Abstract
In functionally graded materials (FGMs), the composition and/or microstructure gradually changes over the volume [3–5], resulting in corresponding changes in the properties of the materials. There are many areas of application for FGMs, and one of them is biomedical application. In this chapter, at first, the merits of the metallic biomaterials with graded composition and/or microstructure are described. Then, microstructures and mechanical properties of Ti/biodegradable-polymer FGMs for bone tissue by spark plasma sintering (SPS) method, continuous graded composition in Ti–ZrO2 bio-FGMs by mixed-powder pouring method, and Al-based FGMs containing TiO2 nanoparticles with antibacterial activity by a centrifugal mixed-powder method are introduced. Also, our experimental results of white ceramic coating on Ti–29Nb–13Ta–4.6Zr alloy for dental application and magnetic graded materials by inhomogeneous heat treatment of SUS304 stainless steel are given.
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References
Sadollah A, Bahreininejad A (2012) Optimum functionally gradient materials for dental implant using simulated annealing. In: Tsuzuki MSG (ed) Simulated annealing – single and multiple objective problems. InTech, New York, Croatia. doi:10.5772/45640
Watari F, Yokoyama A, Matsuo H, Miyao R, Uo M, Kawasaki T, Omori M, Hirai T (2001) Biocompatibility of functionally graded implants. In: Ichikawa K (ed) Functionally graded materials in the 21st century. Kluwer Academic Publishers, Boston, pp 187–190
Hirai T (1996) Functional gradient materials. In: Cahan RW, Hassen P, Kramer EJ (eds) Processing of ceramics, Part 2, Materials science and technology, vol 17B. VCH Publishers, Weinheim, pp 293–341
Suresh S, Mortensen A (1998) Fundamentals of functionally graded materials, processing and thermomechanical behaviour of graded metals and metal-ceramic composites. IOM Communications Ltd., London
Miyamoto Y, Kaysser WA, Rabin BH, Kawasaki A, Ford RG (eds) (1999) Functionally graded materials: design, processing and applications. Kluwer Academic Publishers, Boston
Wataria F, Yokoyama A, Omori M, Hirai T, Kondo H, Uo M, Kawasaki T (2004) Biocompatibility of materials and development to functionally graded implant for bio-medical application. Comput Sci Technol 64:893–908
Amada S (1995) Hierarchical functionally gradient structures of bamboo, barley, and corn. MRS Bull 20:35–36
Watanabe Y, Sato H (2011) Review fabrication of functionally graded materials under a centrifugal force. In: Cuppoletti J (ed) Nanocomposites with unique properties and applications in medicine and industry. InTech, New York, Croatia, pp 133–150
Sampath S, Herman H, Shimoda N, Saito T (1995) Thermal spray processing of FGMs. MRS Bull 20:27–31
Kondo H, Yokoyama A, Omori M, Ohkubo A, Hirai T, Watari F, Uo M, Kawasaki T (2004) Fabrication of titanium nitride/apatite functionally graded implants by spark plasma sintering. Mater Trans 45:3156–3162
Lim Y-M, Park Y-J, Yun Y-H, Hwang K-S (2002) Functionally graded Ti/HAP coatings on Ti–6Al–4 V obtained by chemical solution deposition. Ceram Int 28:37–41
Yin GF, Luo JM, Zheng CQ, Tong HH, Huo YF, Mu LL (1999) Preparation of DLC gradient biomaterials by means of plasma source ion implant-ion beam enhanced deposition. Thin Solid Films 345:67–70
Sato M, Tu R, Goto T, Ueda K, Narushima T (2009) Preparation of functionally graded Bio-ceramic film by MOCVD. Mater Sci Forum 631–632:193–198
Watanabe Y, Iwasa Y, Sato H, Teramoto A, Abe K, Miura-Fujiwara E (2011) Microstructures and mechanical properties of titanium / biodegradable-polymer FGMs for bone tissue fabricated by spark plasma sintering method. J Mater Process Technol 211:1919–1926
Reilly DT, Burstein AH (1975) The elastic and ultimate properties of compact bone tissue. J Biomech 8:393–396
Narushima T (2005) Titanium and its alloys as biomaterials. J Jpn Inst Light Met 55:561–565
Ueda M, Sasaki Y, Ikeda M, Ogawa M (2009) Chemical-hydrothermal synthesis of bioinert ZrO2-TiO2 film on Ti substrates. Mater Trans 50:2104–2107
Tsuji H, Tezuka Y, Saha SK, Suzuki M, Itsuno S (2005) Spherulite growth of L-lactide copolymers: effects of tacticity and comonomers. Polymer 46:4917–4927
Sato H, Umaoka S-i, Watanabe Y, Kim I-S, Kawahara M, Tokita M (2007) Biodegradable fiber reinforced Ti composite fabricated by spark plasma sintering method. Mater Sci Forum 539–543:3201–3206
Miura-Fujiwara E, Teramoto T, Sato H, Kobayashi E, Watanabe Y (2010) Fabrication of Ti-based biodegradable material composites prepared by spark plasma sintering method. Mater Sci Forum 654–656:2158–2161
Hasebe T, Kobayashi E, Tezuka H, Sato T (2013) Effects of sintering conditions on mechanical properties of biomedical porous Ti produced by spark plasma sintering. Jpn J Appl Phys 52:01AE03 (4 pages)
Wen CE, Mabuchi M, Yamada Y, Shimojima K, Chino Y, Asahina T (2001) Processing of biocompatible porous Ti and Mg. Scr Mater 45:1147–1153
Watanabe Y, Miura-Fujiwara E, Sato H (2010) Fabrication of functionally graded materials by centrifugal slurry-pouring method and centrifugal mixed-powder method. J Jpn Soc Powder Powder Metall 57:321–326
Kang CG, Rohatgi PK (1996) Transient thermal analysis of solidification in a centrifugal casting for composite materials containing particle segregation. Metall Mater Trans B 27:277–285
Watanabe Y, Yamanaka N, Fukui Y (1998) Control of composition gradient in a metal-ceramic functionally graded material manufactured by the centrifugal method. Compos Part A 29A:595–601
Piconi C, Maccauro G (1999) Review Zirconia as a ceramic biomaterial. Biogeosciences 20:1–25
Watanabe Y, Miura-Fujiwara E, Sato H (2011) Fabrication of functionally graded materials by combination of centrifugal force and sintering method. J Jpn Soc Powder Powder Metall 58:11–17
Jayachandran M, Tsukamoto H, Sato H, Watanabe Y (2013) Formation behavior of continuous graded composition in Ti-ZrO2 functionally graded material fabricated by mixed-powder pouring method. J Nanomater 2013:504631 (8 pages)
Miura E, Tabaru T, Liu J, Tanaka Y, Shiraishi T, Hisatsune K (2004) Effect of gold coating on interfacial reaction between dental porcelain and titanium. Mater Trans 45:3044–3049
Kuroda D, Niinomi M, Morinaga M, Kato Y, Yashiro T (1998) Design and mechanical properties of New β type titanium alloys for implant materials. Mater Sci Eng A243:244–249
Niinomi M, Hattori T, Morikawa K, Kasuga T, Suzuki A, Fukui H, Niwa S (2002) Development of low rigidity β-type titanium alloy for biomedical applications. Mater Trans 43:2970–2977
Miura-Fujiwara E, Yamada S, Obata A, Sato H, Watanabe Y, Kasuga T, Niinomi M (2012) Oxidation behavior and effect of layer thickness on whiteness and exfoliation behavior of Oxide Film Formed on Ti-Nb-Ta-Zr Alloy. In: Proceedings of the Ti-2011 conference, III, China National Convention Center, Beijing, China, pp 2116–2120
Miura-Fujiwara E, Mizushima K, Yamada S, Watanabe Y, Kasuga T, Niinomi M, Yamasaki T (2013) Aesthetic and mechanical properties of oxide coated Ti-Nb-Ta-Zr alloys as a dental material. In: Proceedings of the 8th pacific rim international conference on advanced materials and processing, TMS (The Minerals, Metals & Materials Society), Hilton Waikoloa Village, Waikoloa, HI, USA, pp 1543–1550
Obata A, Miura-Fujiwara E, Shimizu A, Maeda H, Nakai M, Watanabe Y, Niinomi M, Kasuga T (2013) White-ceramic conversion on Ti-29Nb-13Ta-4.6Zr surface for dental applications. Adv Mater Sci Eng 2013:501621 (9 pages)
Miura-Fujiwara E, Mizushima K, Watanabe Y, Kasuga T, Niinomi M (2014) Color tone and interfacial microstructure of white oxide layer on CP Ti and Ti-Nb-Ta-Zr alloys. Jpn J Appl Phys 53:11RD02
Hasegawa A, Motonomi A, Ikeda I, Kawaguchi S (2000) Color of natural tooth crown in Japanese people. Color Res Appl 25:43–48
Shiba W, Uno M, Ishigami H, Kurachi M (2009) Means for reproducing shade guide color with laboratory-cured prosthetic composite. J Gifu Dent Soc 35:149–159
Yuan W, Ji J, Fu J, Shen J (2008) A facile method to construct hybrid multilayered films as a strong and multifunctional antibacterial coating. J Biomed Mater Res Part B 85B:556–563
Tang W, Chen Z, Katoh S (2004) Preparation of a nanocrystalline TiO2 photocatalyst using a dry-process with acetylene black. Chem Lett 33:1200–1201
Watanabe Y, Inaguma Y, Sato H, Miura-Fujiwara E (2009) A novel fabrication method for functionally graded materials under centrifugal force: the centrifugal mixed-powder method. Materials 2:2510–2525
Uenishi K, Seki M, Takatsugu M, Kunimasa T, Kobayashi KF, Ikeda T, Tsuboi A (2002) Microstructure and tensile strength of stainless steel wires micro spot melted by YAG laser. Mater Trans 43:3083–3087
Mangonon PL, Thomas G (1970) Structure and properties of thermal-mechanically treated 304 stainless steel. Metall Trans 1:1587–1594
Watanabe Y, Nakamura Y, Fukui Y, Nakanishi K (1993) A magneticfunctionally graded material manufactured with deformationinduced martensitic transformation. J Mater Sci Lett 12:326–328
Watanabe Y, Kang SH, Chan JW, Morris JW Jr (1999) Fabrication of magnetically graded material by rolling deformation of wedge-shaped 304 stainless steel. Mater Trans JIM 40:961–966
Watanabe Y, Momose I (2004) Magnetically graded materials fabricated by inhomogeneous heat treatment of deformed stainless steel. Ironmak Steelmak 31:265–268
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Watanabe, Y., Sato, H., Miura-Fujiwara, E. (2015). Functionally Graded Metallic Biomaterials. In: Niinomi, M., Narushima, T., Nakai, M. (eds) Advances in Metallic Biomaterials. Springer Series in Biomaterials Science and Engineering, vol 4. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-46842-5_9
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DOI: https://doi.org/10.1007/978-3-662-46842-5_9
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