Zusammenfassung
Die Raman-Spektroskopie ist seit vielen Jahren eine wichtige Methode zur Untersuchung molekularer Schwingungen. Da die Wirkungsquerschnitte für die nichtresonante Raman-Streuung jedoch im allgemeinen um mehrere Größenordnungen kleiner sind als die für Resonanzfluoreszenz, war vor dem Einsatz von Lasern die geringe Intensität der Streustrahlung oft der begrenzende Faktor für ihre Anwendung. Dies hat sich gründlich geändert, seitdem leistungsstarke Laser als intensive Lichtquellen zur Verfügung stehen, die nicht nur die spontane, lineare Raman-Spektroskopie sehr intensiviert, sondern auch ganz neue Techniken ermöglicht haben, die auf der nichtlinearen Wechselwirkung der Moleküle mit der einfallenden Lichtwelle beruhen, wie z.B. die stimulierte Raman-Streuung, die Entwicklung von Raman-Lasern (Abschn.5.7.6), die kohärente Anti-Stokes Raman-Streuung (CARS), oder die Hyper-Raman-Spektroskopie.
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Demtröder, W. (1993). Laser-Raman Spektroskopie. In: Laserspektroskopie. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-08268-3_8
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