Abstract
In the last two decades, the area of supramolecular chemistry [1] has developed at an impressive rate, first focussing on the creation of new molecules and new assemblies through noncovalent bonds to create remarkable molecules and supermolecules. However, chemists are not only the architects of wonderful static molecular structures but they are naturally interested to make them work or properly assemble to realize new molecular engines, whatever their functions may be. So, recently much attention is being directed toward the functions and applications of the supramolecular objects [2]. Much impetus struck novel fast developing areas, such as that of material science, as well old ones but with a new light and from a different perspective. The latter aspect is quite relevant in the area of life sciences. Supramolecular interactions form the basis of processes that occur in biology and one of the problems from the start was related to the possible reductive convergence to one novel branch of the “old” biomimetic chemistry [3]. Instead, chemists used the supramolecular concepts to understand biological events, such as the aggregation of lipids and membrane formation which had been largely neglected, and, by joining their efforts with biochemists, they helped to fill the cultural gap between chemistry and biochemistry with exciting perspectives. However, the affinity between supramolecular sciences and life sciences is unavoidably strong and it is in particular suggestive of the many functions that supramolecular systems can perform.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
J.-M. Lehn, Supramolecular Chemistry. Concepts and Perspectives; 1995, VCG, Weineheim.
D. J. Cram, Science, 1988, 240, 760
C. J. Pedersen, J. Am. Chem. Soc., 1967, 59, 7017.
For recently published general accounts, see: Supramolecular Science, Where it is and Where it is going, 1999, R. Ungaro and E. Dalcanale eds, Kluwer Acad Publ, Dohrdrecht.
R. Breslow, Chem Soc. Rev. 1972, 1, 553
For comprehensive books, see: H. Dugas Bioorganic Chemistry, 1996, Springer, New York, 3rd ed.
W. Kaim and B. Shwederski, Bioinorganic Chemistry: Inorganic Elements of Life, 1994, Wiley, Chichester.
J.-M. Lehn, Angexv. Chem Int. Eng. Ed., 1988, 27, 89.
A. P. Davis, 1999, in ref.2, pp. 125–146.
J.H. Fendler, Membrane Mimetic Chemistry, 1982, Wiley, New York
U. Tonellato in Solution Chemistry of Surfactants, 1979, K. Mittal ed, vol 2, Plenum, New York, pp 541–553
L. Anoardi, R. Fornasier, U. Tonellato J. Chem Soc., Perkin II, 1981, 260, 1
U. Tonellato, Colloids and Surfaces, 1989, 35, 121
R. A. Moss, R. C. Nahas, S. Ramaswani, and W. J. Sanders, Tetrahedron Lett., 1975, 4435
R. A. Moss, R. C. Nahas, S. Ramaswani, J. Am. Chem. Soc., 1977, 99, 627
R. A. Moss, T. J. Lukas, and R. C. Nahas, J. Am. Chem. Soc., 1978, 100, 5920.
M. Menger and C. E. Portnoy, J. Am. Chem. Soc., 1967, 89, 4698
K. Y. Yatsimirski,, K. Martinek, and I. Berezin, Tetrahedron, 1971, 27, 2855
L. S. Romsted in Micellization, Solubilization, and Microemulsions, 1977 K. Mittal ed, vol. 2, p. 509, Plenum, New York
C. A. Bunton and G. Savelli, Adv. Phys. Org. Chem, 1986, 22, 213.
M. Menger and L. G. Whitesell, J. Am. Chem. Soc. 1985, 107, 707
R. A. Moss, K. W. Alwis, J.-S. Shin, J. Am. Chem Soc. 1984, 106, 2651.
R. Fornasier and U. Tonellato, J. Chem. Soc., Faraday 1, 1980, 76, 1301.
R. Fornasier, D. Milani, P. Scrimin, and U. Tonellato, Gazz Chim It al., 1986, 116, 55;
R. Fornasier, P. Scrimin, P. Tecilla, and U. Tonellato, J. Am. Chem Soc., 1989, 111, 224;
P. Scrimin, P. Tecilla, and U. Tonellato in Organic Reactivity and Biological Aspects, 1995, B. T. Golding, R. G. Griffin, and H. Maskill eds., The Royal Society of Chemistry, pp 223–231.
L. L. Melhado and C. D. Gutsche J. Am Chem Soc., 1978, 100, 1850
W. Tagaki, K. Ogino, Top. Curr. Chem 1985, 128, 144
W. Tagaki, K. Ogino, J. Am. Chem Soc., 1987, 111, 5086.
For recent overviews, see: J. K. M. Sanders, Chem. Eur. J., 1998, 4, 1378 and, in ref. 2, pp 273–286.
U. Tonellato, Pure & Appl. Chem, 1998, 70, 1961 and references therein.
P. Scrimin, P. Tecilla, and U. Tonellato, J. Org. Chem, 1991, 56, 199.
M. C. Cleij, P. Scrimin, P. Tecilla, and U. Tonellato, Langmuir, 1996, 12, 2956
P. Scrimin, P. Tecilla, and U. Tonellato J. Org. Chem., 1993, 58, 3025
P. Scrimin, P. Tecilla, and U. Tonellato Tetrahedron, 1995, 51, 521
M. C. Cleij, P. Scrimin, P. Tecilla, and U. Tonellato, Tetrahedron, 1997, 53, 357.
F. Bertoncin, F. Mancin, P. Scrimin, P. Tecilla, and U. Tonellato, Langmuir, 1998, 14, 975.
R. Fornasier, E. Scarpa, P. Scrimin, P. Tecilla, and U. Tonellato, J. Inch Phenom, 1992, 14, 230.
P. Scrimin, P. Tecilla, U. Tonellato and U. Vignaga, J. Chem Soc., Chem Commun., 1991 449
P. Scrimin, P. Tecilla, and U. Tonellato, G. Valle and A. Veronese, Tetrahedron, 1995, 51, 527
P. Scrimin, P. Tecilla, and U. Tonellato, Eur. J. Org. Chem., 1998, 1, 1143.
J. K. M. Sanders,, in ref. 2, 1999, pp 273–286.
T. M. Fyles and W. F. Van Straaten-Nijenhuis, in Comprehensive Supramolecular Chemistry, 1996, D. N. Reinhoudt ed., vol. 10, Elsevier, Oxford, UK, pp 53–77
F. De Fong and H. C. Visser, , in Comprehensive Supramolecular Chemistry, 1996, D. N. Reinhoudt ed., vol. 10, Elsevier, Oxford, UK, pp 13–51.
F. M. Menger and J. J. Lee, J. Org. Chem, 1993, 58, 1909.
M. C. Cleij, P. Tecilla, U. Tonellato, and P. Scrimin, J Org. Chem., 1997, 62, 5592.
P. Scrimin, U. Tonellato, and N. Zanta, Tetrahedron Lett., 1988, 29, 4967
P. Scrimin, P. Tecilla, and U. Tonellato, Tetrahedron, 1995, 51, 217.
D. D. Lasic, Liposomes: from Physics to Applications, 1993, Elsevier, Amsterdam.
G. Ghirlanda, P. Scrimin, P. Tecilla, and U. Tonellato, J. Org. Chem, 1994, 59, 18.
P. Scrimin, P. Tecilla, R. A. Moss, and K. Bracken , J Am Chem Soc., 1998, 120, 1179.
P. Scrimin, S. Caruso, N. Paggiarin, and P. Tecilla, Langmuir, in press.
E. Benedetti, A. Bavoso, B. Di Blasio, V. Pavone, C. Pedone, C. Toniolo, and G. M. Bonora, Proc Natl. Acad. Sci. U.S.A., 1982, 79, 7951.
P. Scrimin, A. Veronese, P. Tecilla,P. U. Tonellato, V. Monaco, F. Formaggio, M. Crisma, and C. Toniolo, J. Am. Chem. Soc., 1996, 118, 2505.
For overviews, see: Fluorescent Chemosensors for Ion and Molecule Recognition, 1993, A. W. Czarnik ed, ACS Symp. Ser., 538
A. P. de Sllva, H. Q. N. Gunaratne, T. Gunnlaugsson, A. J. M. Huxley, C. P. McCoy, J. T. Rademacher, and T. E. Rice, Chem. Rev., 1997, 97, 1515.
L. Fabbrizzi, M. Licchelli, F. Mancin, M. Pizzeghello, A. Taglietti, P. Tecilla, and U. Tonellato, unpublished results.
P. Grandini, F. Mancin, P. Tecilla, P. Scrimin, and U. Tonellato, Angew. Chem. Int. Ed. Engl., 1999, 38, 3061.
J. M. Lehn in ref.2, 1999, pp 287–304.
D. N. Reinhoudt, J. F. Stoddard, and R. Ungaro, Chem Eur. J., 1998, 4, 1349.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2000 Springer-Verlag Berlin Heidelberg
About this paper
Cite this paper
Scrimin, P., Tecilla, P., Tonellato, U. (2000). Supramolecular Functions of Designed Transition Metal Ion Complexes. In: Fabbrizzi, L., Poggi, A. (eds) Chemistry at the Beginning of the Third Millennium. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-04154-3_4
Download citation
DOI: https://doi.org/10.1007/978-3-662-04154-3_4
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-08687-8
Online ISBN: 978-3-662-04154-3
eBook Packages: Springer Book Archive