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Laser-Raman-Spektroskopie

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Laserspektroskopie

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Zusammenfassung

Die Raman-Spektroskopie ist seit vielen Jahren eine wichtige Methode zur Untersuchung molekularer Schwingungen. Da die Wirkungsquerschnitte für die nichtresonante Raman-Streuung jedoch im allgemeinen um mehrere Größenordnungen kleiner (bis zu 108 mal) sind als die für Resonanzfluoreszenz, war für ihre Anwendung vor dem Einsatz von Lasern die geringe Intensität der Streustrahlung oft der begrenzende Faktor. Dies hat sich gründlich geändert, seitdem leistungsstarke Laser als intensive Lichtquellen zur Verfügung stehen, die nicht nur die spontane, lineare Raman-Spektroskopie sehr intensiviert sondern auch ganz neue Techniken ermöglicht haben, die auf der nichtlinearen Wechselwirkung der Moleküle mit der einfallenden Lichtwelle beruhen wie z.B. die stimulierte Raman-Streuung, die Entwicklung von Raman-Lasern (Abschn.5.7.6), die kohärente Anti-Stokes Raman-Streuung (CARS), oder die Hyper-Raman-Spektroskopie. Auch die Detektionsverfahren sind wesentlich erweitert worden, so daß ein empfindlicher Nachweis möglich wurde.

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Authors and Affiliations

  1. Fachbereich Physik, Universität Kaiserslautern, Erwin-Schrödinger-Straße, 67663, Kaiserslautern, Deutschland

    Professor Dr. Wolfgang Demtröder

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  1. Professor Dr. Wolfgang Demtröder
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Demtröder, W. (2000). Laser-Raman-Spektroskopie. In: Laserspektroskopie. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-08266-9_8

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  • DOI: https://doi.org/10.1007/978-3-662-08266-9_8

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-662-08267-6

  • Online ISBN: 978-3-662-08266-9

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