Skip to main content
SpringerLink
Log in
Book cover

Ga Organogallium Compounds pp 421–428Cite as

Low-Valence Organogallium Compounds

  • Chapter

  • 140 Accesses

Part of the book series: Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition ((1033,volume G-a / 1- / 1))

Abstract

Products of the reaction of Ga(CH2Si(CH3)3)3 with alkali metal hydrides were originally reported to be of the M[Ga(CH2Si(CH3)3)2] type, including a few adducts, and were believed to arise from reductive elimination of Si(CH3)4 from M[Ga(CH2Si(CH3)3)3H] intermediates [1]. But these results could not be reproduced later, and the products were identified as alkali metal compounds of the hydrido anion [Ga(CH2Si(CH3)3)3H]- [2]; see 13.2, p. 320.

This is a preview of subscription content, log in via an institution.

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   74.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  • O. T. Beachley Jr., R. G. Simmons (Inorg. Chem. 19 [1980] 3042/6).

    Google Scholar 

  • R. B. Hallock, O. T. Beachley Jr., Y. J. LI, W. M. Sanders, M. R. Churchill, W. E. Hunter, J. L. Atwood (Inorg. Chem. 22 [1983] 3683/91).

    Article  Google Scholar 

  • H. Schmidbaur, U. Thewalt, T. Zafiropoulos (Angew. Chem. 96 [1984] 60/1

    Google Scholar 

  • H. Schmidbaur, U. Thewalt, T. Zafiropoulos ( Angew. Chem. Intern. Ed. Engl. 23 [1984] 76).

    Article  Google Scholar 

  • H. Schmidbaur, U. Thewalt, T. Zafiropoulos (Organometallics 2 [1984] 1550/4).

    Google Scholar 

  • H. Schmidbaur, U. Thewalt, T. Zafiropoulos (Chem. Ber. 117 [1984] 3381).

    Article  CAS  Google Scholar 

  • U. Thewalt, T. Zafiropoulos, H. Schmidbaur (Z. Naturforsch. 39 b [1984] 1642/6).

    Google Scholar 

  • H. Schmidbaur (Angew. Chem. 97 [1985] 893/904

    Google Scholar 

  • H. Schmidbaur ( Angew. Chem. Intern. Ed. Engl. 24 [1985] 893).

    Article  Google Scholar 

  • H. Schmidbaur, W. Bublak, B. Huber, G. Muller (Organometallics 5 [1986] 1647/51).

    Google Scholar 

  • H. Schmidbaur, T. Zafiropoulos, W. Bublak, P. Burkert, F. H. Kohler (Z. Naturforsch. 41a [1986] 315/8).

    Google Scholar 

  • M. Uson-Finkenzeller, W. Bublak, B. Huber, G. Muller, H. Schmidbaur (Z. Naturforsch. 41b [1986] 346/50).

    Google Scholar 

  • J. A. Howard, R. Sutcliffe, C. A. Hampson, B. Mile (J. Phys. Chem. 90 [1986] 4268/73).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Université d’Aix-Marseille, France

    Jean-Claude Maire

Authors
  1. Jean-Claude Maire
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Ulrich Krüerke
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Marlis Mirbach
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Wolfgang Petz
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Christa Siebert
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Ulrich Krüerke Marlis Mirbach Wolfgang Petz Christa Siebert

Rights and permissions

Reprints and permissions

Copyright information

© 1986 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Maire, JC., Krüerke, U., Mirbach, M., Petz, W., Siebert, C. (1986). Low-Valence Organogallium Compounds. In: Krüerke, U., Mirbach, M., Petz, W., Siebert, C. (eds) Ga Organogallium Compounds. Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition, vol G-a / 1- / 1. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-07374-2_14

Download citation

  • DOI: https://doi.org/10.1007/978-3-662-07374-2_14

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-662-07376-6

  • Online ISBN: 978-3-662-07374-2

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation