Abstract
New polyoxometalate anions with unusual chemical composition and structural features could be prepared by carefully tuning the synthetic procedures. Polyoxometalate anions containing a high amount of Te or Se or residues of acetic acid, fumaric acid, succinic acid, diglycolic acid or thio-diacetic acid as ligands have been characterized by X-ray structure analysis. Coordination polymers with one-dimension ally, two-dimensionally and three-dimensionally infinite structural characteristics could be prepared employing anions of dihydroxy-p-benzoquinones, benzene carboxylic acids, methylene diphosphonic acid, and phosphono-carboxylic acids. Coordination polymers with chain-like or layer-like structure carrying negative excess charge as well as compounds with an open framework structure have been studied.
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Robl, C. (2000). Polyoxometalates and Coordination Polymers. In: Fabbrizzi, L., Poggi, A. (eds) Chemistry at the Beginning of the Third Millennium. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-04154-3_13
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DOI: https://doi.org/10.1007/978-3-662-04154-3_13
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