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Palladium and Boron

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Pd Palladium

Part of the book series: Gmelin Handbook of Inorganic Chemistry / Gmelin Handbuch der Anorganischen Chemie ((2043,volume P-d / B / 2))

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Abstract

Differential thermal analysis, metallographic analysis and X-ray analysis have been used to establish phase data of the binary Pd-B system over the temperature range 500 to 1600°C. Isothermal reaction data are collected in the table below. Compounds formed are Pd4B, Pd3B, Pd5B2 and Pd2B. Each melts to form a liquid phase which extends to approximately PdB0.57 at 1237 K whereupon solid boron forms. Solid palladium dissolves in boron to give a saturated composition near PdB0.25 [1].

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Author information

Authors and Affiliations

  1. Imperial College of Science and Technology, London, Great Britain

    William P. Griffith

  2. Kings College, London, Great Britain

    Stephen D. Robinson

  3. Gelnhausen, Bundesrepublik Deutschland

    Kurt Swars

Authors
  1. William P. Griffith
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  2. Stephen D. Robinson
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  3. Kurt Swars
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Editor information

Editors and Affiliations

  1. Imperial College of Science and Technology, London, Great Britain

    William P. Griffith

  2. Gelnhausen, Bundesrepublik Deutschland

    Kurt Swars

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© 1989 Springer-Verlag Berlin Heidelberg

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Griffith, W.P., Robinson, S.D., Swars, K. (1989). Palladium and Boron. In: Griffith, W.P., Swars, K. (eds) Pd Palladium. Gmelin Handbook of Inorganic Chemistry / Gmelin Handbuch der Anorganischen Chemie, vol P-d / B / 2. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-09188-3_10

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  • DOI: https://doi.org/10.1007/978-3-662-09188-3_10

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-662-09190-6

  • Online ISBN: 978-3-662-09188-3

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