Abstract
Flash vacuum pyrolysis of 5-phenyl-1,2,3,4-thiatriazole produces SNN and C6H5CN. It was carried out at temperatures between 300 and 400 °C/10−3 to 10−5 Torr in an apparatus enabling contact times of ca. 1 ms. SNN can be isolated as a solid (together with C6H5CN) at the cold end of a liquid nitrogen cryostat at 77 K or in an Ar matrix at 10 to 20 K. The yield of SNN, measured by its IR absorbance relative to that of benzonitrile, critically depends on the contact time in the oven and hence on the oven design [1, 2].
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References
Wentrup, C.; Fischer, S.; Maquestiau, A.; Flammang, R. (J. Org. Chem. 51 [1986] 1908/10).
Wentrup, C.; Kambouris, P. (Chem. Rev. 91 [1991] 363/73).
Bender, H.; Carnovale, F.; Peel, J. B.; Wentrup, C. (J. Am. Chem. Soc. 110 [1988] 3458/61).
Holm, A.; Carlsen, L.; Larsen, E. (J. Org. Chem. 43 [1978] 4816/22).
Hassanzadeh, P.; Andrews, L. (J. Am. Chem. Soc. 114 [1992] 83/91).
Kass, S. R.; DePuy, C. H. (J. Org. Chem. 50 [1985] 2874/7).
Powell, F. X. (Chem. Phys. Lett. 33 [1975] 393/5).
Sensarma, S.; Turner, A. G. (Inorg. Chim. Acta 64 [1982] L161/L162).
Brown, R. D.; Elmes, P. S.; McNaughton, D. (J. Mol. Spectrosc. 140 [1990] 390/400).
Behera, L.; Kar, T.; Sannigrahi, A. B. (J. Mol. Struct. 209 [1990] 111/24 [THEOCHEM 68]).
Davy, R. D.; Schaefer, H. F. (J. Am. Chem. Soc. 113 [1991] 1917/22).
Pyykkö, P. (Chem. Phys. Lett. 162 [1989] 349/54).
Zakzhevskii, V. G. (Zh. Neorg. Khim. 36 [1991] 2320/4; Russ. J. lnorg. Chem. [Engl. Transi.] 36 [1991] 1307/10).
Chaban, G. M.; Klimenko, N. M.; Charkin, O. P. (Izv. Akad. Nauk SSSR Ser. Khim. 1990 794/802; Bull. Acad. Sci. USSR Div. Chem. Sci. [Engl. Transi] 1990 704/11).
Gimarc, B. M.; Warren, D. S. (lnorg. Chem. 30 [1991] 3276/80).
Laidlaw, W. G.; Trsic, M. (lnorg. Chem. 20 [1981] 1792/4).
Collins, M. P. S.; Duke, B. J. (J. Chem. Soc. Dalton Trans. 1978 277/9).
Carroll, M. T.; Chang, C.; Bader, R. F. W. (Mol. Phys. 63 [1988] 387/405).
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© 1994 Springer-Verlag Berlin Heidelberg
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Baumann, N., Fachmann, HJ., Jotter, R., Kubny, A. (1994). Dinitrogen Sulfide, SNN. In: Baumann, N., Fachmann, HJ., Jotter, R., Kubny, A. (eds) S Sulfur-Nitrogen Compounds. Gmelin Handbook of Inorganic and Organometallic Chemistry / Gmelin Handbuch der Anorganischen Chemie, vol S / S-N / 10 / a. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-06351-4_5
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DOI: https://doi.org/10.1007/978-3-662-06351-4_5
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