Skip to main content

Liquefied Dimethyl Ether: An Energy-Saving, Green Extraction Solvent

  • Chapter
  • First Online:
Alternative Solvents for Natural Products Extraction

Part of the book series: Green Chemistry and Sustainable Technology ((GCST))

Abstract

Extraction is an essential procedure in the fields of food, pharmacy, and renewable bio-fuels, and it affords the recovery of desired components and the removal of undesired components from the natural feedstock. Conventional extraction techniques involving organic solvents and supercritical fluids have been extensively studied and used. Generally, these techniques are either economically or environmentally unfavourable because of the use of toxic solvents and considerable heating and pressurizing. Recently, a new extraction technique involving the use of liquefied dimethyl ether (DME) as a green solvent has attracted tremendous attention. This technique is economically efficient and environmentally friendly by virtue of the unique physical and chemical properties of DME. Additionally, the DME method can extract/remove the desired/undesired components as well as dewater (dry) the wet materials simultaneously. These advantages render the DME method practicable in several industrial fields. This chapter attempts to outline the potential of liquefied DME as an extraction solvent by elucidating the operating principles, procedures, and some recent studies and results.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 54.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Bligh EG, Dyer WJ (1959) A rapid method of lipid extraction and purification. Can J Biochem Physiol 37:911–917

    Article  CAS  Google Scholar 

  2. Catchpole O, Ryan J, Zhu Y, Fenton K, Grey J, Vyssotski M, Mackenzie A, Nekrasov E, Mitchell K (2010) Extraction of lipids from fermentation biomass using near-critical dimethylether. J Supercrit Fluids 53:34–41

    Article  CAS  Google Scholar 

  3. Czernik S, Bridgwater AV (2004) Overview of applications of biomass fast pyrolysis oil. Energ Fuels 18:590–598

    Article  CAS  Google Scholar 

  4. Delrue F, Setier P-A, Sahut C, Cournac L, Roubaud A, Peltier G, Froment AK (2012) An economic, sustainability, and energetic model of biodiesel production from micro algae. Bioresour Technol 111:191–200

    Article  CAS  Google Scholar 

  5. Demirbas A, Science S, Turkey T (2009) Production of biodiesel from algae oils. Energ Sources A 31:163–168

    Article  CAS  Google Scholar 

  6. EFSA (2009) Scientific opinion of the panel on food contact materials, enzymes, flavourings and processing aids (CEF) on dimethyl ether as an extraction solvent. EFSA J 84:1–13. http://dx.doi.org/10.2903/j.efsa.2009.984

  7. Food and Agriculture Organization of the United Nations-Production (FAOSTAT) (2010) http://faostat.fao.org/DesktopDefault.aspx?PageID=567&lang=en#ancor

  8. Gallagher BJ (2011) The economics of producing biodiesel from algae. Renew Energy 36:158–162

    Article  CAS  Google Scholar 

  9. Holldorff H, Knapp H (1988) Binary vapour-liquid-liquid equilibrium of dimethyl ether-water and mutual solubilities of methyl chloride and water: experimental results and data reduction. Fluid Phase Equilib 44:195–209

    Article  CAS  Google Scholar 

  10. Jae-Yon L, Chan Y, So-Young J, Chi-Yong A, Hee-Mock O (2010) Comparison of several methods for effective lipid extraction from micro algae. Bioresour Technol 101:75–77

    Article  Google Scholar 

  11. Jaime L, Mendiola JA, Ibáñez E, Martin-Álvarez PJ, Cifuentes A, Reglero G, Señoráns FJ (2007) β-Carotene isomer composition of sub- and supercritical carbon dioxide extracts. Antioxidant activity measurement. J Agric Food Chem 55:10585–10590

    Article  CAS  Google Scholar 

  12. Kanda H, Makino H (2009) Clean up process for oil-polluted materials by using liquefied DME. J Environ Eng 4:356–361

    Article  Google Scholar 

  13. Kanda H, Makino H (2010) Energy-efficient coal dewatering using liquefied dimethyl ether. Fuel 89:2104–2109

    Article  CAS  Google Scholar 

  14. Kanda H, Li P (2011) Simple extraction method of green crude from natural blue-green microalgae by dimethyl ether. Fuel 90:1264–1266

    Article  CAS  Google Scholar 

  15. Kanda H, Morita M, Makino H, Takegami K, Yoshikoshi A, Oshita K, Takaoka M, Morisawa S, Takeda N (2011) Deodorization and dewatering of biosolids by using dimethyl ether. Water Environ Res 83:23–25

    Article  CAS  Google Scholar 

  16. Kanda H, Li P, Ikehara T, Yasumoto-Hirose M (2012) Lipids extracted from several species of natural blue-green microalgae by dimethyl ether: extraction yield and properties. Fuel 95:88–92

    Article  CAS  Google Scholar 

  17. Kanda H, Li P, Yoshimura T, Okada S (2013a) Wet extraction of hydrocarbons from Botryococcus braunii by dimethyl ether as compared with dry extraction by hexane. Fuel 105:535–539

    Article  CAS  Google Scholar 

  18. Kanda H, Li P, Makino H (2013b) Production of decaffeinated green tea leaves using liquefied dimethyl ether. Food Bioprod Process. http://dx.doi.org/10.1016/j.fbp.2013.02.001

  19. Kitada K, Machmudah S, Sasaki M, Goto M, Nakashima Y, Kumamoto S, Hasegawa T (2009) Supercritical CO2 extraction of pigment components with pharmaceutical importance from Chlorella vulgaris. J Chem Technol Biotechnol 84:657–661

    Article  CAS  Google Scholar 

  20. Kondamude N, Mohapatra SK, Misra M (2008) Spent coffee grounds as a versatile source of green energy. J Agric Food Chem 56:11757–11760

    Article  Google Scholar 

  21. Liam B, Philip O (2010) Biofuels from microalgae – a review of technologies for production processing, and extraction of biofuels and co-products. Renew Sust Energ Rev 14:557–577

    Article  Google Scholar 

  22. Li P, Kanda H, Makino H (2014) Simultaneous production of bio-solid fuel and bio-crude from vegetal biomass using liquefied dimethyl ether. Fuel 116:370–376

    Article  CAS  Google Scholar 

  23. Molina Grima E, Belarbi E-H, Acién Fernández FG, Robles Medina A, Chisti Y (2003) Recovery of microalgal biomass and metabolites: process options and economics. Biotechnol Adv 20:491–515

    Article  CAS  Google Scholar 

  24. Mussatto SI, Carneiro LM, Silva JPA, Roberto IC, Teixeira JA (2011) A study on chemical constituents and sugars extraction from spent coffee grounds. Carbohydr Polym 83:368–374

    Article  CAS  Google Scholar 

  25. Meng X, Yang J, Xu X, Zhang L, Nie Q, Xian M (2009) Biodiesel production from oleaginous microorganisms. Renew Energy 34:1–5

    Article  Google Scholar 

  26. Oshita K, Takaoda M, Kitade S, Takeda N, Kanda H, Makino H, Matsumoto T, Morisawa S (2010) Extraction of PCBs and water from river sediment using liquefied dimethyl ether as an extractant. Chemosphere 78:1148–1154

    Article  CAS  Google Scholar 

  27. Sawangkeaw R, Bunyakiat K, Ngamprasertsith S (2010) Areview of laboratory-scale research on lipid conversion to biodiesel with supercritical methanol. J Supercrit Fluids 55:1–13

    Article  CAS  Google Scholar 

  28. Wu J, Zhou Y, Lemmon EW (2011) An equation of state for the thermodynamic properties of dimethyl ether. J Chem Eng Data 40:023104

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Peng Li .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2014 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Li, P., Makino, H. (2014). Liquefied Dimethyl Ether: An Energy-Saving, Green Extraction Solvent. In: Chemat, F., Vian, M. (eds) Alternative Solvents for Natural Products Extraction. Green Chemistry and Sustainable Technology. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-43628-8_5

Download citation

Publish with us

Policies and ethics