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Absorption Spectroscopy as an Analytical Method in Rubber Chemistry

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Methoden zur Chemischen Analyse von Gummimischungen

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Abstract

There is a number of textbooks treating the fundamentals of spectroscopy and absorption spectroscopy in particular, and we assume that the reader of this material is familiar with the principles involved. On the basis of economy of instrumentation, utility, and convenience of technique, the rubber analyst will be mostly interested in the ultraviolet, visible and near-infrared spectral regions up to 3.2 μ, to which this discussion is therefore largely confined The identification of materials is based upon plotting units of absorbance (ordinate) versus units of wavelength (abscissa) to obtain an absorbance curve over the spectral region of interest. If absorbance is selective, some wavelengths are absorbed more than others, and the curve will show a series of peaks (maxima) and valleys (minima) which is characteristic for the compound. Comparison of the absorbance spectra with a catalog of known spectra of materials will usually identify the unknown material. This is simplified if the number of possible materials is limited, as is the case in rubber compounds.

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Bibliography

  1. Friedel, R. A., and M. Orobin: Ultraviolet Spectra of Aromatic Compounds, 579 spectra. New York City, U.S.A.: John Wiley and Sons.

    Google Scholar 

  2. Mellon, M. G.: Analytical Absorption Spectroscopy, 618 p., New York City, U.S.A., John Wiley and Sons.

    Google Scholar 

  3. Kaye, W. I.: Spectrochimica Acta, Part I — 6, 257 (1954)

    CAS  Google Scholar 

  4. Kaye, W. I.: Ibid. Part II — 7, 181 (1955).

    CAS  Google Scholar 

  5. Mees, F. G.: Stevens, unpublished work.

    Google Scholar 

  6. O’conner, R. T.: Jour. Amer. Oil Chem. Soc. 33, 1 (1956).

    Google Scholar 

  7. Kress, K. E.: unpublished work.

    Google Scholar 

  8. Kress, K. E., and F. G. Mess Stevens: Anal. Chem. 27, 528 (1955)

    Article  CAS  Google Scholar 

  9. Kress, K. E., and F. G. Mess Stevens: Rubber Chem. Techn. 29, 319 (1956).

    Article  Google Scholar 

  10. Kress, K. E., and F. G. Mees Stevens: „Chemical and Spectrophotometric Methods of Guanidine Accelerator Analysis“, unpublished (1950).

    Google Scholar 

  11. Wadelin, C. W.: Anal. Chem. 28, 1530 (1956).

    Article  CAS  Google Scholar 

  12. Kress, K. E.: Anal. Chem. 23, 313 (1951).

    Article  CAS  Google Scholar 

  13. Kress, K. E.: Anal. Chem. 30, 432 (1958).

    Article  CAS  Google Scholar 

  14. Fiorenza, A.: Rubber Age, N. Y., 80, 69 (1956).

    CAS  Google Scholar 

  15. Voet, A.: Rubber Age, N. Y. 82, 657 (1958).

    CAS  Google Scholar 

  16. Vandenbelt, J. M., J. Forsyth, and A. Garrett: Anal. Chem. 17, 235 (1945).

    CAS  Google Scholar 

  17. Brode, W. R.: Chemical Spectroscopy, Second Ed., (1943), New York City, U.S.A.: John Wiley and Sons.

    Google Scholar 

  18. Lothian, G. F.: Absorption Spectrophotometry, 196 p. London, England: Hilger and Watts, Ltd. 1949.

    Google Scholar 

  19. Meehan, E. J: Jour. Polymer Science, 1, 175 (1946)

    Article  CAS  Google Scholar 

  20. Meehan, E. J: Rubber Chem. Techn. 19, 1077 (1946).

    Article  Google Scholar 

  21. Banes, F. W., and L. T. Eby: Ind. Eng. Chem., Anal. Ed., 18, 535 (1946)

    Google Scholar 

  22. Banes, F. W., and L. T. Eby: Rubber Chem. Tech. 20, 55 (1947).

    Article  Google Scholar 

  23. Kress, K. E.: Anal. Chem. 29, 803 (1957).

    Article  CAS  Google Scholar 

  24. Kress, K. E.: “The Quantitative Absorptiometric Determination of Elastomers in Rubber Products”, application of near-infrared, to be published in Anal. Chem.

    Google Scholar 

  25. Dufraisee, C., and J. Houpillart: Rev. gen. Caoutchouc 16, 44 (1939)

    Google Scholar 

  26. Dufraisee, C., and J. Houpillart: Chem. Abstracts 33, 9043. 3 (1939).

    Google Scholar 

  27. Dufraisee, C., and J. Houpillart: Rev. gen. Cauotchouc, 19, 207 (1942)

    Google Scholar 

  28. Dufraisee, C., and J. Houpillart: Rubber Chem. Techn. 19, 1051 (1946).

    Article  Google Scholar 

  29. Dufraisee, C., and A. Jarrijon: Compt. rend. 215, 181 (1942)

    Google Scholar 

  30. Dufraisee, C., and A. Jarrijon: Rubber Chem. Tech. 17, 941 (1944).

    Article  Google Scholar 

  31. Jarrijon, A.: Rev. gen. Caoutchouc 18, 217 (1941)

    CAS  Google Scholar 

  32. Jarrijon, A.: Chem. Abstracts 37, 2955. 7 (1943).

    Google Scholar 

  33. Jarrijon, A.: Rev. gen. Caoutchouc 20, 155, 177 (1943)

    Google Scholar 

  34. Jarrijon, A.: Rubber Chem. Tech. 19, 1061 (1946).

    Article  Google Scholar 

  35. Koch, H. P.: Jour. Chem. Soc. 92, 401 (1949).

    Google Scholar 

  36. Brock, M. J., and G. D. Loumh: Anal. Chem. 27, 1575 (1955)

    Article  CAS  Google Scholar 

  37. Brock, M. J., and G. D. Loumh: Rubber Chem. Tech. 29, 635 (1956).

    Article  Google Scholar 

  38. Humphry, B. J.: Anal. Ed., Ind. Eng. Chem., 8, 153 (1936).

    Google Scholar 

  39. Hilton, C. L., and J. E. Newell: Rubber Age, 83, 981 (1958).

    Google Scholar 

  40. Parker, C. A., and J. M. Berriman: Trans. I.R. I. 28, 279 (1952)

    Google Scholar 

  41. Parker, C. A., and J. M. Berriman: Ibid. 30, 69 (1954)

    Google Scholar 

  42. Parker, C. A., and J. M. Berriman: Rubber Chem. Tech. 26, 449 (1953).

    Article  CAS  Google Scholar 

  43. Bellamy, L. J., J. H. Lawrie, and E. W. S. Press: Trans. I.R.I., 22, 308 (1947)

    CAS  Google Scholar 

  44. Bellamy, L. J., J. H. Lawrie, and E. W. S. Press: Rubber Chem. Tech. 21, 195, 734 (1948).

    Google Scholar 

  45. Zijp, J. W. H.: Recueil 75, 1053, 1060, 1129, 115 (1956).

    Google Scholar 

  46. Zijp, J. W. H.: Recueil 77, 129 (1958).

    Article  CAS  Google Scholar 

  47. Burchfield, H. P.: Ind. Eng. Chem., Anal. Ed. 17, 806 (1945)

    Google Scholar 

  48. Burchfield, H. P.: Rubber Chem. Tech. 19, 832 (1946).

    Article  Google Scholar 

  49. Brock, M. J., and G. D. Louth: “The Identifification of Polymers and Polymer Mixtures”, application of Near-Infrared, to be published in Anal. Chem.

    Google Scholar 

  50. Kress, K. E.: Anal. Chem. 27, 1618 (1955)

    Article  CAS  Google Scholar 

  51. Kress, K. E.: Rubber Chem. Tech. 29, 620 (1956).

    Article  Google Scholar 

  52. Chilton, J. M.: Anal. Chem. 25, 1274 (1953)

    Article  CAS  Google Scholar 

  53. Chilton, J. M.: Ibid. 26, 940 (1595).

    Google Scholar 

  54. Barnes, R. B., V. Z. Williams, A. R. Davis, and P. Giesecke: Ind. Eng. Chem., Anal. Ed., 16, 9 (1944)

    Google Scholar 

  55. Barnes, R. B., V. Z. Williams, A. R. Davis, and P. Giesecke: Rubber Chem. Tech., 17, 253 ( 1944

    Article  Google Scholar 

  56. Barnes, R. B., V. Z. Williams, A. R. Davis, and P. Giesecke: Rubber Chem. Tech. 17, 757 (1944).

    Article  CAS  Google Scholar 

  57. Sheppard, N., and G. B. B. M. Sutherland: Trans. Faraday Soc., 41, 261 (1945)

    Article  CAS  Google Scholar 

  58. Sheppard, N., and G. B. B. M. Sutherland: Rubber Chem. Tech. 19, 66 (1946).

    Article  CAS  Google Scholar 

  59. Dinsmore, H. L., and D. C. Smith: Anal. Chem. 20, 11 (1948).

    Article  CAS  Google Scholar 

  60. Field, J. E., D. E. Woodford, and S. D. German: Jour. Applied Physics, 17, 386 (1946)

    Article  CAS  Google Scholar 

  61. Field, J. E., D. E. Woodford, and S. D. German: Rubber Chem. Tech. 19, 1113 (1946).

    Article  Google Scholar 

  62. Hendricks, S. B., S. G. Wildman, and E. J. Jones: Arch. of Biochem. 7, 427 (1945)

    CAS  Google Scholar 

  63. Hendricks, S. B., S. G. Wildman, and E. J. Jones: Rubber Chem. Tech. 19, 501 (1946).

    Article  CAS  Google Scholar 

  64. Troussier, M.: Rev. gen. Caoutchouc 32, 229 (1955)

    CAS  Google Scholar 

  65. Troussier, M.: Rubber Chem. Technol. 29, 302 (1956).

    Article  CAS  Google Scholar 

  66. Binder, J. L.: Anal. Chem. 26, 1877 (1954).

    Article  CAS  Google Scholar 

  67. Hart, E. J., and A. W. Meyer: Jour. A.C.S. 71, 1980 (1949)

    Google Scholar 

  68. Hart, E. J., and A. W. Meyer: Rubber Chem. Tech. 23, 98 (1950).

    Article  Google Scholar 

  69. Nielsen, L. E., R. Buchdahl, and G. C. Claver: Ind. Eng. Chem., 43, 341 (1951)

    Article  CAS  Google Scholar 

  70. Nielsen, L. E., R. Buchdahl, and G. C. Claver: Rubber Chem. Techn. 24, 574 (1951).

    Article  Google Scholar 

  71. Allirot, R., and L. Orsini: Revue gen. Caoutchouc, 30, 42 (1953)

    Google Scholar 

  72. Allirot, R., and L. Orsini: Rubber Chem. Tech. 26, 411 (1953).

    Article  CAS  Google Scholar 

  73. Harms, D. L.: Anal. Chem. 25, 1140 (1953).

    Article  CAS  Google Scholar 

  74. Kruse, P. F., Jr., W. B. W.llace’ Anal. Chem. 25, 1156 (1953).

    Google Scholar 

  75. Straits, S., and Madorsky: Ind. Eng. Chem. 48, 1212 (1956).

    Article  Google Scholar 

  76. Sheppard, N., and G. B. M. Sutherland: Jour. of Chem. Soc., 1699 (1947)

    Google Scholar 

  77. Sheppard, N., and G. B. M. Sutherland: Rubber Chem. Tech. 21, 799 (1948).

    Article  CAS  Google Scholar 

  78. Kress, K. E.: to be published in Anal. Chem.

    Google Scholar 

  79. Tryon, M., E. Horowitz, and J. Mandel: Jour Research, Natl. Bur. Standards 55, 219 (1955).

    Article  CAS  Google Scholar 

  80. Thompson, H. W., and P. Torrington: Trans. Faraday Soc. 41, 246 (1945)

    Article  CAS  Google Scholar 

  81. Thompson, H. W., and P. Torrington: Rubber Chem. Techn. 19, 46 (1946).

    Article  CAS  Google Scholar 

  82. Barnes, R. B., H. Liddel, and V. Z. Williams: Ind. Eng. Chem., Anal. Ed. 15, 83 (1943)

    Google Scholar 

  83. Barnes, R. B., H. Liddel, and V. Z. Williams: Rubber Chem. Tech. 16, 634 (1943).

    Article  Google Scholar 

  84. Salomon, G., and A. C. Van Der Schee: Jour. Polymer Sci. 14, 287 (1954)

    Article  CAS  Google Scholar 

  85. Salomon, G., and A. C. Van Der Schee: Rubber Chem. Tech. 28, 224 (1955).

    Article  CAS  Google Scholar 

  86. Jones, R. V., C. W. Moberly, and W. B. Reynolds: Ind. Eng. Chem. 45, 1117 (1953)

    Article  CAS  Google Scholar 

  87. Jones, R. V., C. W. Moberly, and W. B. Reynolds: Rubber Chem. Tech. 27, 74 (1954).

    Article  Google Scholar 

  88. Stair, R., and W. W. Coblentz: Jour. Research Natl. Bur. Standards 15, 295 (1935).

    Article  CAS  Google Scholar 

  89. Bentley, F. F., and G. Rapparort: Anal. Chem. 26, 1980 (1954).

    Google Scholar 

  90. Mann, J.: Trans. Inst. Rubber Ind. 27, 232 (1951)

    CAS  Google Scholar 

  91. Mann, J.: Rubber Chem. Tech. 25, 350 (1952).

    Article  CAS  Google Scholar 

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  1. K. E. Kress
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Kress, K.E. (1960). Absorption Spectroscopy as an Analytical Method in Rubber Chemistry. In: Methoden zur Chemischen Analyse von Gummimischungen. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-12487-1_5

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  • DOI: https://doi.org/10.1007/978-3-662-12487-1_5

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-662-12488-8

  • Online ISBN: 978-3-662-12487-1

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