Abstract
Mercury is considered a dangerous heavy metal to both humans and the ecosystem because it is highly toxic to the central nervous system and it tends to bioaccumulate in the human body. Coal-fired power plants are one of the main sources of mercury emission to the environment. During combustion, the mercury in the coal is transformed into three species: particle-bound mercury, vapor-phase elemental mercury, and vapor-phase oxidized mercury. Particle-bound Hgp is easily removed by dust control equipment such as baghouse filters and electrostatic precipitators (ESPs). Vapor-phase oxidized mercury is water soluble which makes its removal in wet flue-gas desulfurization units (FGD) possible. Vapor-phase elemental mercury is extremely volatile and insoluble. Therefore, the conversion of mercury from one form to another is important for selecting the appropriate mercury removal technology.
Coal-fired power plants have been considered to be the primary anthropogenic source of mercury into the atmosphere. For example, these account for about one-third of all anthropogenic mercury emissions in the USA. In China, mercury emission from nonferrous metals smelting, coal combustion, and miscellaneous activities contributed about 45 %, 38 %, and 17 %, respectively. Mercury contamination is widespread in different ecological compartments such as atmosphere, soil, and water. Mercury is a global pollutant. The research on mercury in America and Europe has been widely conducted. Anthropogenic emissions of mercury still increase in Asia because of increased burning of coal and increasedindustrialization.
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References
Antonia Lopez-Anton M, Yuan Y, Ron P, Mercedes Maroto-Valer M (2010) Analysis of mercury species present during coal combustion by thermal desorption. Fuel 89:629–634
Wang Q, Shen W, Ma Z (2000) Estimation of mercury emission from coal combustion in China. Environ Sci Technol 34:2711–2713
Park KS, Seo YC, Lee SJ et al (2008) Emission and speciation of mercury from various combustion sources. Powder Technol 180:151–156
Chi Y, Yan N, Zan Q, Qiao S et al (2009) The performance of iodine on the removal of elemental mercury from the simulated coal-fired flue gas. J Hazard Mater 166:776–781
Kyung Bo Ko, Youngchul Byun, Moohyun Cho et al (2008) Influence of HCl on oxidation of gaseous elemental mercury by dielectric barrier discharge process. Chemosphere 71:1674–1682
Granite EJ, Pennline HW (2002) Photochemical removal of mercury from flue gas. Ind Eng Chem Res 41:5470–5476
Lee TG, Hedrick E, Biswas P (2002) Hg reaction in the presence of chlorine species, homogeneous gas phase and heterogeneous gas–solid phase. J Air Waste Manage 52:1316–1323
McLarnon CR, Granite EJ, Pennline HW (2005) The PCO process for photochemical removal of mercury from flue gas. Fuel Process Technol 87:85–89
Zhao Y, Mann MD, Pavlish JH, Mibeck BAF, Dunham GF, Olson ES (2006) Application of gold catalyst for mercury oxidation by chlorine. Environ Sci Technol 40:1603–1608
Galbreath KC, Zygarlicke CJ (1996) Mercury speciation in coal combustion and gasification flue gases. Environ Sci Technol 30:2421–2426
Brown TD, Smith DN, Hargis RN, O’Dowd J (1999) Mercury measurement and its control, what we know, have learned, and need to further investigate. J Air Waste Manage 49:628–640
Pai P, Niemi D, Powers B (2000) A North American inventory of anthropogenic mercury emissions. Fuel Process Technol 65:101–115
Wang Q, Shen W, Ma Z (1999) The estimation of mercury emission from coal combustion in China. China Environ Sci 19:318–321
Seigneur C, Vijayaraghavan K, Lohman K et al (2004) Modeling the atmospheric fate and transport of mercury over North America, power plant emission scenarios. Fuel Process Technol 85:441–450
Yan Cao, Chin-Min Cheng, Chien-Wei Chen et al (2008) Abatement of mercury emissions in the coal combustion process equipped with a Fabric Filter Baghouse. Fuel 87:3322–3330
Crocker CR, Benson SA, Laumb JD (2004) SCR catalyst blinding due to sodium and calcium sulfate formation. Prep Pap-Am Chem Soc Div Fuel Chem 49:169–172
NBSC (National Bureau of Statistics of China) (2002) China statistical yearbook. www.stats.gov.cn/yearbook2001/indexC.htm (in Chinese)
Rigby K, Johnson R, Neufort R, Gunther P, Hurns E, Klatt A et al (2000) SCR catalyst design issues and operation experience, coals with high arsenic concentrations and coals from power river basin. Presented at the international joint power generation conference, UPGC2000-15067, 23–26 July 2000
Senior CL, Linjewile T, Denison M, Swensen D, Shino D, Bockelie M et al. SCR deactivation mechanisms related to alkali and alkali earth elements. In: Conference on selective catalytic reduction (SCR) and selective non-catalytic reduction (SNCR) for NOx control, Pittsburgh, PA, 20–30 Oct 2003
Zhang L, Wong MH (2007) Environmental mercury contamination in China, sources and impacts. Environ Int 33:108–121
Li P, Feng XB, Qiu GL, Shang LH, Li ZG (2009) Mercury pollution in Asia, a review of the contaminated sites. J Hazard Mater 168:591–601
St. Louis VL, Rudd WM, Kelly CA, Hall BD, Rolfhus KR, Scott KJ, Lindberg SE, Don W (2001) Importance of the forest canopy to fluxes of methyl mercury and total mercury to a boreal ecosystem. Environ Sci Technol 35:3089–3098
Guor-Cheng Fang, Yuh-ShenWu, Tai-Hua Chang (2009) Comparison of atmospheric mercury (Hg) among Korea, Japan, China and Taiwan during 2000–2008. J Hazard Mater 162:607–615
Anna G, Pacyna JM (2009) Mercury emission from coal-fired power plants in Poland. Atmos Environ 43:5668–5673
Pacyna EG, Pacyna JM, Steenhuisen F (2006) Global anthropogenic mercury emission inventory for 2000. Atmos Environ 40:4048–4063
Pacyna EG, Pacyna JM (2002) Global emission of mercury from anthropogenic sources in 1995. Water Air Soil Pollut 137(1–4):149–65
Shia R-L, Seigneur C, Pai P, Ko M, Sze ND (1999) Global simulation of atmospheric mercury concentrations and deposition fluxes. J Geophys Res 104:23747–23760
Pacyna EG, Pacyna JM, Steenhuisen F, Wilson S (2006) Global anthropogenic mercury emission inventory for 2000. Atmos Environ 40:4048–4063
DME (Department of Minerals and Energy) (2005) Digest of South African Energy Statistics. Department of Minerals and Energy, Pretoria
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Wu, J., Cao, Y., Pan, W., Pan, W. (2015). The Status of Mercury Emission from Coal Combustion Power Station. In: Coal Fired Flue Gas Mercury Emission Controls. Energy and Environment Research in China. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-46347-5_2
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