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Increase of Platinum Group Element Concentrations in Soils and Airborne Dust During the Period of Vehicular Exhaust Catalysts Introduction

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Platinum Metals in the Environment

Part of the book series: Environmental Science and Engineering ((ENVSCIENCE))

Abstract

In Europe, new cars had to be fitted with catalytic converters since 1993. Besides the desired air quality improvement, an accumulation of the catalytic active noble metals Pt, Pd, and Rh in the environment could soon be observed. This work aimed at a monitoring of platinum group element (PGE) emission and accumulation by comparing analytical data, all generated in 1999 and in 2005 and thus covering an important time span of vehicular exhaust catalysts introduction in Germany. A comparison of analytical results of 2005 with those of 1999 revealed a distinct increase of PGE concentrations in soils closely along heavy traffic roads mainly by a factor of 2–9 in the considered urban area located in northern Germany. At a crowded road in Braunschweig city with stop and go traffic, the highest soil concentrations were determined, namely 261 µg/kg for Pt, 124 µg/kg for Pd and 38.9 µg/kg for Rh. The investigations also revealed that especially Pt and Rh concentrations were comparably elevated in airborne dust in 2005. A sampling at the already mentioned roadside revealed airborne dust concentrations of 1,730 µg/kg for Pt, 410 µg/kg for Pd, and 110 µg/kg for Rh.

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References

  • Fritsche J, Meisel T (2004) Determination of anthropogenic input of Ru, Rh, Pd, Re, Os, Ir, and Pt in soil along Austrian motorways by isotope dilution ICP-MS. Sci Total Environ 325:145–154

    Article  Google Scholar 

  • Govindaraju K (1994) Compilation of working values and sample description for 383 geostandards. Geostan Newsl 18:1–158

    Article  Google Scholar 

  • Moldovan M (2007) Origin and fate of platinum group elements in the environment. Anal Bioanal Chem 388:537–540

    Article  Google Scholar 

  • Morcelli CPR, Figueiredo AMG, Sarkis JES, Enzweiler J, Kakazu M, Sigolo JB (2005) PGEs and other traffic-related elements in roadside soils from Sao Paulo, Brazil. Sci Total Environ 345:81–91

    Article  Google Scholar 

  • Puls C, Limbeck A, Hann S (2012) Bioaccessibility of palladium and platinum in urban aerosol particulates. Atmos Environ 55:213–219

    Article  Google Scholar 

  • Rauch S, Peucker-Ehrenbrink B, Molina LT, Molina MJ, Ramos R, Hemond HF (2006) Platinum group elements in airborne particles in Mexico City. Environ Sci Technol 40:7554–7560

    Article  Google Scholar 

  • Sobrova P, Zehnalek J, Adam V, Beklova M, Kizek R (2012) The effects on soil/water/plant/animal systems by platinum group elements. Cent Eur J Chem 10:1369–1382

    Article  Google Scholar 

  • Wang Y, Li X (2012) Health risk of platinum group elements from automobile catalysts. Proc Eng 45:1004–1009

    Article  Google Scholar 

  • Wichmann H, Anquandah GAK, Schmidt C, Zachmann D, Bahadir AM (2007) Increase of platinum group element concentrations in soils and airborne dust in an urban area in Germany. Sci Total Environ 388:121–127

    Article  Google Scholar 

  • Wichmann H, Bahadir M (2001) Determination of the noble metals platinum, rhodium, and palladium in airborne particles. Fresenius Environ Bull 10:106–108

    Google Scholar 

  • Wiseman CLS, Zereini F (2009) Airborne particulate matter, platinum group elements and human health: a review of recent evidence. Sci Total Environ 407:2493–2500

    Article  Google Scholar 

  • Zereini F, Alt F, Messerschmidt J, von Bohlen A, Liebl K, Püttmann W (2004) Concentration and distribution of platinum group elements (Pt, Pd, Rh) in airborne particulate matter in Frankfurt am Main Germany. Environ Sci Technol 38:1686–1692

    Article  Google Scholar 

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Correspondence to Hubertus Wichmann .

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Wichmann, H., Bahadir, M. (2015). Increase of Platinum Group Element Concentrations in Soils and Airborne Dust During the Period of Vehicular Exhaust Catalysts Introduction. In: Zereini, F., Wiseman, C. (eds) Platinum Metals in the Environment. Environmental Science and Engineering(). Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-44559-4_11

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