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Catalysis and Zeolites pp 81–197Cite as

Modification of Zeolites

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Abstract

Zeolites, in a narrow definition, are porous crystalline aluminosilicates having a uniform pore structure and exhibiting ion-exchange behavior. The framework of zeolites consists of SiO4 and AlO4 tetrahedra sharing oxygen ions located at their apices, thus resulting in the general framework formula (AlO2)x(SiO2)(n−x), where n is the number of tetrahedra per unit cell, and x ≤ n/2. Since aluminum is trivalent, every AlO2 unit carries a negative charge, which is compensated by a positive charge associated with a cation. Therefore, the ion-exchange capacity of a zeolite depends on the chemical composition, i. e., a higher ion-exchange capacity is observed in zeolites of low SiO2/Al2O3 ratio [la]. The specific ion-exchange capacity varies with the structure of the zeolite and the exchange cation.

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  1. Günter H. Kühl
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  1. Institut für Technische Chemie I, Universität Stuttgart, D-70550, Stuttgart, Germany

    Jens Weitkamp

  2. Bayer AG, Geschäftsbereich Chemikalien CH-F-FC, Gebäude G 8, D-51368, Leverkusen, Germany

    Lothar Puppe

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Kühl, G.H. (1999). Modification of Zeolites. In: Weitkamp, J., Puppe, L. (eds) Catalysis and Zeolites. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-03764-5_3

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