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High-Temperature Size Exclusion Chromatography

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Size Exclusion Chromatography

Part of the book series: Springer Laboratory ((SPLABORATORY))

Abstract

Several commercially important plastics, such as polyethylene and polypropylene, are not soluble in any solvents at room temperature. They are soluble in o-dichlorobenzene (ODCB) or 1,2,4-trichlorobenzene (TCB) at temperatures above 100 °C and SEC of these polymers is carried out at temperatures above 130 °C. Requirements for solvents used for high-temperature (HT) SEC are high boiling points, i.e. low volatility, good solubility for these polymers and a low viscosity at high temperature, in addition to good compatibility with the stationary phase.

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Author information

Authors and Affiliations

  1. Mie University, 4-8, Ibuka, 453-0012, Nagoya, Japan

    Prof. Sadao Mori

  2. Central Research and Development, DuPont Company, P.O. Box 80228, 19880-0228, Wilmington, Delaware, USA

    Dr. Howard G. Barth

Authors
  1. Prof. Sadao Mori
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  2. Dr. Howard G. Barth
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© 1999 Springer-Verlag Berlin Heidelberg

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Mori, S., Barth, H.G. (1999). High-Temperature Size Exclusion Chromatography. In: Size Exclusion Chromatography. Springer Laboratory. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-03910-6_10

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  • DOI: https://doi.org/10.1007/978-3-662-03910-6_10

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-08493-5

  • Online ISBN: 978-3-662-03910-6

  • eBook Packages: Springer Book Archive

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