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Abstract

An overview is given for the factors governing electrochemical reactions and processes: thermodynamics, kinetics, mass transport, ionic and electronic resistance, the charged electrode interface/double layer and the experimentation required to decouple these competing factors. These parameters are discussed in terms of the 28 chapters in the Springer Handbook of Electrochemical Energy. Important electrochemical references and resources are provided.

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Abbreviations

DSA:

dimensionally stable anode

DSE:

dimensionally stable electrode

EIS:

electrochemical impedance spectroscopy

emf:

electromotive force

IS:

impedance spectroscopy

PEMFC:

proton-exchange membrane fuel cell

PEM:

proton-exchange membrane

PFSA:

perfluorosulfonic acid

RDE:

rotating-disk electrode

SEI:

secondary electrode interface

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Breitkopf, C., Swider-Lyons, K. (2017). Modern Electrochemistry. In: Breitkopf, C., Swider-Lyons, K. (eds) Springer Handbook of Electrochemical Energy. Springer Handbooks. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-46657-5_2

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  • DOI: https://doi.org/10.1007/978-3-662-46657-5_2

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