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The Si-C Phase Diagram

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Si Silicon

Part of the book series: Gmelin Handbook of Inorganic Chemistry / Gmelin Handbuch der Anorganischen Chemie ((2074,volume S-i / B / 1-5 / 3))

Abstract

The two most recently published [1 to 3] phase diagrams for the Si-C system show somewhat deviating results. They were combined by [4], giving the diagram shown in Fig. 1. The only condensed phases that occur in this phase diagram are silicon, silicon carbide (SiC), and graphite [4]. See also [5, 6]. In addition, however, decomposition of a gaseous mixture of SiCl4, CH4, and Ar at 1900 K has been found to give in up to 24% yield an Si-containing phase corresponding to nearly perfect graphite, with a maximum content of 0.14% Si, along with pyrocarbon [7].

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Authors and Affiliations

  1. NUKEM GmbH, Hanau, Germany

    Vera Haase, Gerhard Kirschstein, Hildegard List, Sigrid Ruprecht, Raymond Sangster, Friedrich Schröder, Wolfgang Töpper, Hans Vanecek & Hartmut Katscher

  2. Universität Karlsruhe, Germany

    Jürgen Schlichting

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  1. Vera Haase
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  2. Gerhard Kirschstein
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Hartmut Katscher Raymond Sangster Friedrich Schröder

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© 1985 Springer-Verlag Berlin Heidelberg

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Haase, V. et al. (1985). The Si-C Phase Diagram. In: Katscher, H., Sangster, R., Schröder, F. (eds) Si Silicon. Gmelin Handbook of Inorganic Chemistry / Gmelin Handbuch der Anorganischen Chemie, vol S-i / B / 1-5 / 3. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-06994-3_1

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  • DOI: https://doi.org/10.1007/978-3-662-06994-3_1

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-662-06996-7

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