Abstract
In melts like alkali halides the acidic oxide MoO3 likewise tends to become an acid. It reacts either with O2- to form an oxo anion, be it monomeric (MoO 2-4 ), dimeric, trimeric, etc., or it reacts with the “basic” solvent [1]. The basicity of the monomolybdate anion in any case can be described in terms of the solvent [2]. The melt substantially affects the 0-containing anions. For a comparative discussion regarding nitrate and chloride melts as well as 0-containing anions of Cr, Mo, and W, see [3].
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Tytko, KH., Gras, D. (1988). Oxomolybdenum Species in Melts. In: Katscher, H., Schröder, F. (eds) Oxomolybdenum Species in Aqueous Solutions (Continued). Oxomolybdenum Species in Nonaqueous Solvents. Oxomolybdenum Species in Melts. Peroxomolybdenum Species. Mo. Molybdän. Molybdenum (System-Nr. 53), vol M-o / A-B / B / 3 / b. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-09171-5_8
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