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Excitation Dynamics in Molecular Solids

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Part of the book series: Topics in Applied Physics ((TAP,volume 49))

Abstract

Excitation dynamics in molecular crystals have much in common with excitation dynamics of ionic crystals and glasses. While the optical spectroscopy of the electronic centers in solids (Chap. 1) was treated for both ionic and molecular solids in a unified way, the review of the excitation dynamics in this chapter has to be compared with somewhat parallel reviews dealing predominantly with inorganic solids (Chaps. 2-6). This is done partly for pragmatic reasons and partly in view of the unique opportunities afforded by the study of molecular crystals. In isotopic substituted molecular crystals one has essentially “perfect randomness” in the substitutional composition, as well as minimal effects due to local heterogeneities. Thus, such studies may be the best proving grounds for the testing of theoretical concepts. Also, the ease of excitation fusion in such crystals provides clear-cut criteria for the testing of long-range excitation transport in undoped crystals.

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References

  1. See for example: W.H. Flygare: Molecular Structure and Dynamics (Prentice-Hall, Englewood Cliffs, N.J. 1978 ) p. 105

    Google Scholar 

  2. F. Urbach: Phys. Rev. 92, 1324 (1953)

    ADS  Google Scholar 

  3. Y. Toyozawa: Prog. Theor. Phys. 20, 53 (1958)

    ADS  MATH  Google Scholar 

  4. R. Kubo in: Fluctuation, Relaxation and Resonance in Magnetic Systems, ed. by D. ter Haar ( Oliver and Boyd, Edinburgh 1965 )

    Google Scholar 

  5. H. Sumi: J. Phys. Soc. Jpn. 32, 616 (1972)

    ADS  Google Scholar 

  6. S. Fisher, S. Rice: J. Chem. Phys. 52, 2089 (1970)

    ADS  Google Scholar 

  7. M.K. Grover, R. Silbey: J. Chem. Phys. 52, 2099 (1970)

    ADS  Google Scholar 

  8. D.P. Craig, L.A. Dissado: Chem. Phys. 14, 89 (1976)

    ADS  Google Scholar 

  9. J. Klafter, J. Jortner: Chem. Phys. Lett. 50, 202 (1977)

    ADS  Google Scholar 

  10. G.C. Morris, M.G. Sceats: Chem. Phys. 3, 342 (1974)

    ADS  Google Scholar 

  11. C.B. Harris: Chem. Phys. Lett. 52, 5 (1977); J. Chem. Phys. 67, 5607 (1977)

    ADS  Google Scholar 

  12. R. Kubo, K. Tomita: J. Phys. Soc. Jpn. 9, 888 (1954)

    ADS  Google Scholar 

  13. P.W. Anderson: J. Phys. Soc. Jpn. 9, 316 (1954)

    ADS  Google Scholar 

  14. S.L. Robinette, G.J. Small, S.H. Stevenson: J. Chem. Phys. 68, 4790 (1978)

    ADS  Google Scholar 

  15. J.J. Hopfield: Phys. Rev. 112, 1555 (1958)

    ADS  MATH  Google Scholar 

  16. S.L. Robinette, G.J. Small: J. Chem. Phys. 65, 837 (1976)

    ADS  Google Scholar 

  17. A.H. Francis, C.B. Harris: Chem. Phys. Lett. 9, 181 (1971)

    ADS  Google Scholar 

  18. A.H. Zewail, C.B. Harris: Chem. Phys. Lett. 28, 8 (1974)

    ADS  Google Scholar 

  19. D.M. Burland, D.E. Cooper, M.D. Fayer, C.R. Gochanour: Chem. Phys. Lett. 52, 279 (1977)

    ADS  Google Scholar 

  20. A.H. Francis, C.B. Harris: Chem. Phys. Lett. 9, 188 (1971)

    ADS  Google Scholar 

  21. D.D. Dlott, M.D. Fayer: Chem. Phys. Lett. 41, 305 (1976)

    ADS  Google Scholar 

  22. D.M. Burland: J. Chem. Phys. 59, 4283 (1973)

    ADS  Google Scholar 

  23. D.M. Burland, R.M. Macfarlane: J. Lumin. 12/13, 213 (1976)

    Google Scholar 

  24. D.M. Burland, U. Konzelmann, R.M. Macfarlane: J. Chem. Phys. 67, 1926 (1977)

    ADS  Google Scholar 

  25. C.B. Harris: Chem. Phys. Lett. 52, 5 (1977)

    ADS  Google Scholar 

  26. M.R. Philpott: J. Chem. Phys. 52, 5842 (1970)

    ADS  Google Scholar 

  27. G.C. Morris, M.G. Sceats: Chem. Phys. 3, 332 (1974)

    ADS  Google Scholar 

  28. T. Muto: Prog. Theor. Phys. (Kyoto) 4, 181 (1949)

    ADS  MathSciNet  Google Scholar 

  29. K. Huang: Phys. Proc. R. Soc. (London) A204, 406 (1950)

    ADS  MATH  Google Scholar 

  30. S. Pekar: Zh. Eksp. Theo. Fiz. 20, 510 (1950)

    Google Scholar 

  31. M. Lax: J. Chem. Phys. 20, 1752 (1952)

    ADS  MathSciNet  Google Scholar 

  32. R.C. O’Rourke: Phys. Rev. 91, 265 (1953)

    ADS  MATH  Google Scholar 

  33. T.H. Keil: Phys. Rev. A140, 601 (1965)

    ADS  Google Scholar 

  34. D.L. Dexter: Solid State Phys. 6, 353 (1958)

    Google Scholar 

  35. K.K. Rebane: Impurity Spectra of Solids ( Plenum Press, New York 1970 )

    Google Scholar 

  36. G.J. Small: J. Chem. Phys. 58, 2015 (1973)

    ADS  Google Scholar 

  37. D.E. McCumber, M.D. Sturge: J. Appl. Phys. 34, 1682 (1963)

    ADS  Google Scholar 

  38. P.H. Chereson, P.S. Friedman, R. Kopelman: J. Chem. Phys. 56, 3716 (1972)

    ADS  Google Scholar 

  39. B.H. Loo, A.H. Francis: J. Chem. Phys. 65, 5076 (1977)

    ADS  Google Scholar 

  40. B.H. Loo, A.H. Francis, K.W. Hipps: J. Chem. Phys. 65, 5068 (1976)

    ADS  Google Scholar 

  41. K.W. Hipps, A.H. Francis: J. Phys. Chem. 83, 1879 (1979)

    Google Scholar 

  42. F.P. Burke, G.J. Small: Chem. Phys. 5, 198 (1974)

    ADS  Google Scholar 

  43. G.J. Small: Chem. Phys. Lett. 57, 501 (1978)

    ADS  Google Scholar 

  44. H. de Vries, D.A. Wiersma. Chem. Phys. Lett. 51, 565 (1977)

    ADS  Google Scholar 

  45. H. de Vries, D.A. Wiersma: Phys. Rev. Lett. 36, 91 (1975)

    Google Scholar 

  46. H. Sternlicht, G.C. Nieman, G.W. Robinson: J. Chem. Phys. 38, 1326; 39, 1610 (1963)

    Google Scholar 

  47. R.E. Merrifield: Pure Appl. Chem. 27, 481 (1971)

    Google Scholar 

  48. R.G. Kepler, J.C. Caris, P. Avakian, E. Abramson: Phys. Rev. Lett. 10, 400 (1963)

    ADS  Google Scholar 

  49. P. Avakian, R.E. Merrifield: Phys. Rev. Lett. 13, 541 (1964)

    ADS  Google Scholar 

  50. V. Ern, P. Avakian, R.E. Merrifield: Phys. Rev. 148, 862 (1966)

    ADS  Google Scholar 

  51. M. Levine, J. Jortner, A. Szoke: J. Chem. Phys. 45, 1591 (1966)

    ADS  Google Scholar 

  52. V. Ern: Phys. Rev. Lett. 22, 343 (1969)

    ADS  Google Scholar 

  53. V. Ern, A. Suna, Y. Tomkiewicz, P. Avakian, R.P. Groff: Phys. Rev. B 5, 3222 (1972)

    ADS  Google Scholar 

  54. V. Ern: J. Chem. Phys. 56, 6259 (1972)

    ADS  Google Scholar 

  55. H.C. Wolf, H. Port: J. Lumin. 12/13, 33 (1976)

    Google Scholar 

  56. M. Trlifaj: Czech. J. Phys. 8, 510 (1958)

    ADS  MathSciNet  Google Scholar 

  57. D.L. Dexter: J. Chem. Phys. 21, 836 (1953)

    ADS  Google Scholar 

  58. H. Haken, P. Reinecker: Z. Phys. 249, 253 (1972)

    ADS  Google Scholar 

  59. E. Schwarzer, H. Haken: Opt. Commun. 9, 64 (1973)

    ADS  Google Scholar 

  60. R.C. Powell, Z.G. Soos: J. Lumin. 11, 1 (1975)

    Google Scholar 

  61. A.S. Davydov: Theory of Molecular Excitons ( Plenum Press, New York 1971 )

    Google Scholar 

  62. G.W. Robinson: Ann. Rev. Phys. Chem. 21, 429 (1970)

    ADS  Google Scholar 

  63. R. Kopelman: In Excited States H, ed. by E.C. Lim ( Academic Press, New York 1975 )

    Google Scholar 

  64. R.M. Hochstrasser, P.N. Prasad: In Excited States I, ed. by E.C. Lim ( Academic Press, New York 1974 )

    Google Scholar 

  65. L. Altwegg, M.A. Davidovich, J. Funfschilling, I. Zschokke-Granacher: Phys. Rev. B 18, 4444 (1978)

    ADS  Google Scholar 

  66. L. Altwegg, M. Chabr, I Zschokke-Granacher: Phys. Rev. B. 14, 1963 (1976)

    ADS  Google Scholar 

  67. Th. Forster: Ann. Phys. 6, 55 (1948)

    Google Scholar 

  68. F. Lipsett, A. Dekker: Can. J. Phys. 30, 165 (1951)

    Google Scholar 

  69. H.C. Wolf: Z. Phys. 143, 266 (1955); 145, 116 (1956)

    Google Scholar 

  70. D.M. Hanson,G.W. Robinson: J. Chem. Phys. 43, 4174 (1965)

    ADS  Google Scholar 

  71. G. Castro, G.W. Robinson: J. Chem. Phys. 50, 1159 (1969)

    ADS  Google Scholar 

  72. E.B. Priestley, A. Haug: J. Chem. Phys. 49, 622 (1968)

    ADS  Google Scholar 

  73. K.W. Benz: Ph.D. Thesis, University of Stuttgart (1970)

    Google Scholar 

  74. P. Argyrakis: Ph.D. Thesis, University of Michigan (1979); P. Argyrakis, R. Kopelman: Chem. Phys. (in press)

    Google Scholar 

  75. H. Auweter: Ph.D. Thesis, University of Stuttgart (1978)

    Google Scholar 

  76. A. Hammer, H.C. Wolf: Mol. Cryst. 4, 191 (1968)

    Google Scholar 

  77. V.M. Agranovich, Yu. V. Konobeev: Phys. Status Solidi 27, 435 (1968)

    Google Scholar 

  78. S.L. Robinette, S.H. Stevenson, G.J. Small: J. Chem. Phys. 69, 5231 (1978)

    ADS  Google Scholar 

  79. G.C. Nieman, G.W. Robinson: J. Chem. Phys. 37, 2150 (1962)

    ADS  Google Scholar 

  80. H. Sternlicht, G.C. Nieman, G.W. Robinson: J. Chem. Phys. 38, 1326 (1963)

    ADS  Google Scholar 

  81. G.W. Robinson, R.P. Frosch: J. Chem. Phys. 38, 1187 (1963)

    ADS  Google Scholar 

  82. H-K. Hong, R. Kopelman: Phys. Rev. Lett. 25, 1030 (1970)

    ADS  Google Scholar 

  83. H-K. Hong, R. Kopelman: J. Chem. Phys. 55, 724 (1971)

    ADS  Google Scholar 

  84. F.W. Ochs: Ph.D. Thesis, University of Michigan (1974)

    Google Scholar 

  85. R. Kopelman, E.M. Monberg, F.W. Ochs: Chem. Phys. 19, 413 (1977)

    Google Scholar 

  86. E.F. Krause: Taxicab Geometry (Addison-Wesley, Menlo Park, Calif. 1975 )

    Google Scholar 

  87. F.B. Tudron, S.D. Colson: J. Chem. Phys. 65, 4184 (1976)

    ADS  Google Scholar 

  88. S.D. Colson, R.E. Turner, V. Vaida: J. Chem. Phys. 66, 2187 (1977)

    ADS  Google Scholar 

  89. R. Kopelman, E.M. Monberg, F.W. Ochs: Chem. Phys. 21, 373 (1977)

    Google Scholar 

  90. F. Perrin: C.R. Acad. Sci. 178, 1978 (1924)

    Google Scholar 

  91. H-K. Hong, R. Kopelman: J. Chem. Phys. 55, 5380 (1971)

    ADS  Google Scholar 

  92. V.L. Broude, A.V. Leiderman, T.G. Tratas: Fiz. Tverd. Tela 13, 3624 (1971)

    Google Scholar 

  93. R. Kopelman: Cambridge Conf. Molecular Energy Transfer (1971)

    Google Scholar 

  94. K.E. Mauser, H. Port, H.C. Wolf: Chem. Phys. 1, 74 (1973)

    Google Scholar 

  95. H-K. Hong, G.W. Robinson: J. Chem. Phys. 54, 1369 (1971)

    ADS  Google Scholar 

  96. H. Port, D. Vogel, H.C. Wolf: Chem. Phys. Lett. 34, 23 (1975)

    ADS  Google Scholar 

  97. C.L. Braun, H.C. Wolf: Chem. Phys. Lett. 9, 260 (1971)

    ADS  Google Scholar 

  98. R.M. Hochstrasser, J.D. Whiteman: J. Chem. Phys. 56, 5945 (1972)

    ADS  Google Scholar 

  99. D.C. Ahlgren: Ph.D. Thesis, University of Michigan (1979)

    Google Scholar 

  100. R. Kopelman, E.M. Monberg, F.W. Ochs, P.N. Prasad: J. Chem. Phys. 62, 292 (1975)

    ADS  Google Scholar 

  101. R. Kopelman, E.M. Monberg, F.W. Ochs, P.N. Prasad: Phys. Rev. Lett. 34, 1506 (1975)

    ADS  Google Scholar 

  102. R. Kopelman: In Radiationless Processes in Molecules and Condensed Phases, ed. by F.K. Fong, Topics in Applied Physics, Vol. 15 (Springer, Berlin, Heidelberg, New York 1976 ) p. 297

    Google Scholar 

  103. S.D. Colson, S.M. George, T. Keyes, V. Vaida: J. Chem. Phys. 67, 4941 (1977)

    ADS  Google Scholar 

  104. F.M. Monberg, R. Kopelman: V.L. Broude Memorial Issue, Mol. Cryst. Liq. Cryst. 57, 271 (1980)

    Google Scholar 

  105. V.K.S. Shante, S. Kirkpatrick: Adv. Phys. 20, 325 (1971)

    ADS  Google Scholar 

  106. J. Hoshen, R. Kopelman: Phys. Rev. B. 14, 3438 (1976)

    ADS  Google Scholar 

  107. J. Hoshen, R. Kopelman, E.M. Monberg: J. Stat. Phys. 19, 219 (1978)

    ADS  Google Scholar 

  108. P.W. Kasteleyn, C.M. Fortuin: J. Phys. Soc. Jpn. 26, 11 (1969)

    ADS  Google Scholar 

  109. J.Hoshen, P. Klymko, R. Kopelman: Unpublished

    Google Scholar 

  110. R. Kopelman, E.M. Monberg, J.S. Newhouse, F.W. Ochs: J. Lumin. 18/19, 41 (1979)

    Google Scholar 

  111. J.S. Newhouse, R. Kopelman: Unpublished

    Google Scholar 

  112. J. Hoshen, R. Kopelman: J. Chem. Phys. 65, 2817 (1976)

    ADS  Google Scholar 

  113. A. Sur, J.L. Lebovitz, J. Marro, M.H. Kalos, S. Kirkpatrick: J. Stat. Phys. 15, 345 (1976)

    ADS  Google Scholar 

  114. D.C. Ahlgren, E.M. Monberg, R. Kopelman: Chem. Phys. Lett. 64, 122 (1979)

    ADS  Google Scholar 

  115. E.M. Monberg: Ph.D. Thesis, University of Michigan (1977)

    Google Scholar 

  116. D.C. Ahlgren, R. Kopelman: J. Chem. Phys. 70, 3133 (1979)

    ADS  Google Scholar 

  117. D. Weaire, B. Kramer: J. Non-Cryst. Solids 32, 131 (1979)

    ADS  Google Scholar 

  118. D.J. Thouless: In Les Houches Ill-Condensed Matter, ed. by R. Balian ( North-Holland, Amsterdam 1979 ) p. 1

    Google Scholar 

  119. J. Klafter, J. Jortner: Chem. Phys. Lett. 49, 410 (1977)

    ADS  Google Scholar 

  120. J. Klafter, J. Jortner: Chem. Phys. Lett. 60, 5 (1978)

    ADS  Google Scholar 

  121. J. Klafter, J. Jortner: J. Chem. Phys. 71, 1961 (1979)

    ADS  Google Scholar 

  122. S.K. Lyo: Phys. Rev. B3, 3331 (1971)

    ADS  Google Scholar 

  123. R. Orbach: Phys. Lett. A48, 417 (1974)

    Google Scholar 

  124. S.D. Colson: Private communication (1977)

    Google Scholar 

  125. R. Kopelman: Symp. Molecular Structure and Spectroscopy, Columbus, Ohio (1967) Paper R7

    Google Scholar 

  126. S.D. Woodruff: Ph.D. Thesis, University of Michigan (1976)

    Google Scholar 

  127. E.M. Monberg, R. Kopelman, Chem. Phys. Lett. 58, 492, 497 (1978)

    ADS  Google Scholar 

  128. L. Harmon, R. Kopelman: Unpublished

    Google Scholar 

  129. P.W. Anderson: Phys. Rev. 109, 1492 (1958)

    ADS  Google Scholar 

  130. D.D. Smith, R.D. Mead, A.H. Zewail: Chem. Phys. Lett. 50, 358 (1977)

    ADS  Google Scholar 

  131. H. Port: Private communication (June 1979)

    Google Scholar 

  132. D. Burland, A.H. Zewail: Adv. Chem. Phys. 40, 369 (1979)

    Google Scholar 

  133. E.W. Montroll: J. Math. Phys. 10, 753 (1969)

    ADS  Google Scholar 

  134. S. Chandrasekhar: Rev. Mod. Phys. 15, 1 (1943)

    ADS  MATH  MathSciNet  Google Scholar 

  135. K. Lakatos-Lindenberg, K.E. Shuler: J. Math. Phys. 12, 633 (1971)

    ADS  MATH  MathSciNet  Google Scholar 

  136. P. Argyrakis, R. Kopelman: J. Chem. Phys. 66, 3301 (1977)

    ADS  Google Scholar 

  137. P. Argyrakis, R. Kopelman. Chem. Phys. Lett. 61, 187 (1979)

    ADS  Google Scholar 

  138. G.J. Small: Private communication (June 1979). See also ref. [7.72]

    Google Scholar 

  139. P.N. Prasad, R. Kopelman: J. Chem. Phys. 57, 863 (1972)

    ADS  Google Scholar 

  140. R. Kopelman: J. Phys. Chem. 80, 2191 (1976)

    Google Scholar 

  141. J.C. Laufer, R. Kopelman: J. Chem. Phys. 57, 3202 (1972)

    ADS  Google Scholar 

  142. S.T. Gentry, R.Kopelman: (Unpublished)

    Google Scholar 

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Francis, A.H., Kopelman, R. (1981). Excitation Dynamics in Molecular Solids. In: Yen, W.M., Selzer, P.M. (eds) Laser Spectroscopy of Solids. Topics in Applied Physics, vol 49. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-12213-6_7

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