Abstract
In the old kingdoms of upper and lower Egypt, in many examples of burial chambers mural paintings depicting significant events, inscribed stelae or tablets have been excavated that show an astonishing proximity to our modern approach to chirality. In Fig. 1.1, an example is given of a stele that exhibits hieroglyphs carved out of stone such that they are mirrored on both sides of the so-called “ankh cross”. This ankh cross plays an important role in Egyptian mythology — it is the symbol for life. The pharaohs firmly believed in life after death, and, accordingly, they wanted to link the symbol for life with their coffins as well as with the mural paintings and stelae of the burial chamber. In addition, the hieroglyphs closely related to the ankh cross appear twice, i.e., in the form of their two mirror images. This ancient interpretation of chirality/life/death is well in line with the modern assumption that life processes, for example, enzymatic transformation processes, are highly enantioselective, but that dead organic matter may also be transformed and in part mineralised by very enantioselective processes.
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References
Pasteur L (1848), Mémoire sur la relation qui peut exister entre la forme crystalline et la composition chimique, et sur la cause de la polarisation rotatoire. Comptes Rend Acad Sci 26: 535–538
Jacques, J (1993) The molecule and its double. McGrawHill, p 128
Gardner, M (1990) The ambidextrous universe: mirror asymmetry and time-reversed worlds. Scribner, New York, p 293
Faller J, Hühnerfuss H, König WA, Krebber R, Ludwig P (1991) Do marine bacteria degrade a-hexachlorocyclohexane stereoselectively? Environ Sci Technol 25: 676–678.
Kallenborn R, Hühnerfuss H, König WA (1991) Enantioselective metabolism of (±)-ahexachlorocyclohexane in organs of the Eider Duck. Angew Chem 103:328–329; Angew Chem Int Ed Engl 30: 320–321
Fletcher S (1993) Chirality in the umbilical cord. Br J Obstet Gynaecol Mar 100: 234236
Waxman DJ, Light DR, Walsh C (1982) Chiral sulfoxidations catalyzed by rat liver cytochromes P-450. Biochemistry 21: 2499–2507
Harju MT, Haglund P (1999) Determination of rotational barriers of atropisomeric polychlorinated biphenyls. J Anal Chem 364: 219–223
Schurig V, Glausch A, Fluck M (1995) On the enantiomerization barrier of atropisomeric 2,2’,3,3’,4,6’-hexachlorobiphenyl (PCB 132). Tetrahedron Asymm 6: 2161–2164
Weseloh G, Wolf C, König WA (1996) New technique for the determination of interconversion processes based on capillary zone electrophoresis: studies with axially chiral biphenyls. Chirality 8: 441–445
Wolf C, Hochmuth DH, König WA, Roussel C (1996) Influence of substituents on the rotational energy barrier of axially chiral biphenyls. Part 2. Liebigs Ann 1996: 357–63
Walter W, Francke W (1998) Beyer-Walter, Lehrbuch der Organischen Chemie, 23rd edn. S Hirzel Verlag, Stuttgart, p 1176
March J (1985) Advanced organic chemistry. Reactions, mechanisms, and structure. Wiley, New York, p 1346
Cahn RS, Ingold CK, Prelog V (1956) The specification of asymmetric configuration in organic chemistry. Experientia 12: 81–124
Cahn RS, Ingold CK, Prelog V (1966) Spezifikation der molekularen Chiralität. Angew Chem 78:413–447; Angew Chem Int Ed Engl 5: 385–415
Prelog V, Helmchen G (1982) Grundlagen des CIP-Systems und Vorschläge für eine Revision. Angew Chem 94:614–631; Angew Chem Int Ed Engl 21: 567–583
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Kallenborn, R., Hühnerfuss, H. (2001). Introduction. In: Chiral Environmental Pollutants. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-06243-2_1
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