The Carbonate System in Marine Environments

  • F. J. Millero
Part of the Environmental Science book series (ESE)


The major portion of carbon in the oceans occurs in the carbonate system. This system involves the following equilibria


Indian Ocean Deep Water Pacific Ocean Total Alkalinity Carbonate System 
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References for Appendix

  1. Dickson AG (1990a) Standard potential of the reaction: AgCI(s) + 1.2H2(g) = Ag(s) + HC1(aq), and the stastandard acidity constant of the ion HSO4 in synthetic sea water from 273.15 to 318.15 K. J Chem Thermodyn 22: 13–127CrossRefGoogle Scholar
  2. Dickson AG (199ob) Thermodynamics of the dissociation of boric acid in synthetic seawater from 273.15 to 318.15 K. Deep-Sea Res 37:755-766Google Scholar
  3. Dickson AG, Riley JP (1979) The estmation of acid dissociation constants in seawater from potentiometric titrations with strong base. I. The ion product of water - Kw. Mar Chem 7:89–99Google Scholar
  4. Millero FJ (1979) The thermodynamics of the carbonic acid system in seawater. Geochim Cosmochim Acta 43: 1651–1661CrossRefGoogle Scholar
  5. Millero FJ (1995) Thermodynamics of the carbon dioxide system in the oceans. Geochim Cosmochim Acta 59: 661–677CrossRefGoogle Scholar
  6. Mucci A (1983) The solubility of calcite and aragonite in seawater at various salinities, temperatures and one atmosphere total pressure. Amer J Sci 283: 780–799CrossRefGoogle Scholar
  7. Weiss R (1974) Carbon dioxide in water and seawater: The solubility of a non-ideal gas. Mar Chem 8: 347–359CrossRefGoogle Scholar

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© Springer-Verlag Berlin Heidelberg 2000

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  • F. J. Millero

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