Skip to main content

Protolytic Weathering of Montmorillonite, Described by Its Effective Surface Fractal Dimension

  • Chapter
Fractals and Dynamic Systems in Geoscience

Abstract

Octahedral coordinated aluminum is released by the attack of protons from clay minerals like montmorillonite. Apart from other effects, this leads to an alteration of the form of the surface of the clay particles. We used fractal geometry to describe this change in form. The effective surface fractal dimension (D) was determined before and after acid treatment by using the dependency: number of yardsticks necessary to cover the surface versus size of the yardstick area. We used n-alkanols with different cross sectional areas to determine this dependency. This resulted in a D: 2.55 for the untreated and a D: 2.85 for the acid treated clay.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  • Avnir D, Farin D, Pfeifer P (1992) A discussion of some aspects of surface fractality and of its determination. New J Chem 16: 439–449.

    Google Scholar 

  • Breen C, Flynn J, Parkes GMB (1993) Thermogravimetric, infrared and mass-spectroscopic analysis of the desorption of methanol, propan-1-ol, propan-2-ol and 2-methylpropan-2-ol from momtmorillonite. Clay Min 28: 123–138.

    Article  Google Scholar 

  • Drake JM, Levitz P, Klafter J (1990) A comment on the fractal dilemma in porous silica gels. New J Chem 14: 77–81.

    Google Scholar 

  • Fahn R (1973): Einfluß der Struktur und der Morphologie von Bleicherden auf die Bleichwirkung bei Ölen und Fetten. Fette Seifen Anstrichmittel 75: 77.

    Article  Google Scholar 

  • Ohoud MB, Van Damme H (1990) La texture fractale des argiles gonflantes. CR Acad Sci Paris t 311 Série II: 665–670.

    Google Scholar 

  • Pfeifer P, Avnir D, Farin D (1984) Scaling behaviour of surface irregularity in the molecular domain: from adsorptions studies to fractal categories. J Stat Phys 36: 699–716

    Article  Google Scholar 

  • Sokolowska J, Stawinski J, Patrykiejew A, Sokolowski S (1989) A note on fractal analysis of adsorption process by soils and soil minerals. Int Agrophysics 5: 3–12.

    Google Scholar 

  • Srasra E, Bergaya F, Van Damme H, Ariguib NK (1989) Surface properties of an activated bentonite-decolorisation of rape-seed oils. Appl Clay Sci 4: 411–417.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1994 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Niemeyer, J., Machulla, G. (1994). Protolytic Weathering of Montmorillonite, Described by Its Effective Surface Fractal Dimension. In: Kruhl, J.H. (eds) Fractals and Dynamic Systems in Geoscience. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-07304-9_26

Download citation

  • DOI: https://doi.org/10.1007/978-3-662-07304-9_26

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-662-07306-3

  • Online ISBN: 978-3-662-07304-9

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics