Abstract
Hydraulic conductivity (K) of a porous medium as defined by Darcy’s law
is a transport coefficient which depends both on matrix and pore fluid properties, where Q is discharge, A cross-sectional area, and dh/dl the change in head per unit change in length. The relevant pore fluid properties were determined empirically to be density (p) and dynamic viscosity (μ). Intrinsic permeability (k) was defined to describe the conductive properties of a medium independent of the fluid flowing through it (Nutting 1930)
with g as the gravitational constant. In a rigid, noninteracting porous medium with an effective pore radius of r, k was shown to be equal to (Bear 1972)
Where f(σ) is a function of pore shape and f(θ a function of porosity, both dimensionless.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Acar YB, Olivieri I (1989) Pore fluid effects on the fabric and hydraulic conductivity of laboratory-compacted clay. Geotechnical engineering. Transport Res Rec 1219:144–159
Acar YB, Seals RK (1984) Clay barrier technology for shallow land waste disposal facilities. Haz Waste 1:167–181
Amoozegar A, Warrick AW, Fuller WH (1986) Movement of selected organic liquids into dry soils Haz Mat Haz Waste 3:29–41
Anderson DC, Brown KW, Thomas JC (1985) Conductivity of compacted clay soils to water and organic liquids. Waste man Res 3:339–349
Aylmore LAG, Quirk JP (1962) The structural status of clay systems. In: Ingerson E (ed) Clays and clay minerals. Earth Science Series, Monograph 11. Pergamon Press, New York, pp 104–130
Bagley EB, Scigliano JM (1976) Polymer solutions. In: Dack MRJ (ed) Solutions and solubilities. Wiley Interscience, New York pp 437–485
Barshad I (1952) Factors affecting the interlayer expansion of vermiculite and montmorillonite with organic substances. Soil Sci Soc Am Proc 16:176–182
Barton AFM (1983) Handbook of solubility parameters and other cohesion parameters. CRC Press, Boca Raton
Bear J(1972) Dynamics of fluids in porous media. Elsevier New York
Berkheiser V, Mortland MM (1975) Variability in exchange ion position in smectite: dependence on interlayer solvent. Clays Clay Miner 23:404–410
Bohn HL, McNeal BL, O’Connor GA (1979) Soil chemistry. John Wiley New York
Bradley WF (1945) Molecular associations between montmorillonite and some poly-functional organic liquids. J Am Chem Soc 67:975–981
Brindley GW (1980) Intracrystalline swelling of montmorillonites in water-dimethylsulfoxide systems. Clays Clay Miner 28:369–372
Brindley GW, Wiewiora K, Wiewiora A (1969) Intracrystalline swelling of montmorillonite in some water-organic mixtures. Clay organic studies, XVII. Am Mineralogist 54:1635–1644
Brown KW, Thomas JC (1984) Conductivity of three commercially available clays to petroleum products and organic solvents. Haz Waste 1:545–553
Brown KW, Thomas JC (1987) A mechnaism by which organic liquids increase the hydraulic conductivity of compacted clay materials. Soil Sci Soc Am J 51:1451–1459
Brown KW, Thomas JC, Green JW (1986) Field cell verification of the effects of concentrated organic solvents on the conductivity of compacted soils. Haz Waste Haz Mat 3:1–19
Chen S, Low PF, Cushman JH, Roth CB (1987) Organic compound effects on swelling and flocculation of Upton montmorillonite. Soil Sci Soc Am J 51:1444–1450
Delville A, Laszlo P (1990) The origin of the swelling of clays by water. Langmuir 6:1289–1294
Demond AH, Rathfelder K, Abriola LM (1996) Simulation of organic liquid flow in porous media using estimated and measured transport properties. J Contam Hydol 22:223–239
Emerson WW (1963) The swelling of Na montmorillonite due to water adsorption. Aust J soil Res 1:129–143
Gerstl Z, Galin Ts, Yaron B (1994) Mass flow of a volatile organic liquid mixture in soils. J Environ Qual 23:487–493
Graber ER, Mingelgrin U (1994) Clay swelling and regular solution theory. Environ Sci Technol 28:2360–2365
Green WJ, Lee GF, Jones A (1981) Clay-soils permeability and hazardous waste storage. J Water Pollut Control Fed 53:1347–1354
Hettiaratchi JPA, Hrudey SE (1987) Influence of contaminant organic-water mixtures on shrinkage of impermeable clay soils with regard to hazardous waste landfill liners. Haz Mat Haz Waste 4:377–388
Hildebrand JH, Prausnitz JM, Scott RL (1970) Regular and related solutions. Van Nostrand Reinhold, New York
Israelachvili J, Pashley R (1982) The hydrophobic interaction is long range, decaying exponentially with distance. Nature 300:341–342
Jarsjo J, Destouni G, Yaron B (1997) On the relation between viscosity and hydraulic conductivity values for volatile organic liquid mixtures in soils. J Contam Hydrol 25:113–127
Low PF (1980) The swelling of clay. II. Montmorillonites. Soil Sci Soc Am Proc 44:667–676
Low PF (1981) The swelling of clay. III. Dissociation of exchangeable cations. Soil Sci Soc Am Proc 45:1074–1078
Low PF, Margheim JF (1979) The swelling of clay. I. Basic concepts and empirical equations. Soil Sci Soc Am Proc 43:473–481
MacEwan DMC (1948) Complexes of clays with organic compounds. I. Complex formation between montmorillonite and halloysite and certain organic liquids. Trans Faraday Soc 44:349–367
Mark HF, Tobolsky AV (1950) Physical chemistry of high polymeric systems, Chap 8. Interscience Publ New York
Moore CA, Mitchell JK (1974) Electromagnetic forces and soil strength. Geotechnique 24:627–640
Murray RS, Quirk JP (1982) The physical swelling of clays in solvents. Soil Sci Soc Am J 46:865–868
Norrish K (1954) The swelling of montmorillonite. Trans Faraday Soc Lond 18:120–134
Norrish K, Rausell-Colom JA (1961) Low angle x-ray diffraction studies of the swelling of montmorillonite and vermiculite. Clays Clay Miner 10:123–144
Nutting PG (1930) Physical analysis of oil sands. Bull Am Assoc Petroe Geol 14:1337–1349
Olejnik S, Posner AM, Quirk JP (1974) Swelling of montmorillonite in polar organic liquids. Clays Clay Miner 22:361–365
Rowell DL (1965) Influence of positive charge on the inter- and intra-crystalline swelling of oriented aggregates of Na montmorillonite in NaCl solutions. Soil Sci 100:340–347
Schramm M, Warrick AW, Fuller WH (1986) Permeability of soils to four organic liquids and water. Haz Mat Haz Waste 3:21–27
Tsvetkov F, Heller-Kallai L, Mingelgrin U (1993) Potassium halide-treated montmorillonite (KTM) as a solid phase in liquid chromatography. Clays Clay Miner 41:527–536
van Olphen H (1962) Compaction of clay sediments in the range of molecular particle distances. In: Ingerson E (ed) Clays and clay minerals. Earth Science Series, Monograph 11. Pergamon Press, New York pp 178–187
van Olphen H (1963) An introduction to clay colloid chemistry. Interscience Publ New York
Viani BE, Low PF, Roth CB (1983) Direct measurement of the relation between interlayer force and interlayer distance in the swelling of montmorillonite. J Colloid Interface Sci 96:229–244
Viani BE, Roth CB, Low PF (1985) Direct measurement of the relation between swelling pressure and interlayer distance in Li-vermicultie. Clays Clay Miner 33:244–250
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1998 Springer-Verlag Berlin Heidelberg
About this paper
Cite this paper
Graber, E.R., Mingelgrin, U. (1998). Permeability of Porous Media as Affected by Shrinkage and Swelling of Clays. In: Rubin, H., Narkis, N., Carberry, J. (eds) Soil and Aquifer Pollution. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-03674-7_4
Download citation
DOI: https://doi.org/10.1007/978-3-662-03674-7_4
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-08294-8
Online ISBN: 978-3-662-03674-7
eBook Packages: Springer Book Archive