Abstract
In metal-hydrogen (M-H) systems, all kinds of chemical bonds are realized: ionic, covalent and metallic. Here, we deal almost exclusively with metallic hydrides, which, by nature of metallic bonding, commonly exist over extended ranges of nonstoichiometric compositions. These hydrides can be called interstitial alloys, where interstitial sites of metal lattices are occupied by hydrogen (H) atoms, randomly at high temperatures and in some regular ways at lower temperatures. Frequently, metal lattices themselves undergo structural changes to accommodate a larger number of H atoms interstitially. Thus, a variety of phases can exist in M-H binary systems.
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Fukai, Y. (1993). Phase Diagrams and Statistical Thermodynamics of Binary M-H Systems. In: The Metal-Hydrogen System. Springer Series in Materials Science , vol 21. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-02801-8_1
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