

ultraviolet–visible

δ

chemical shift

γ

absorption band

λ

wavelength

ε

molar absorptivity

References

  1. [03Med]
    Medforth, C.J., Haddad, R.E., Muzzi, C.M., Dooley, N.R., Jaquinod, L., Shyr, D.C., Nurco, D.J., Olmstead, M.M., Smith, K.M., Ma, J.-G., Shelnutt, J.A.: Inorg. Chem. 42, 2227–2241 (2003)CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2016

Authors and Affiliations

  • R. Gupta
    • 1
  1. 1.JaipurIndia

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