Zusammenfassung
Im vorigen Kapitel wurden durchstimmbare Laser für die verschiedenen Spektralgebiete vorgestellt. Nun wollen wir uns der Anwendung dieser Laser in der Spektroskopie zuwenden. Dabei sollen zuerst solche Methoden behandelt werden, bei denen die spektrale Auflösung prinzipiell begrenzt ist durch die Linienbreiten der molekularen Übergänge. Diese Auflösungsgrenze wird auch tatsächlich erreicht, wenn die Frequenzbreite der Lichtquelle schmal ist gegenüber der Halbwertsbreite der Absorptionslinien. Da im allgemeinen im gasförmigen Zustand das Linienprofil molekularer Übergänge durch die Doppler-Breite bestimmt wird, spricht man bei diesen Methoden auch von Doppler-begrenzter Laser Spektroskopie.
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Demtröder, W. (1991). Doppler-begrenzte Absorptions- und Fluoreszenz- Spektroskopie mit Lasern. In: Laserspektroskopie. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-08270-6_6
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