Abstract
Besides various bio-applications such as biomedicine, bioassay, photon dynamic treatment, and drug delivery, UCNPs have also been used in other applications. They can be explored as a NIR absorber in solar cells because they can absorb NIR light which has been wasted in traditional solar cells. They can be used as sensitizer in photocatalysis due to the energy transfer from UCNPs to the quantum dots or organic dyes. They are considered as next generation anti-counterfeiting materials due to their unique optical properties. In this chapter, the recent progress on other applications (besides bio-application) based on UCNPs is reviewed.
Rui Wang and Fan Zhang contributed together to this chapter.
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Mader, H.S., Kele, P., Saleh, S.M., Wolfbeis, O.S.: Upconverting luminescent nanoparticles for use in bioconjugation and bioimaging. Curr. Opin. Chem. Biol. 14, 582–596 (2010)
Haase, M., Schafer, H.: Upconverting nanoparticles. Angew. Chem. Int. Ed. 50, 5808–5829 (2011)
Wang, F., Liu, X.G.: Recent advances in the chemistry of lanthanide-doped upconversion nanocrystals. Chem. Soc. Rev. 38, 976–989 (2009)
Halme, J., Vahermaa, P., Miettunen, K., Lund, P.: Device physics of dye solar cells. Adv. Mater. 22, E210–E234 (2010)
Hagfeldt, A., Boschloo, G., Sun, L.C., Kloo, L., Pettersson, H.: Dye-sensitized solar cells. Chem. Rev. 110, 6595–6663 (2010)
Hoppe, H., Sariciftci, N.S.: Organic solar cells: an overview. J. Mater. Res. 19, 1924–1945 (2004)
Kamat, P.V.: Quantum dot solar cells. Semiconductor nanocrystals as light harvesters. J. Phys. Chem. Cells 112, 18737–18753 (2008)
Goetzberger, A., Luther, J., Willeke, G.: Solar cells: past, present, future. Sol. Energ. Mater. Sol. Cells 74, 1–11 (2002)
Chapin, D.M., Fuller, C.S., Pearson, G.L.: A new silicon p-n junction photocell for converting solar radiation into electrical power. J. Appl. Phys. 25, 676–677 (1954)
Goetzberger, A., Hebling, C., Schock, H.W.: Photovoltaic materials, history, status and outlook. Mater. Sci. Eng. R 40, 1–46 (2003)
Wang, H.Q., Batentschuk, M., Osvet, A., Pinna, L., Brabec, C.J.: Rare-earth ion doped up-conversion materials for photovoltaic applications. Adv. Mater. 23, 2675–2680 (2011)
Li, X.M., Zhang, F., Zhao, D.Y.: Highly efficient lanthanide upconverting nanomaterials: progresses and challenges. Nano Today 8, 643–676 (2013)
Richards, B.S.: Luminescent layers for enhanced silicon solar cell performance: down-conversion. Sol. Energy Mater. Sol. Cells 90, 1189–1207 (2006)
Trupke, T., Green, M.A., Wurfel, P.: Improving solar cell efficiencies by down-conversion of high-energy photons. J. Appl. Phys. 92, 1668–1674 (2002)
Klampaftis, E., Ross, D., McIntosh, K.R., Richards, B.S.: Enhancing the performance of solar cells via luminescent down-shifting of the incident spectrum: a review. Sol. Energy Mater. Sol. Cells 93, 1182–1194 (2009)
Wegh, R.T., Donker, H., Oskam, K.D., Meijerink, A.: Visible quantum cutting in LiGdF4: Eu3+ through downconversion. Science 283, 663–666 (1999)
Struempel, C., McCann, M., Beaucarne, G., Arkhipov, V., Slaoui, A., Svrcek, V., del Canizo, C., Tobias, I.: Modifying the solar spectrum to enhance silicon solar cell efficiency–an overview of available materials. Sol. Energy Mater. Sol. Cells 91, 238–249 (2007)
Shalav, A., Richards, B.S., Green, M.A.: Luminescent layers for enhanced silicon solar cell performance: up-conversion. Sol. Energy Mater. Sol. Cells 91, 829–842 (2007)
Imenes, A.G., Mills, D.R.: Spectral beam splitting technology for increased conversion efficiency in solar concentrating systems: a review. Sol. Energy Mater. Sol. Cells 84, 19–69 (2004)
Wolf, M.: Limitations and possibilities for improvement of photovoltaic solar energy converters .1. considerations for earths surface operation. Proceedings of the Institute of Radio Engineers 48, 1246–1263 (1960)
Barnham, K.W.J., Duggan, G.: A new approach to high-efficiency multi-band-gap solar-cells. J. Appl. Phys. 67, 3490–3493 (1990)
Keevers, M.J., Green, M.A.: Efficiency improvements of silicon solar-cells by the impurity photovoltaic effect. J. Appl. Phys. 75, 4022–4031 (1994)
Shan, G.B., Demopoulos, G.P.: Near-infrared sunlight harvesting in dye-sensitized solar cells via the insertion of an upconverter-TiO2 nanocomposite layer. Adv. Mater. 22, 4373–4377 (2010)
Su, L.T., Karuturi, S.K., Luo, J.S., Liu, L.J., Liu, X.F., Guo, J., Sum, T.C., Deng, R.R., Fan, H.J., Liu, X.G., Tok, A.I.Y.: Photon upconversion in hetero-nanostructured photoanodes for enhanced near-infrared light harvesting. Adv. Mater. 25, 1603–1607 (2013)
Gibart, P., Auzel, F., Guillaume, J.C., Zahraman, K.: Below band-gap IR response of substrate-free GaAs solar cells using two-photon up-conversion. Jpn. J Appl. Phys. Part 1-Regul. Pap. Short Notes Rev. Pap. 35, 4401–4402 (1996)
Richards, B.S., Shalav, A.: Enhancing the near-infrared spectral response of silicon optoelectronic devices via up-conversion. IEEE. T. Electron Dev. 54, 2679–2684 (2007)
Shalav, A., Richards, B.S., Trupke, T., Kramer, K.W., Gudel, H.U.: Application of NaYF4: Er3+ up-converting phosphors for enhanced near-infrared silicon solar cell response. Appl. Phys. Lett. 86, 013505 (2005)
Chen, D.Q., Lei, L., Yang, A.P., Wang, Z.X., Wang, Y.S.: Ultra-broadband near-infrared excitable upconversion core/shell nanocrystals. Chem. Commun. 48, 5898–5900 (2012)
Li, Z.Q., Li, X.D., Liu, Q.Q., Chen, X.H., Sun, Z., Liu, C., Ye, X.J., Huang, S.M.: Core/shell structured NaYF4:Yb3+/Er3+/Gd+3 nanorods with Au nanoparticles or shells for flexible amorphous silicon solar cells. Nanotechnology 23, 025402 (2012)
Trupke, T., Shalav, A., Richards, B.S., Wurfel, P., Green, M.A.: Efficiency enhancement of solar cells by luminescent up-conversion of sunlight. Sol. Energy Mater. Sol. Cells 90, 3327–3338 (2006)
de Wild, J., Rath, J.K., Meijerink, A., van Sark, W., Schropp, R.E.I.: Enhanced near-infrared response of a-Si:H solar cells with beta-NaYF4:Yb3+(18 %), Er3+(2 %) upconversion phosphors. Sol. Energy Mater. Sol. Cells 94, 2395–2398 (2010)
de Wild, J., Meijerink, A., Rath, J.K., van Sark, W., Schropp, R.E.I.: Towards upconversion for amorphous silicon solar cells. Sol. Energy Mater. Sol. Cells 94, 1919–1922 (2010)
Li, Y., Wang, G.F., Pan, K., Jiang, B.J., Tian, C.G., Zhou, W., Fu, H.G.: NaYF4:Er3+/Yb3+-graphene composites: preparation, upconversion luminescence, and application in dye-sensitized solar cells. J. Mater. Chem. 22, 20381–20386 (2012)
Fujishima, A., Honda, K.: Electrochemical photolysis of water at a semiconductor electrode. Nature 238, 37–38 (1972)
Augustynski, J.: The role of the surface intermediates in the photoelectrochemical behavior of anatase and rutile TiO2. Electrochim. Acta 38, 43–46 (1993)
Fang, W.Q., Gong, X.-Q., Yang, H.G.: On the unusual properties of anatase TiO2 exposed by highly reactive facets. J. Phys. Chem. L. 2, 725–734 (2011)
Bickley, R.I., Gonzalezcarreno, T., Lees, J.S., Palmisano, L., Tilley, R.J.D.: A structural investigation of titanium-dioxide photocatalysts. J. Solid State Chem. 92, 178–190 (1991)
Reeves, P., Ohlhausen, R., Sloan, D., Pamplin, K., Scoggins, T., Clark, C., Hutchinson, B., Green, D.: Photocatalytic destruction of organic-dyes in aqueous TiO2 suspensions using concentrated simulated and natural solar-energy. Sol. Energy 48, 413–420 (1992)
Bacsa, R.R., Kiwi, J.: Effect of rutile phase on the photocatalytic properties of nanocrystalline titania during the degradation of p-coumaric acid. Appl. Catal. B-environ 16, 19–29 (1998)
Yamazaki, S., Matsunaga, S., Hori, K.: Photocatalytic degradation of trichloroethylene in water using TiO(2) pellets. Water Res. 35, 1022–1028 (2001)
Chen, H.H., Nanayakkara, C.E., Grassian, V.H.: Titanium dioxide photocatalysis in atmospheric chemistry. Chem. Rev. 112, 5919–5948 (2012)
Linsebigler, A.L., Lu, G.Q., Yates, J.T.: Photocatalysis on TiO2 surfaces—principles, mechanisms and selected results. Chem. Rev. 95, 735–758 (1995)
Shiraiwa, M., Sosedova, Y., Rouviere, A., Yang, H., Zhang, Y.Y., Abbatt, J.P.D., Ammann, M., Poschl, U.: The role of long-lived reactive oxygen intermediates in the reaction of ozone with aerosol particles. Nat. Chem. 3, 291–295 (2011)
Fujishima, A., Zhang, X.T., Tryk, D.A.: TiO2 photocatalysis and related surface phenomena. Surf. Sci. Rep. 63, 515–582 (2008)
Hoffmann, M.R., Martin, S.T., Choi, W.Y., Bahnemann, D.W.: Environmental applications of semiconductor photocatalysis. Chem. Rev. 95, 69–96 (1995)
Chen, X., Mao, S.S.: Titanium dioxide nanomaterials: synthesis, properties, modifications, and applications. Chem. Rev. 107, 2891–2959 (2007)
Mills, A., LeHunte, S.: An overview of semiconductor photocatalysis. J. Photochem. Photobiol., A 108, 1–35 (1997)
Li, W., Wang, Y., Lin, H., Shah, S.I., Huang, C.P., Doren, D.J., Rykov, S.A., Chen, J.G., Barteau, M.A.: Band gap tailoring of Nd3+-doped TiO2 nanoparticles. Appl. Phys. Lett. 83, 4143–4145 (2003)
Morikawa, T., Asahi, R., Ohwaki, T., Aoki, K., Taga, Y.: Band-gap narrowing of titanium dioxide by nitrogen doping. Jpn. J Appl. Phys. Part 2-Lett. 40, L561–L563 (2001)
Nakano, Y., Morikawa, T., Ohwaki, T., Taga, Y.: Deep-level optical spectroscopy investigation of N-doped TiO2 films. Appl. Phys. Lett. 86, 132104 (2005)
Vogel, R., Hoyer, P., Weller, H.: Quantum-sized PBS, CDS, AG2S, SB2S3, and BI2S3 particles as sensitizers for various nanoporous wide-bandgap semiconductors. J. Phys. Chem. 98, 3183–3188 (1994)
Fitzmaurice, D., Frei, H., Rabani, J.: Time-resolved optical study on the charge-carrier dynamics in a TiO2/AGI sandwich colloid. J. Phys. Chem. 99, 9176–9181 (1995)
Zhang, Z.J., Wang, W.Z., Yin, W.Z., Shang, M., Wang, L., Sun, S.M.: Inducing photocatalysis by visible light beyond the absorption edge: effect of upconversion agent on the photocatalytic activity of Bi2WO6. Appl. Catal. B-environ 101, 68–73 (2010)
Qin, W.P., Zhang, D.S., Zhao, D., Wang, L.L., Zheng, K.Z.: Near-infrared photocatalysis based on YF3:Yb3+, Tm3+/TiO2 core/shell nanoparticles. Chem. Commun. 46, 2304–2306 (2010)
Shi, J.W., Ye, J.H., Ma, L.J., Ouyang, S.X., Jing, D.W., Guo, L.J.: Site-selected doping of upconversion luminescent Er3+ into SrTiO3 for visible-light-driven photocatalytic H–2 or O–2 evolution. Chem. Eur. J. 18, 7543–7551 (2012)
Ren, L., Qi, X., Liu, Y.D., Huang, Z.Y., Wei, X.L., Li, J., Yang, L.W., Zhong, J.X.: Upconversion-P25-graphene composite as an advanced sunlight driven photocatalytic hybrid material. J. Mater. Chem. 22, 11765–11771 (2012)
Obregon, S., Colon, G.: Evidence of upconversion luminescence contribution to the improved photoactivity of erbium doped TiO2 systems. Chem. Commun. 48, 7865–7867 (2012)
Li, Z.X., Shi, F.B., Zhang, T., Wu, H.S., Sun, L.D., Yan, C.H.: Ytterbium stabilized ordered mesoporous titania for near-infrared photocatalysis. Chem. Commun. 47, 8109–8111 (2011)
Feng, G.F., Liu, S.W., Xiu, Z.L., Zhang, Y., Yu, J.X., Chen, Y.G., Wang, P., Yu, X.J.: Visible light photocatalytic activities of TiO2 nanocrystals doped with upconversion luminescence agent. J. Phys. Chem. C 112, 13692–13699 (2008)
Li, C.H., Wang, F., Zhu, J.A., Yu, J.C.: NaYF4 Yb, Tm/CdS composite as a novel near-infrared-driven photocatalyst. Appl. Catal. B-environ 100, 433–439 (2010)
Suyver, J.F., Aebischer, A., Biner, D., Gerner, P., Grimm, J., Heer, S., Kramer, K.W., Reinhard, C., Gudel, H.U.: Novel materials doped with trivalent lanthanides and transition metal ions showing near-infrared to visible photon upconversion. Opt. Mater. 27, 1111–1130 (2005)
Meruga, J.M., Baride, A., Cross, W., Kellar, J.J., May, P.S.: Red-green-blue printing using luminescence-upconversion inks. J Mater. Chem. C 2, 2221–2227 (2014)
Kim, W.J., Nyk, M., Prasad, P.N.: Color-coded multilayer photopatterned microstructures using lanthanide (III) ion co-doped NaYF4 nanoparticles with upconversion luminescence for possible applications in security. Nanotechnology 20, 185301 (2009)
Blumenthal, T., Meruga, J., May, P.S., Kellar, J., Cross, W., Ankireddy, K., Vunnam, S., Luu, Q.N.: Patterned direct-write and screen-printing of NIR-to-visible upconverting inks for security applications. Nanotechnology 23, 185305 (2012)
Meruga, J.M., Cross, W.M., May, P.S., Luu, Q., Crawford, G.A., Kellar, J.J.: Security printing of covert quick response codes using upconverting nanoparticle inks. Nanotechnology 23, 395201 (2012)
Sangeetha, N.M., Moutet, P., Lagarde, D., Sallen, G., Urbaszek, B., Marie, X., Viau, G., Ressier, L.: 3D assembly of upconverting NaYF4 nanocrystals by AFM nanoxerography: creation of anti-counterfeiting microtags. Nanoscale 5, 9587–9592 (2013)
Zhang, Y.H., Zhang, L.X., Deng, R.R., Tian, J., Zong, Y., Jin, D.Y., Liu, X.G.: Multicolor Barcoding in a single upconversion crystal. J. Am. Chem. Soc. 136, 4893–4896 (2014)
Liu, F., Ma, E., Chen, D.Q., Yu, Y.L., Wang, Y.S.: Tunable red-green upconversion luminescence in novel transparent glass ceramics containing Er: NaYF4 nanocrystals. J. Phys. Chem. B 110, 20843–20846 (2006)
Chen, D.Q., Wang, Y.S., Zheng, K.L., Guo, T.L., Yu, Y.L., Huang, P.: Bright upconversion white light emission in transparent glass ceramic embedding Tm(3+)/Er(3+)/Yb(3+):beta-YF(3) nanocrystals. Appl. Phys. Lett. 91, 251903 (2007)
Chen, D.Q., Yu, Y.L., Huang, P., Weng, F.Y., Lin, H., Wang, Y.S.: Optical spectroscopy of Eu3+ and Tb3+ doped glass ceramics containing LiYbF4 nanocrystals. Appl. Phys. Lett. 94, 041909 (2009)
Chen, D.Q., Yu, Y.L., Wang, Y.S., Huang, P., Weng, F.Y.: Cooperative energy transfer up-conversion and quantum cutting down-conversion in Yb3+:TbF3 nanocrystals embedded glass ceramics. J. Phys. Chem. C 113, 6406–6410 (2009)
Chen, D.Q., Yu, Y.L., Huang, P., Wang, Y.S.: Nanocrystallization of lanthanide trifluoride in an aluminosilicate glass matrix: dimorphism and rare earth partition. CrystEngComm 11, 1686–1690 (2009)
Chen, D.Q., Yu, Y.L., Huang, P., Lin, H., Shan, Z.F., Wang, Y.S.: Color-tunable luminescence of Eu3+ in LaF3 embedded nanocomposite for light emitting diode. Acta Mater. 58, 3035–3041 (2010)
Sivakumar, R., van Veggel, F., Raudsepp, M.: Bright white light through up-conversion of a single NIR source from sol-gel-derived thin film made with Ln(3+)-doped LaF3 nanoparticles. J. Am. Chem. Soc. 127, 12464–12465 (2005)
Sudarsan, V., Sivakumar, S., van Veggel, F., Raudsepp, M.: General and convenient method for making highly luminescent sol-gel derived silica and alumina films by using LaF3 nanoparticles doped with lanthanide ions (Er3+, Nd3+, and Ho3+). Chem. Mater. 17, 4736–4742 (2005)
Sivakumar, S., Boyer, J.C., Bovero, E., van Veggel, F.: Up-conversion of 980 nm light into white light from sol-gel derived thin film made with new combinations of LaF3:Ln(3+) nanoparticles. J. Mater. Chem. 19, 2392–2399 (2009)
Zhang, C., Zhou, H.P., Liao, L.Y., Feng, W., Sun, W., Li, Z.X., Xu, C.H., Fang, C.J., Sun, L.D., Zhang, Y.W., Yan, C.H.: Luminescence modulation of ordered upconversion nanopatterns by a photochromic diarylethene: rewritable optical storage with nondestructive readout. Adv. Mater. 22, 633–637 (2010)
Lin, C.K., Berry, M.T., Anderson, R., Smith, S., May, P.S.: Highly luminescent NIR-to-visible upconversion thin films and monoliths requiring no high-temperature treatment. Chem. Mater. 21, 3406–3413 (2009)
Boyer, J.C., Johnson, N.J.J., van Veggel, F.: Upconverting lanthanide-doped NaYF4-PMMA polymer composites prepared by in situ polymerization. Chem. Mater. 21, 2010–2012 (2009)
Chai, R.T., Lian, H.Z., Hou, Z.Y., Zhang, C.M., Peng, C., Lin, J.: Preparation and characterization of upconversion luminescent NaYF4:Yb3+, Er3+(Tm3+)/PMMA bulk transparent nanocomposites through in situ photopolymerization. J. Phys. Chem. C 114, 610–616 (2010)
Downing, E., Hesselink, L., Ralston, J., Macfarlane, R.: A three-color, solid-state, three-dimensional display. Science 273, 1185–1189 (1996)
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Zhang, F. (2015). Upconversion Nanoparticles for Other Applications. In: Photon Upconversion Nanomaterials. Nanostructure Science and Technology. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-45597-5_11
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