Abstract
Excitation dynamics in molecular crystals have much in common with excitation dynamics of ionic crystals and glasses. While the optical spectroscopy of the electronic centers in solids (Chap. 1) was treated for both ionic and molecular solids in a unified way, the review of the excitation dynamics in this chapter has to be compared with somewhat parallel reviews dealing predominantly with inorganic solids (Chaps. 2-6). This is done partly for pragmatic reasons and partly in view of the unique opportunities afforded by the study of molecular crystals. In isotopic substituted molecular crystals one has essentially “perfect randomness” in the substitutional composition, as well as minimal effects due to local heterogeneities. Thus, such studies may be the best proving grounds for the testing of theoretical concepts. Also, the ease of excitation fusion in such crystals provides clear-cut criteria for the testing of long-range excitation transport in undoped crystals.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsPreview
Unable to display preview. Download preview PDF.
References
See for example: W.H. Flygare: Molecular Structure and Dynamics (Prentice-Hall, Englewood Cliffs, N.J. 1978 ) p. 105
F. Urbach: Phys. Rev. 92, 1324 (1953)
Y. Toyozawa: Prog. Theor. Phys. 20, 53 (1958)
R. Kubo in: Fluctuation, Relaxation and Resonance in Magnetic Systems, ed. by D. ter Haar ( Oliver and Boyd, Edinburgh 1965 )
H. Sumi: J. Phys. Soc. Jpn. 32, 616 (1972)
S. Fisher, S. Rice: J. Chem. Phys. 52, 2089 (1970)
M.K. Grover, R. Silbey: J. Chem. Phys. 52, 2099 (1970)
D.P. Craig, L.A. Dissado: Chem. Phys. 14, 89 (1976)
J. Klafter, J. Jortner: Chem. Phys. Lett. 50, 202 (1977)
G.C. Morris, M.G. Sceats: Chem. Phys. 3, 342 (1974)
C.B. Harris: Chem. Phys. Lett. 52, 5 (1977); J. Chem. Phys. 67, 5607 (1977)
R. Kubo, K. Tomita: J. Phys. Soc. Jpn. 9, 888 (1954)
P.W. Anderson: J. Phys. Soc. Jpn. 9, 316 (1954)
S.L. Robinette, G.J. Small, S.H. Stevenson: J. Chem. Phys. 68, 4790 (1978)
J.J. Hopfield: Phys. Rev. 112, 1555 (1958)
S.L. Robinette, G.J. Small: J. Chem. Phys. 65, 837 (1976)
A.H. Francis, C.B. Harris: Chem. Phys. Lett. 9, 181 (1971)
A.H. Zewail, C.B. Harris: Chem. Phys. Lett. 28, 8 (1974)
D.M. Burland, D.E. Cooper, M.D. Fayer, C.R. Gochanour: Chem. Phys. Lett. 52, 279 (1977)
A.H. Francis, C.B. Harris: Chem. Phys. Lett. 9, 188 (1971)
D.D. Dlott, M.D. Fayer: Chem. Phys. Lett. 41, 305 (1976)
D.M. Burland: J. Chem. Phys. 59, 4283 (1973)
D.M. Burland, R.M. Macfarlane: J. Lumin. 12/13, 213 (1976)
D.M. Burland, U. Konzelmann, R.M. Macfarlane: J. Chem. Phys. 67, 1926 (1977)
C.B. Harris: Chem. Phys. Lett. 52, 5 (1977)
M.R. Philpott: J. Chem. Phys. 52, 5842 (1970)
G.C. Morris, M.G. Sceats: Chem. Phys. 3, 332 (1974)
T. Muto: Prog. Theor. Phys. (Kyoto) 4, 181 (1949)
K. Huang: Phys. Proc. R. Soc. (London) A204, 406 (1950)
S. Pekar: Zh. Eksp. Theo. Fiz. 20, 510 (1950)
M. Lax: J. Chem. Phys. 20, 1752 (1952)
R.C. O’Rourke: Phys. Rev. 91, 265 (1953)
T.H. Keil: Phys. Rev. A140, 601 (1965)
D.L. Dexter: Solid State Phys. 6, 353 (1958)
K.K. Rebane: Impurity Spectra of Solids ( Plenum Press, New York 1970 )
G.J. Small: J. Chem. Phys. 58, 2015 (1973)
D.E. McCumber, M.D. Sturge: J. Appl. Phys. 34, 1682 (1963)
P.H. Chereson, P.S. Friedman, R. Kopelman: J. Chem. Phys. 56, 3716 (1972)
B.H. Loo, A.H. Francis: J. Chem. Phys. 65, 5076 (1977)
B.H. Loo, A.H. Francis, K.W. Hipps: J. Chem. Phys. 65, 5068 (1976)
K.W. Hipps, A.H. Francis: J. Phys. Chem. 83, 1879 (1979)
F.P. Burke, G.J. Small: Chem. Phys. 5, 198 (1974)
G.J. Small: Chem. Phys. Lett. 57, 501 (1978)
H. de Vries, D.A. Wiersma. Chem. Phys. Lett. 51, 565 (1977)
H. de Vries, D.A. Wiersma: Phys. Rev. Lett. 36, 91 (1975)
H. Sternlicht, G.C. Nieman, G.W. Robinson: J. Chem. Phys. 38, 1326; 39, 1610 (1963)
R.E. Merrifield: Pure Appl. Chem. 27, 481 (1971)
R.G. Kepler, J.C. Caris, P. Avakian, E. Abramson: Phys. Rev. Lett. 10, 400 (1963)
P. Avakian, R.E. Merrifield: Phys. Rev. Lett. 13, 541 (1964)
V. Ern, P. Avakian, R.E. Merrifield: Phys. Rev. 148, 862 (1966)
M. Levine, J. Jortner, A. Szoke: J. Chem. Phys. 45, 1591 (1966)
V. Ern: Phys. Rev. Lett. 22, 343 (1969)
V. Ern, A. Suna, Y. Tomkiewicz, P. Avakian, R.P. Groff: Phys. Rev. B 5, 3222 (1972)
V. Ern: J. Chem. Phys. 56, 6259 (1972)
H.C. Wolf, H. Port: J. Lumin. 12/13, 33 (1976)
M. Trlifaj: Czech. J. Phys. 8, 510 (1958)
D.L. Dexter: J. Chem. Phys. 21, 836 (1953)
H. Haken, P. Reinecker: Z. Phys. 249, 253 (1972)
E. Schwarzer, H. Haken: Opt. Commun. 9, 64 (1973)
R.C. Powell, Z.G. Soos: J. Lumin. 11, 1 (1975)
A.S. Davydov: Theory of Molecular Excitons ( Plenum Press, New York 1971 )
G.W. Robinson: Ann. Rev. Phys. Chem. 21, 429 (1970)
R. Kopelman: In Excited States H, ed. by E.C. Lim ( Academic Press, New York 1975 )
R.M. Hochstrasser, P.N. Prasad: In Excited States I, ed. by E.C. Lim ( Academic Press, New York 1974 )
L. Altwegg, M.A. Davidovich, J. Funfschilling, I. Zschokke-Granacher: Phys. Rev. B 18, 4444 (1978)
L. Altwegg, M. Chabr, I Zschokke-Granacher: Phys. Rev. B. 14, 1963 (1976)
Th. Forster: Ann. Phys. 6, 55 (1948)
F. Lipsett, A. Dekker: Can. J. Phys. 30, 165 (1951)
H.C. Wolf: Z. Phys. 143, 266 (1955); 145, 116 (1956)
D.M. Hanson,G.W. Robinson: J. Chem. Phys. 43, 4174 (1965)
G. Castro, G.W. Robinson: J. Chem. Phys. 50, 1159 (1969)
E.B. Priestley, A. Haug: J. Chem. Phys. 49, 622 (1968)
K.W. Benz: Ph.D. Thesis, University of Stuttgart (1970)
P. Argyrakis: Ph.D. Thesis, University of Michigan (1979); P. Argyrakis, R. Kopelman: Chem. Phys. (in press)
H. Auweter: Ph.D. Thesis, University of Stuttgart (1978)
A. Hammer, H.C. Wolf: Mol. Cryst. 4, 191 (1968)
V.M. Agranovich, Yu. V. Konobeev: Phys. Status Solidi 27, 435 (1968)
S.L. Robinette, S.H. Stevenson, G.J. Small: J. Chem. Phys. 69, 5231 (1978)
G.C. Nieman, G.W. Robinson: J. Chem. Phys. 37, 2150 (1962)
H. Sternlicht, G.C. Nieman, G.W. Robinson: J. Chem. Phys. 38, 1326 (1963)
G.W. Robinson, R.P. Frosch: J. Chem. Phys. 38, 1187 (1963)
H-K. Hong, R. Kopelman: Phys. Rev. Lett. 25, 1030 (1970)
H-K. Hong, R. Kopelman: J. Chem. Phys. 55, 724 (1971)
F.W. Ochs: Ph.D. Thesis, University of Michigan (1974)
R. Kopelman, E.M. Monberg, F.W. Ochs: Chem. Phys. 19, 413 (1977)
E.F. Krause: Taxicab Geometry (Addison-Wesley, Menlo Park, Calif. 1975 )
F.B. Tudron, S.D. Colson: J. Chem. Phys. 65, 4184 (1976)
S.D. Colson, R.E. Turner, V. Vaida: J. Chem. Phys. 66, 2187 (1977)
R. Kopelman, E.M. Monberg, F.W. Ochs: Chem. Phys. 21, 373 (1977)
F. Perrin: C.R. Acad. Sci. 178, 1978 (1924)
H-K. Hong, R. Kopelman: J. Chem. Phys. 55, 5380 (1971)
V.L. Broude, A.V. Leiderman, T.G. Tratas: Fiz. Tverd. Tela 13, 3624 (1971)
R. Kopelman: Cambridge Conf. Molecular Energy Transfer (1971)
K.E. Mauser, H. Port, H.C. Wolf: Chem. Phys. 1, 74 (1973)
H-K. Hong, G.W. Robinson: J. Chem. Phys. 54, 1369 (1971)
H. Port, D. Vogel, H.C. Wolf: Chem. Phys. Lett. 34, 23 (1975)
C.L. Braun, H.C. Wolf: Chem. Phys. Lett. 9, 260 (1971)
R.M. Hochstrasser, J.D. Whiteman: J. Chem. Phys. 56, 5945 (1972)
D.C. Ahlgren: Ph.D. Thesis, University of Michigan (1979)
R. Kopelman, E.M. Monberg, F.W. Ochs, P.N. Prasad: J. Chem. Phys. 62, 292 (1975)
R. Kopelman, E.M. Monberg, F.W. Ochs, P.N. Prasad: Phys. Rev. Lett. 34, 1506 (1975)
R. Kopelman: In Radiationless Processes in Molecules and Condensed Phases, ed. by F.K. Fong, Topics in Applied Physics, Vol. 15 (Springer, Berlin, Heidelberg, New York 1976 ) p. 297
S.D. Colson, S.M. George, T. Keyes, V. Vaida: J. Chem. Phys. 67, 4941 (1977)
F.M. Monberg, R. Kopelman: V.L. Broude Memorial Issue, Mol. Cryst. Liq. Cryst. 57, 271 (1980)
V.K.S. Shante, S. Kirkpatrick: Adv. Phys. 20, 325 (1971)
J. Hoshen, R. Kopelman: Phys. Rev. B. 14, 3438 (1976)
J. Hoshen, R. Kopelman, E.M. Monberg: J. Stat. Phys. 19, 219 (1978)
P.W. Kasteleyn, C.M. Fortuin: J. Phys. Soc. Jpn. 26, 11 (1969)
J.Hoshen, P. Klymko, R. Kopelman: Unpublished
R. Kopelman, E.M. Monberg, J.S. Newhouse, F.W. Ochs: J. Lumin. 18/19, 41 (1979)
J.S. Newhouse, R. Kopelman: Unpublished
J. Hoshen, R. Kopelman: J. Chem. Phys. 65, 2817 (1976)
A. Sur, J.L. Lebovitz, J. Marro, M.H. Kalos, S. Kirkpatrick: J. Stat. Phys. 15, 345 (1976)
D.C. Ahlgren, E.M. Monberg, R. Kopelman: Chem. Phys. Lett. 64, 122 (1979)
E.M. Monberg: Ph.D. Thesis, University of Michigan (1977)
D.C. Ahlgren, R. Kopelman: J. Chem. Phys. 70, 3133 (1979)
D. Weaire, B. Kramer: J. Non-Cryst. Solids 32, 131 (1979)
D.J. Thouless: In Les Houches Ill-Condensed Matter, ed. by R. Balian ( North-Holland, Amsterdam 1979 ) p. 1
J. Klafter, J. Jortner: Chem. Phys. Lett. 49, 410 (1977)
J. Klafter, J. Jortner: Chem. Phys. Lett. 60, 5 (1978)
J. Klafter, J. Jortner: J. Chem. Phys. 71, 1961 (1979)
S.K. Lyo: Phys. Rev. B3, 3331 (1971)
R. Orbach: Phys. Lett. A48, 417 (1974)
S.D. Colson: Private communication (1977)
R. Kopelman: Symp. Molecular Structure and Spectroscopy, Columbus, Ohio (1967) Paper R7
S.D. Woodruff: Ph.D. Thesis, University of Michigan (1976)
E.M. Monberg, R. Kopelman, Chem. Phys. Lett. 58, 492, 497 (1978)
L. Harmon, R. Kopelman: Unpublished
P.W. Anderson: Phys. Rev. 109, 1492 (1958)
D.D. Smith, R.D. Mead, A.H. Zewail: Chem. Phys. Lett. 50, 358 (1977)
H. Port: Private communication (June 1979)
D. Burland, A.H. Zewail: Adv. Chem. Phys. 40, 369 (1979)
E.W. Montroll: J. Math. Phys. 10, 753 (1969)
S. Chandrasekhar: Rev. Mod. Phys. 15, 1 (1943)
K. Lakatos-Lindenberg, K.E. Shuler: J. Math. Phys. 12, 633 (1971)
P. Argyrakis, R. Kopelman: J. Chem. Phys. 66, 3301 (1977)
P. Argyrakis, R. Kopelman. Chem. Phys. Lett. 61, 187 (1979)
G.J. Small: Private communication (June 1979). See also ref. [7.72]
P.N. Prasad, R. Kopelman: J. Chem. Phys. 57, 863 (1972)
R. Kopelman: J. Phys. Chem. 80, 2191 (1976)
J.C. Laufer, R. Kopelman: J. Chem. Phys. 57, 3202 (1972)
S.T. Gentry, R.Kopelman: (Unpublished)
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1981 Springer-Verlag Berlin Heidelberg
About this chapter
Cite this chapter
Francis, A.H., Kopelman, R. (1981). Excitation Dynamics in Molecular Solids. In: Yen, W.M., Selzer, P.M. (eds) Laser Spectroscopy of Solids. Topics in Applied Physics, vol 49. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-12213-6_7
Download citation
DOI: https://doi.org/10.1007/978-3-662-12213-6_7
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-662-12215-0
Online ISBN: 978-3-662-12213-6
eBook Packages: Springer Book Archive