Abstract
The high performance characteristics of advanced composite materials depend not only on the physical properties of fiber and matrix but also upon the interfacial region that exists between these dissimilar components. This inter-facial region or interphase that is intermediate between the fiber phase and the matrix phase provides an important function in overall composite performance [1]. The interphase facilitates stress transfer from the moderately weak matrix resin to the high strength fiber and protects the fiber from environmental degradation. Stress can occur from differences in thermal expansion coefficients of fiber/matrix, cure shrinkage of thermoset matrices, or crystallization of thermoplastic matrices. Moreover the interphase can affect the matrix resin by preferential absorption of reactive monomer, oligomer or polymer or facilitate nucleation of crystalline high performance thermoplastic matrix.
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References
J. D. Miller and H. Ishida, “Adhesive-Adherend Interface and Interphase”, in “Fundamentals of Adhesion”, L. H. Lee, editor, Plenum, N.Y. (in press).
T. Takahagi and A. Ishitani, in “Molecular Characterization of Composite Interfaces,” H. Ishida and G. Kumar, editors, Plenum Press, N.Y. (1985).
I. L. Kalnin and H. Jager, in “Carbon Fibers and Their Composites,” E. Fitzer, editor, Springer, Berlin Heideberg New York (1985).
Ibid. p. 64.
E. P. Plueddemann, “Silane Coupling Agents,” Plenum, N.Y. 1982.
H. Ishida and J. L. Koenig, J. Col. Intf. Sci 64(3), 555 (1978).
J. L. Koenig, “Chemically Modified Surfaces,” Volume 1, D. E. Leyden, editor, Gordon and Breach, N.Y. (1986).
L. V. Phillips and A. M. Hercules, “Chemically Modified Surfaces,” D. E. Leyden, editor, Gordon and Breach, N.Y. (1986).
A. T. DeBenedetto and P. J. Lex, Poly. Eng and Sci. 29(8), 543 (1989).
M. R. Wertheimer and H. P. Schreiber, J. Appl. Poly. Sci., 26, 2087 (1981).
M. Takayanagi, T. Kajiyama and T. Katayose, ibid., 27, 3903 (1982).
F. M. Logulla, Sr. and Y-T. Wu, U.S. 4,418,164 (11/29/83) Dupont.
K. K. Chawla, “Composite Materials,” p. 97, Springer, Berlin Heidelberg New York (1987).
I. L. Kalnin and H. Jager, Chapter 1 in “Carbon Fibers and Their Composites,” E. Fitzer, editor, Springer, Berlin Heidelberg New York (1985) p. 66.
Reference 12, p. 157.
H. X. Nguyen, G. C. Weedon and H. W. Chang, SAMPE 34, 1603 (1989).
R. L. Hagenson, D. F. Register and D. A. Soules, ibid, 34, 2255 (1989).
L. T. Drzal, M. J. Rich, M. F. Koenig, P. F. Lloyd, J. Adhesion 16, 133 (1983).
P. S. Theocaris, G. Spathis and B. Kefales, Colloid & Polym. Sci, 260, 837 (1982).
Reference 1, p. 27.
F. S. Cheng, J. L. Kardos and T. L. Tolbert, SPE Journal 26, 62 (1970); J. L. Kardos, J. Adhesion, 4(1), (1972).
R. E. Lavengood and M. J. Michno, Jr. Proc. Div. Techn. Conf. Eng. Prop. Structure Div, SPE, 127 (1975).
J. L. Kardos, Chem Tech, July, p. 430 (1984).
D. L. Caldwell and D. A. Jarvie, SAMPE 33, 1268 (1988).
W. A. Fraser, F. H. Ancker, A. T. DeBenedetto and B. Elbirli, Poly. Comp, 4, 238 (1983).
C. T. Necker, V. Krishnamurthy, M. W. Barsoum and I. L. Kamel, SAMPE 34, 2161 (1989).
W-L. Wu, SAMPE J, 26(2), 11 (1990).
J. P. Rabe, Angew. Chem. Int. Ed. Engl., 28(1), 117 (1989).
J. L. Ackerman, Poly Prep, 29(1), 88 (1988).
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© 1994 Springer-Verlag Berlin Heidelberg
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Pilato, L.A., Michno, M.J. (1994). Composite Interphase. In: Advanced Composite Materials. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-35356-1_5
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DOI: https://doi.org/10.1007/978-3-662-35356-1_5
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