Abstract
The inner-shell ionization of atoms results in an emission of characteristic x-ray quanta or Auger electrons. A wavelength- or an energy-dispersive x-ray spectrometer can be coupled to a transmission electron microscope to record x-ray quanta emitted from the specimen. The quantitative methods developed for the x-ray microanalysis of bulk materials can be transferred to the investigation of thin specimens.
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References
S.T. Stephenson: The continous x-ray spectrum, in Handbuch der Physik, Vol. 30, ed. by S. Flügge ( Springer, Berlin 1957 ) p. 337
N.A. Dyson: X-Rays in Atomic and Nuclear Physics ( Longman, London 1973 )
H.H. Kramers: On the theory of x-ray absorption and of the continuous x-ray spectrum. Philos. Mag. 46, 836 (1923)
R.H. Pratt, H.K. Tseng, C.M. Lee, L. Kissel: Bremsstrahlung energy spectra from electrons of kinetic energy 1 keV= T1 =2000 keV incident on neutral atoms 2≤ Z ≤92. Atomic Data and Nuclear Data Tables 20, 175 (1977)
H.K. Tseng, C.M. Lee: Electron bremstrahlung angular distributions in the 1–500 keV energy range. Phys. Rev. A 19, 187 (1979)
P. Bernsen, L. Reimer: Total rate imaging with x-rays in a SEM, in Scanning Electron Microscopy 1984/IV ( SEM Inc., AMF O’Hare, Chicago ) p. 1707
A. Sommerfeld: Uber die Beugung and Bremsung der Elektronen. Ann. Phys. 11, 257 (1931)
P. Kirkpatrick, L. Wiedmann: Theoretical continuous x-ray energy and polarization. Phys. Rev. 67, 321 (1945)
N.F. Mott, H.S.W. Massey: The Theory of Atomic Collisions, 3rd ed. ( Oxford Univ. Press, Oxford 1965 )
C.R. Worthington, S.G. Tomlin. The intensity of emission of characteristic x-radiation. Proc. Phys. Soc. A 69, 401 (1956)
M. Gryzinski: Classical theory of atomic collisions. I. Theory of inelastic collisions. Phys. Rev. A 138, 336 (1965)
C.J. Powell: Cross-sections for ionization of inner-shell electrons by electrons. Rev. Mod. Phys. 48, 33 (1976)
C.J. Powell: Inelastic scattering of electrons, in Electron Beam Interactions with Solids, ed. by D.F. Kyser et al. ( SEM Inc., AMF O’Hare, Chicago 1982 ) p. 19
J.W. Motz, R.C. Placions: K-ionization cross sections for relativistic electrons. Phys. Rev. A 136, 662 (1964)
J.A. Bearden: X-ray wavelengths. Rev. Mod. Phys. 39, ‘78 (1967)
J.A. Bearden, A.F. Burr: Reevaluation of x-ray atomic energy levels. Rev. Mod. Phys. 39, 125 (1967)
R.W. Fink, R.C. Jopson, H. Mark, C.D. Swift: Atomic fluorescence yields. Rev. Mod. Phys. 38, 513 (1966)
W. Bambynek, B. Crasemann, R.W. Fink, H.U. Freund, H. Mark, C.D. Swift, R.E. Price, R.V. Rao: X-ray fluorescence yields, Auger and CosterKronig transition probabilities. Rev. Mod. Phys. 44, 716 (1972)
H.U. Freund: Recent experimental values for K-shell fluorescence yields. X-Ray Spectrom. 4, 90 (1975)
P. Kruit, J.A. Venables: High-spatial-resolution surface-sensitive electron spectroscopy using a magnetic parallelizer. Ultramicroscopy 25, 183 (1988)
T.K. Kelly: Mass absorption coefficients and their relevance in electron probe microanalysis. Trans. Inst. Min. Metall. B 75, 59 (1966)
K.F.J. Heinrich: X-ray absorption uncertainty, in The Electron Microprobe, ed. by T.D. McKinley, K.F.J. Heinrich, D.B. Wittry ( Wiley, New York 1966 )
J.W. Mayer, E. Rimini: Ion Beam Handbook for Materials Analysis ( Academic, New York 1977 )
J.H. Hubble: Photon mass attenuation and energy absorption coefficients from 1 keV to 20 keV. Int’l J. Appl. Radiat. Isot. 33, 1269 (1982)
C.J. Cooke, P. Duncumb: Performance analysis of a combined microscope and electron probe microanalyser `EMMA’, in 5th Int’l Congr. on X-Ray Optics and Microanalysis, ed. by G. Möllenstedt, K.H. Gaukler ( Springer, Berlin, Heidelberg 1969 ) p. 245
C.J. Cooke, I.K. Openshaw: Combined high resolution electron microscopy and x-ray microanalysis, in [Ref.1.55, Vol.1, p.175]
D.A. Gedcke: The Si(Li) x-ray energy analysis system: operating principles and performance. X-Ray Spectrometry 1, 129 (1972)
D.A. Gedcke: The Si(Li) x-ray spectrometer for x-ray microanalysis, in [Ref.1.105, p.403]
C.E. Fiori, D.E. Newbury: Artifacts observed in energy-dispersive x-ray spectrometry in the SEM, in Scanning Electron Microscopy 1978/I ( SEM Inc., AMF O’Hare, Chicago ) p. 401
T.J. White, D.R. Cousens, G.J. Auchterlonie: Preliminary characterization of an intrinsic germanium detector on a 400-keV microscope. J. Microsc. 162, 379 (1991)
P.J. Staham, J.V.P. Long, G. White, K. Kandiah: Quantitative analysis with an energy-dispersive detector using a pulsed electron probe and active signal processing. X-Ray Spectrometry 3, 153 (1974)
C.E. Lyman, J.I. Goldstein, D.B. Williams, D.W. Ackland, S. von Harrach, A.W. Nicholls. P.J. Staham: High-performance x-ray detection in a new analytical electron microscope. J. Microsc. 176, 85 (1994)
T.A. Hall: Reduction of background due to backscattered electrons in energy dispersive x-ray microanalysis. J. Microsc. 110, 103 (1977)
B. Neumann, L. Reimer: A permanent magnet system for electron deflection in front of an energy dispersive x-ray spectrometer. Scanning 1, 130 (1978)
N.C. Barbi, A.O. Sandborg, J.C. Russ, C.E. Soderquist: Light element analysis on the SEM using a windowless energy dispersive x-ray spectrometer, in Scanning Electron Microscopy 1974, ed. by O. Johari ( IIT Research Inst., Chicago 1974 ) p. 289
J.C. Russ: Procedures for quantitative ultralight element energy dispersive x-ray analysis, in Scanning Electron Microscopy 1977/I, ed. by O. Johari ( IIT Research Inst., Chicago 1977 ) p. 289
C.E. Lyman, D.B. Williams, J.I. Goldstein: X-ray detectors and spectrometers. Ultramicroscopy 28, 137 (1988)
R. Schmidt, M. Feller-Kniepmeier: Investigation of system-induced background radiation using a 0–160 keV high-purity germanium detector. Ultra-microscopy 34, 229 (1990)
F. Hofer, W. Grogger, P. Golob: Detector strategy in x-ray microanalysis, in Analytical TEM in Materials Science, Proc. Autumn School 1993, ed. by J. Heydenreich, W. Neumann (Max-Planck Inst. für Mikrostrukturphysik, Halle 1993 ), p. 50
M.J. Jacobs, J. Baborovska: Quantitative microanalysis of thin foils with a combined electron microscope—microanalyser (EMMA-3), in Electron Microscopy 1972 (IoP, London 1972 ) p. 136
G.W. Lorimer, F. Cliff, J.N. Clark: Determination of the thickness and spatial resolution for the quantitative analysis of thin foils, in Developments in Electron Microscopy and Analysis, ed. by J.A. Venables ( Academic, London 1976 ) p. 153
R. König: Quantitative microanalysis of thin foils, in [Ref.1.29, p.526]
J.I. Goldstein, J.L. Costley, G.W. Lorimer, S.J.B. Reed: Quantitative x-ray analysis in the electron microscope, in Scanning Electron Microscopy 1977/I, ed. by O. Johari ( IIT Research Inst., Chicago 1977 ) p. 315
Z. Horita, T. Sano, M. Nemoto: A new form of the extrapolation method for absorption correction in quantitative x-ray microanalysis with the analytical electron microscope. Ultramicroscopy 35, 27 (1991)
J. Philibert, R. Tixier: Electron probe microanalysis of TEM specimens, in [Ref.1.12, p.333]
G.W. Lorimer, S.A. Al-Salman, G. Cliff: The quantitative analysis of thin specimens: Effects of absorption, fluorescence and beam spreading, in Developments in Electron Microscopy and Analysis 1977, ed. by D.L. Misell ( IoP, London 1977 ) p. 369
I.M. Anderson, J. Bentley, C.B. Carter: The secondary fluorescence correction for x-ray microanalysis in the analytical electron microscope. J. Microsc. 178, 226 (1995)
C.R. Hall: On the production of characteristic x-rays in thin metal crystals. Proc. Roy. Soc. (London) A 295, 140 (1966)
D. Cherns, A. Howie, M.H. Jacobs: Characteristic x-ray production in thin crystals. Z. Naturforsch. A 28, 565 (1973)
B. Neumann, L. Reimer: Anisotropic x-ray generation in thin and bulk single crystals. J. Phys. D 13, 1737 (1980)
A.J. Bourdillon, P.G. Self, W.M. Stobbs: Crystallographic orientation effects in energy dispersive x-ray analysis. Philos. Mag. A 44, 1335 (1981)
I. Hashimoto, E. Wakai, H. Yamaguchi: Dependence of the x-ray detection orientation on Cliff—Lorimer factor for quantitative microanalysis in an electron microscope. Ultramicroscopy 32, 121 (1990)
J.C.H. Spence, J. Tafto: ALCHEMI: a new technique for locating atoms in small crystals. J. Microsc. 130, 147 (1983)
S.J. Pennycook: Delocalization corrections for electron channeling analysis. Ultramicroscopy 26, 239 (1988)
C.J. Rossouw, P.S. Turner, T.J. White, A.J, O’Connor: Statistical analysis of electron channelling microanalytical data for the determination of site occupancies of impurities. Philos. Mag. Lett. 60, 225 (1989)
W. Qian, B. Tötdal, R. Hoier, J.C.H. Spence: Channelling effects on oxygen-characteristic x-ray emission and their use as a reference site for ALCHEMI. Ultramicroscopy 41, 147 (1992)
J. Taft0, Z. Liliental: Studies of the cation atom distribution in ZnCrxFe2_xO4 spinels using the channeling effect in electron induced x-ray emission. J. Appl. Cryst. 15, 260 (1992)
L.J. Allen, T.W. Josefsson, C.J. Rossouw: Interaction delocalization in characteristic x-ray emission from light elements. Ultramicroscopy 55, 258 (1994)
W. Nüchter, W. Sigle: Electron channelling: a method in real-space crystallography and a comparison with the ALCHEMI. Philos. Mag. A 71, 165 (1995)
J. Taft0, O.L. Krivanek: Site-specific valence determination by EELS. Phys. Rev. Lett. 48, 560 (1982)
J. Taft0, G. Lehmpfuhl: Direction dependence in EELS from single crystals. Ultramicroscopy 7, 287 (1982)
J. Bentley, N.J. Zaluzec, E.A. Kenik, R.W. Carpenter: Optimization of an analytical electron microscope for x-ray microanalysis, in Scanning Electron Microscopy 1979/11, ed. by O. Johari (SEM, AMF O’Hare, IL 1979 ) p. 581
J. Philibert, R. Tixier: Electron penetration and the atomic number correction in electron probe microanalysis. J. Phys. D 1, 685 (1968)
M.J. Nasir: Quantitative analysis on thin films in EMMA-4 using block standards, in Electron Microscopy 1972 (IoP, Lonson 1972 ) p. 142
G. Cliff, G.W. Lorimer: Quantitative analysis of thin metal foils using EMMA-4 — the ratio technique, in Electron Microscopy 1972 ( IoP, London 1972 ) p. 140
G. Cliff, G.W. Lorimer: The quantitative analysis of thin specimens. J. Microsc. 103, 203 (1975)
M.N. Thompson, P. Doig, J.W. Edington, P.E.J. Flewitt: The influence of specimen thickness on x-ray count rates in STEM microanalysis. Philos. Mag. 35, 1537 (1977)
J.K. Park, A.J. Ardell: Solute-enriched surface layers and x-ray microanalysis of thin foils of a commercial aluminium alloy. J. Microsc. 165, 301 (1992)
P. Schwaab: Quantitative energy-dispersive x-ray microanalysis of thin metal specimens using the STEM. Scanning 9, 1 (1987)
R. Gauvin, G. L’Espérance: Determination of the C 7 / parameter in the Bethe formula for the ionization cross-section by use of Cliff—Lorimer k a b factors obtained at different accelerating voltages. J. Microsc. 163, 295 (1991)
T.P. Schreiber, A.M. Wims: A quantitative x-ray microanalysis thin film method using K-, L- and M-lines. Ultramicroscopy 6, 323 (1981)
J.E. Wood, D.C. Williams, J.I. Goldstein: Experimental and theoretical determination of ka,Fe factors for quantitative x-ray microanalysis in the analytical electron microscope. J. Microsc. 133, 255 (1984)
D.B. Williams, J.R. Michael, J.I. Goldstein, A.D. Romig: Definition of the spatial resolution of x-ray microanalysis in thin foils. Ultramicroscopy 47, 121 (1992)
C.E. Lyman, P.E. Manning, D.J. Duquette, E. Hall: STEM microanalysis of duplex stainless steel weld metal, in Scanning Electron Microscopy 1978/I, ed. by O. Johari (SEM, AMF O’Hare, IL 1978 ) p. 213
D.B. Williams, J.I. Goldstein: STEM/x-ray microanalysis across cx/y interfaces in FeNi meteorites, in [Ref.1.57, p.416]
N.J. Long: Digital x-ray mapping on an HB501 STEM, a new approach for the analysis of interfaces. Ultramicroscopy 34, 81 (1990)
A.M. Ritter, W.G. Morris, M.F. Henry: Factors affecting the measurement of composition profiles in STEM, in Scanning Electron Microscopy 1979/I, ed. by O. Johari (SEM, AMF O’Hare, IL 1979 ) p. 121
T.A. Hall: The microprobe assay of chemical elements, in Physical Techniques in Biological Research, Vol. 1, Pt.A, ed. by G. Oster (Academic, New York 1971 ) p. 157
T.A. Hall, H.C. Anderson, T. Appleton: The use of thin specimens for x-ray microanalysis in biology. J. Microsc. 99, 177 (1973)
T.A. Hall, B.L. Gupta: EDS quantitation and application to biology, in [Ref.1.66, p.169]
A. Warley: Standards for the application of x-ray microanalysis to biological specimens. J. Microsc. 157, 135 (1990)
A. Patak, A. Wright, A.T. Marshall: Evaluation of several common standards for the x-ray microanalysis of thin biological sections. J. Microsc. 170, 265 (1993)
H. Shuman, A.V. Somlyo, A.P. Somlyo: Quantitative electron probe microanalysis of biological thin sections: Methods and validity. Ultramicroscopy 1, 317 (1976)
G.M. Roomans: Standards for x-ray microanalysis of biological specimens, in Scanning Electron Microscopy 1979/II, ( SEM Inc., AMF O’Hare, IL 1979 ) p. 649
F.F. Ingram, M.J. Ingram: Electron microprobe calibration for measurements of intracellular water, in Scanning Electron Microscopy 1979/II ( SEM Inc., AMF O’Hare, IL 1979 ) p. 649
G.M. Roomans, H.L.M. van Gaal: Organometallic and organometalloid compounds as standards for microprobe analysis of epoxy resin embedded tissue. J. Microsc. 109, 235 (1977)
N. Roos, T. Barnard: Aminoplastic standards for quantitative x-ray microanalysis of thin sections of plastic embedded biological material. Ultramicroscopy 15, 277 (1984)
A.J. Morgan, C. Winters: Practical notes on the production of thin amino-plastic standards for quantitative x-ray microanalysis. Micron Microsc. Acta 20, 209 (1989)
W.C. De Bruijn, M.I. Cleton-Soeteman: Application of Chelex standard beads in integrated morphometrical and x-ray microanalysis, in Scanning Electron Microscopy 1985/II ( SEM Inc., AMF O’Hare, IL 1985 ) p. 715
A. Dörge, R. Rick, K. Gehring, K. Thurau: Preparation of frozen-dried cryosections for quantitative x-ray microanalysis of electrolytes in biological soft tissue. Pflügers Arch. 373, 85 (1978)
T. von Zglinicki, M. Bimmler, W. Krause: Estimation of organelle water fractions from frozen-dried cryosections. J. Microsc. 146, 67 (1987)
K.E. Tvedt, G. Kopstad, J. Halgunset, O.A. Haugen: Rapid freezing of small biopsies and standards for cryosectioning and x-ray microanalysis. Am. J. Clin. Pathol. 92, 51 (1989)
D.C. Joy, D.M. Maher: The electron energy-loss spectrum: facts and artifacts, in Scanning Electron Microscopy 1980/I ( SEM Inc., Chicago 1980 ) p. 25
A.J. Craven, T.W. Buggy: Correcting electron energy loss spectra for artefacts introduced by serial collection. J. Microsc. 136, 227 (1984)
O.L. Krivanek, C.C. Ahn, R.B. Keeney: Parallel detection electron spectrometer using quadrupole lenses. Ultramicroscopy 22, 103 (1987)
A.J. Gubbens, O.L. Krivanek: Applications of post-column imaging filter in biology and materials science. Ultramicroscopy 51, 146 (1993)
R.F. Egerton, Y.Y. Yang, S.C. Cheng: Characterization and use of the Gatan parallel-recording electron energy-loss spectrometer. Ultramicroscopy 48, 239 (1993)
D.W. Johnson: A Fourier series method for numerical Kramers—Kronig analysis. J. Phys. A 8, 490 (1975)
R.F. Egerton, S.C. Cheng: Thickness measurement by EELS, in Proc. 43rd Ann. Meeting EMSA, ( San Francisco Press, San Francisco, CA 1985 ) p. 389
D.R. Liu, D.B. Williams: Influence of some practical factors on background extrapolation in EELS quantification. J. Microsc. 156, 201 (1987)
T. Pun, J.R. Ellis, M. Eden: Weighted least squares estimation of background in EELS imaging. J. Microsc. 137, 93 (1985)
C. Colliex, C. Jeanguillaume, P. Trebbia: Quantitative local microanalysis with EELS, in [Ref.1.119, p.251]
M. Unser, J.R. Ellis, T. Oun, M. Eden: Optimal background estimation in EELS. J. Microsc. 145, 245 (1987)
C.W. Sorber, G.A.M. Ketelaars, E.S. Gelsema, J.F. Jongkind, W.C. De Bruijn: Quantitative analysis of electron energy-loss spectra from ultrathinsectioned biological material. J. Microsc. 162, 23 (1991)
A.L.D. Beckers, E.S. Gelsema, W.C. De Bruijn: An efficient method for calculating the least-squares background fit in EELS. J. Microsc. 171, 87 (1993)
J. Bentley, G.L. Lehmann, P.S. Sklad: Improved background fitting for EELS, in [Ref.1.58, Vol. 1, p.585]
H. Shuman, P. Kruit: Quantitative data-processing of parallel recorded EELS with low signal to background. Rev. Sci. Instr. 56, 231 (1985)
M.K. Kundmann: Analysis of semiconductor EELS in the low-loss regime, in Microbeam Analysis 1986, ed. by A.D. Romig, W.F. Chambers ( San Francisco Press, San Francisco, CA 1986 ) p. 417
C.P. Scott, A.J. Craven, C.J. Gilmore, A.W. Bowen: Background fitting in the low-loss region of electron energy-loss spectra, in [Ref.1.60, Vol.2, p.56]
J.D. Steele, J.M. Titchmarsh, J.N. Chapman, J.H. Paterson: A single stage process for quantifying electron energy-loss spectra. Ultramicroscopy 17, 273 (1985)
R.D. Leapman, C.R. Swyt: Separation of overlapping core edges in electron energy loss spectra by multiple least squares fitting. Ultramicroscopy 26, 393 (1988)
D.W. Johnson, J.C.H. Spence: Determination of the single-scattering probability distribution from plural-scattering data. J. Phys. D 7, 771 (1974)
C.R. Swyt, R.D. Leapman: Plural scattering in electron energy-loss microanalysis, in Scanning Electron Microscopy 19827, ( SEM Inc., Chicago 1982 ) p. 73
R.F. Egerton, P.A. Crozier: The use of Fourier techniques in EELS, in San- ning Electron Microscopy, Supp1. 2 ( SEM Inc., Chicago 1988 ) p. 245
C.R. Bradley, M.L. Wroge, P.C. Gibbons: How to remove multiple scattering from core-excitation spectra. Ultramicroscopy 16, 95 (1985); 19, 317 (1986); 21, 305 (1987)
D.S. Su, P. Schattschneider: Numerical aspects of the deconvolution of angle- integrated electron energy-loss spectra. J. Microsc. 167, 63 (1992)
D.S. Su, P. Schattschneider: Deconvolution of angle-resolved electron energy-loss spectra. Philos. Mag. A 65, 1127 (1992)
K. Wong, R.F. Egerton: Correction for the effects of elastic scattering in core-loss quantification. J. Microsc. 178, 198 (1995)
M. Isaacson, D. Johnson: The microanalysis of light elements using transmitted energy loss electrons. Ultramicroscopy 1, 33 (1975)
R.F. Egerton, M.J. Whelan: High resolution microanalysis of light elements by electron energy loss spectrometry, in [Ref.1.56, Vol.1, p.384]
J. Sévely, J.Ph. Pérez, B. Jouffrey: Energy loss of electrons through Al and carbon films from 300 keV up to 1200 keV, in [Ref.1.78, p.32]
R.F. Egerton: Formulae for light-element microanalysis by electron energy-loss spectrometry. Ultramicroscopy 3, 243 (1978)
P.G. Self, P.R. Buseck: Low-energy limit to channelling effects in the inelastic scattering of fast electrons. Philos. Mag. A 48, L21 (1983)
J. Tafto, O.L. Krivanek: Characteristic energy-losses from channeled 100 keV electrons. Nucl. Instr. Methods 194. 153 (1982)
R.F. Egerton, C.J. Rossouw, M.J. Whelan: Progress towards a method for quantitative microanalysis of light elements by electron energy-loss spectrometry, in Developments in Electron Microscopy and Analysis, ed. by J.A. Venables ( Academic, London 1976 ) p. 129
C.E. Fiori, R.D. Leapman, C.R. Swyt, S.B. Andrews: Quantitative x-ray mapping of biological cryosections. Ultramicroscopy 24, 237 (1988)
D.E. Johnson, K. Izutsu, M. Cantino, J. Wong: High spatial resolution spectroscopy in the elemental microanalysis and imaging of biological systems. Ultramicroscopy 24, 221 (1988)
A. LeFurgey, S.D. Davilla, D.A. Kopf, J.R. Sommer, P. Ingram: Real-time quantitative elemental analysis and mapping: microchemical imaging in cell physiology. J. Microsc. 165, 191 (1992)
A. Berger, J. Mayer, H. Kohl: Detection limits in elemental distribution images produced by energy filtering TEM: case study of grain boundaries in Si3N4. Ultramicroscopy 55, 101 (1994)
C. Colliex: An illustrated review of various factors governing the high spatial resolution capabilities in EELS microanalysis. Ultramicroscopy 18, 131 (1985)
R.D. Leapman: STEM elemental mapping by electron energy-loss spectroscopy. Ann. New York Acad. Sci. 483, 326 (1986)
H. Shuman, C.F. Chang, E.L. Bahe, A.P. Somlyo: Electron energy-loss spectroscopy: quantitation and imaging. Ann. New York Acad. Sci. 483, 295 (1986)
R.H. Barckhaus, H.J. Höhling, I. Fromm, P. Hirsch, L. Reimer: Electron spectroscopic diffraction and imaging of the early and mature stages of calcium phosphate formation in the epiphyseal growth plate. J. Microsc. 162, 155 (1991)
H. Lehmann, U. Kunz, A. Jacob: A simplified preparation procedure of plant material for elemental analysis by ESI and EELS techniques. J. Microsc. 162, 77 (1991)
W. Probst, E. Zellmann, R. Bauer: Electron spectroscopic imaging of frozen-hydrated sections. Ultramicroscopy 28, 312 (1989)
R.R. Schröder: Zero-loss energy-filtered imaging of frozen-hydrated proteins: model calculations and implications for future developments. J. Microsc. 166, 389 (1992)
M. Creuzburg: Entstehung von Alkalimetallen bei der Elektronenbestrahlung von Alkalihalogeniden. Z. Phys. 194, 211 (1966)
P.A. Crozier, J.N. Chapman, A.J. Craven, J.M. Titchmarsh: Some factors affecting the accuracy of EELS in determining elemental concentrations in thin films, in Analytical Electron Microscopy 1984, ed. by D.B. Williams, D.C. Joy ( San Francisco Press, San Francisco, CA 1984 ) p. 79
T.O. Ziebold: Precision and sensitivity in electron microprobe analysis. Anal. Chem. 39, 858 (1967)
D.C. Joy, D.M. Maher: Sensitivity limits for thin specimen x-ray analysis, in Scanning Electron Microscopy 1977/I (IIT Research Inst., Chicago, IL 1977 ) p. 325
R.D. Leapman: EELS quantitative analysis, in [Ref.1.70, p.47]
D.C. Joy, D.M. Maher: Electron energy loss spectroscopy: Detectable limits for elemental analysis. Ultramicroscopy 5, 333 (1980)
R.D. Leapman, S.B. Andrews: Biological electron energy loss spectroscopy: the present and the future. Microsc. Microanal. Microstr. 2, 387 (1991)
C. Mory, C. Colliex: Elemental analysis near the single-atom detection level by processing sequences of energy-filtered images. Ultramicroscopy 28, 339 (1989)
K.H. Körtje: Image-EELS: simultaneous recording of multiple electron energy-loss spectra from series of electron spectroscopic images. J. Microsc. 174, 149 (1994)
K.M. Adamson-Sharpe, F.P. Ottensmeyer: Spatial resolution and detection sensitivity in microanalysis by electron energy loss selected imaging. J. Microsc. 122, 309 (1981)
D.P. Bazett-Jones, F.P. Ottensmeyer: DNA organization in nucleosomes. Can. J. Biochem. 60, 364 (1982)
F.P. Ottensmeyer, D.W. Andrews, A.L. Arsenault, Y.M. Heng, G.T. Simon, G.C. Weatherly: Elemental imaging by electron energy loss microscopy. Scanning 10, 227 (1988)
A. Berger, H. Kohl: Optimum imaging parameters for elemental mapping in an energy filtering TEM. Optik 92, 175 (1993)
U. Plate, H.J. Höhling, L. Reimer, R.H. Barckhaus, R. Wienecke, H.P. Wies-mann, A. Boyde: Analysis of the calcium distribution in predentine by EELS and of the early crystal formation in dentine by ESI and ESD. J. Microsc. 166, 329 (1992)
R.H. Ritchie: Quantal aspects of the spatial resolution of energy-loss measurements in electron microscopy. Philos. Mag. A 44, 931 (1981)
H. Kohl: Image formation by inelastically scattered electrons: image of a surface plasmon. Ultramicroscopy 11, 53 (1983)
H. Kohl, A. Berger: The resolution limit for elemental mapping in energy-filtering TEM. Ultramicroscopy 59, 191 (1995)
D.A. Muller, J. Silcox: Delocalization in inelastic scattering. Ultramicroscopy 59, 195 (1995)
W. Jäger, J. Mayer: Energy-filtered TEM of Sim Gen superlattices and Si-Ge heterostructures. I. Experimental results. Ultramicoscopy 59, 33 (1995)
J.C.H. Spence, J. Lynch: STEM microanalysis by transmission EELS in crystals. Ultramicroscopy 9, 267 (1982)
C. Colliex: An illustrated review of various factors governing the high spatial resolution capabilities in EELS microanalysis. Ultramicroscopy 18, 131 (1985)
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Reimer, L. (1997). Elemental Analysis by X-Ray and Electron Energy-Loss Spectroscopy. In: Transmission Electron Microscopy. Springer Series in Optical Sciences, vol 36. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-14824-2_10
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