Abstract
White polymer light-emitting diodes (WPLEDs) [1] have received great attention because of their potential application in backlight for flat panel displays and solid-state lighting sources. Basically, there are two approaches to realize high-efficiency WPLEDs. One is the polymer blend system [2–4] based on the additive color-mixing theory where the blend of the three primary colors (red, green, and blue) or two complementary colors (blue and orange) lead to pure white emission. However, voltage dependence of emitted color and phase separation hinder the utilization of the polymer blends [5]. To overcome these issues, an alternative approach, i.e., white-light emission from a single-component system, is desirable. Several studies have succeeded in realizing highly efficient WPLEDs based on polyfluorene derivatives containing red-, green-, and blue-emitting units in the backbone or the sidechain [6–11]. The color of the emission can be finely tuned by adjusting the composition of the RGB units and controlling the partial energy transfer from blue- to the low-energy-emissive units.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Wu H, Ying L, Yang W et al (2009) Progress and perspective of polymer white light-emitting devices and materials. Chem Soc Rev 38:3391–3400
Gong X, Ma WL, Ostrowski JC et al (2004) White electrophosphorescence from semiconducting polymer blends. Adv Mater 16:615–619
Gong X, Wang S, Moses D et al (2005) Multilayer polymer light-emitting diodes: white-light emission with high efficiency. Adv Mater 17:2053–2058
Zou J, Wu H, Lam C-S et al (2011) Simultaneous optimization of charge-carrier balance and luminous efficacy in highly efficient white polymer light-emitting devices. Adv Mater 23:2976–2980
Noh YY, Lee CL, Kim JJ et al (2003) Energy transfer and device performance in phosphorescent dye doped polymer light emitting diodes. J Chem Phys 118:2853–2864
Tu GL, Zhou QG, Cheng YX et al (2004) White electroluminescence from polyfluorene chemically doped with 1,8-napthalimide moieties. Appl Phys Lett 85:2172–2174
Liu J, Zhou QG, Cheng YX et al (2005) The first single polymer with simultaneous blue, green, and red emission for white electroluminescence. Adv Mater 17:2974–2978
Lee SK, Hwang DH, Jung BJ et al (2005) The fabrication and characterization of single-component polymeric white-light-emitting diodes. Adv Funct Mater 15:1647–1655
Jiang JX, Xu YH, Yang W et al (2006) High-efficiency white-light-emitting devices from a single polymer by mixing singlet and triplet emission. Adv Mater 18:1769–1773
Liu J, Chen L, Shao S et al (2007) Three-color white electroluminescence from a single polymer system with blue, green and red dopant units as individual emissive species and polyfluorene as individual polymer host. Adv Mater 19:4224–4228
Chien CH, Liao SF, Wu CH et al (2008) Electrophosphorescent polyfluorenes containing osmium complexes in the conjugated backbone. Adv Funct Mater 18:1430–1439
Liu J, Guo X, Bu L et al (2007) White electroluminescence from a single-polymer system with simultaneous two-color emission: polyfluorene as blue host and 2,1,3-benzothiadiazole derivatives as orange dopants on the side chain. Adv Funct Mater 17:1917–1925
Liu J, Shao S, Chen L et al (2007) White electroluminescence from a single polymer system: improved performance by means of enhanced efficiency and red-shifted luminescence of the blue-light-emitting species. Adv Mater 19:1859–1863
Poulsen DA, Kim BJ, Ma B et al (2010) Site isolation in phosphorescent bichromophoric block copolymers designed for white electroluminescence. Adv Mater 22:77–82
Shao S, Ding J, Wang L et al (2012) White electroluminescence from all-phosphorescent single polymers on a fluorinated poly(arylene ether phosphine oxide) backbone simultaneously grafted with blue and yellow phosphors. J Am Chem Soc 134:20290–20293
Adachi C, Kwong RC, Djurovich P et al (2001) Endothermic energy transfer: a mechanism for generating very efficient high-energy phosphorescent emission in organic materials. Appl Phys Lett 79:2082–2084
Ding J, Lue J, Cheng Y et al (2009) Effect of ancillary ligands on the properties of heteroleptic green iridium dendrimers functionalized with carbazole dendrons. J Organomet Chem 694:2700–2704
Wu F-I, Yang X-H, Neher D et al (2007) Efficient white-electrophosphorescent devices based on a single polyfluorene copolymer. Adv Funct Mater 17:1085–1092
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
Copyright information
© 2014 Springer-Verlag Berlin Heidelberg
About this chapter
Cite this chapter
Shao, S. (2014). All-Phosphorescent Single-Component White Polymers. In: Electrophosphorescent Polymers Based on Polyarylether Hosts. Springer Theses. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-44376-7_4
Download citation
DOI: https://doi.org/10.1007/978-3-662-44376-7_4
Published:
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-662-44375-0
Online ISBN: 978-3-662-44376-7
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)