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Alloys with Zirconium

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Rh Rhodium

Part of the book series: Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition ((1047,volume R-h / R-h / A / 1))

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Abstract

Superconductivity in rhodium-zirconium alloys was discovered by [1]. This has encouraged a number of investigations on the equilibrium diagram [2 to 5]. These resulted in the diagram shown in [6]. The diagram shown in Fig. 72 and Fig. 73, p. 116, is the result of the most complete investigation so far carried out using differential thermal analysis, levitation thermal analysis, X-ray analysis, electron microprobe analysis, metallography and superconductivity measurements [7]. The diagram is a complex one with some phases transforming martensitically and consequently the equiatomic region is shown enlarged in the second figure; reactivity of the constituents with gases and refractories poses many experimental problems in such work, and the role of oxygen in stabilizing a Ti2Ni phase found by some investigators has been demonstrated by [8, 9]. More recently, the effect of hydrogen on the superconducting properties has been shown [10].

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  1. Bishop Stortford Herts, UK

    G. R. Watts

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  1. Gelnhausen, Bundesrepublik Deutschland

    Kurt Swars

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Watts, G.R. (1991). Alloys with Zirconium. In: Swars, K. (eds) Rh Rhodium. Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition, vol R-h / R-h / A / 1. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-06411-5_26

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