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Structure and Deformation

  • Chapter
Polymer Fracture

Part of the book series: Polymers ((POLYMERS,volume 2))

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Abstract

The basic structural elements of high polymer solids are the chain molecules. The variety of their structure and flexibility permits different modes of organization and mechanical interaction. At this point the characteristic elements of structure and superstructure of amorphous and semicrystalline polymers will be introduced. The interrelations between chain parameters (structure and regularity), crystal or superstructural parameters (degree of crystallinity, lattice structure, nucleation and growth kinetics, defects), and environmental parameters are extensively discussed in the literature and are not the object of this book [1–3].

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References for Chapter 2

  1. P. H. Geil: Polymer Single Crystals, New York: Interscience 1963.

    Google Scholar 

  2. A. Keller: Polymer crystals, Rep. Progr. Phys. 31, 623–704 (1968).

    Article  CAS  Google Scholar 

  3. B. Wunderlich Macromolecular Physics: Crystal Structure, Morphology, Defects (Vol. 1), Crystal Nucleation, Growth, Annealing (Vol. 2 ), New York and London: Academic Press 1973.

    Google Scholar 

  4. E. W. Fischer: Structure of amorphous organic polymers in bulk, Proc. Conf. Non-Crystalline Solids, Clausthal-Zellerfeld, Sept. 1976.

    Google Scholar 

  5. R. G. Kirste, W. A. Kruse, J. Schelten: Makromol. Chem. 162, 299 (1972).

    Article  CAS  Google Scholar 

  6. J. P. Cotton, D. Decker, H. Benoit, B. Farnoux, J. Higgins, G. Jannink, R. Ober, C. Picot, J. des Cloizeaux: Macromolecules 7, 863 (1974).

    Article  Google Scholar 

  7. P. J. Flory: Statistical Mechanicsof Chain Molecules, New York: Wiley 1969.

    Google Scholar 

  8. P. J. Flory: Spatial configuration of macromolecular chains, The 1974 Nobel Lecture, Brit. Polymer J. 8, 1–10 (1976).

    Article  CAS  Google Scholar 

  9. R. Hosemann: Makromol. Chem., Suppl. 1, 559–577 (1975). R. Hosemann: Ber. Bunsenges. phys. Chem. 74, 755–767 (1970).

    Google Scholar 

  10. W. Pechhold: Kolloid-Z. Z. Polymere 228, 1 (1968).

    Article  CAS  Google Scholar 

  11. W. Pechhold: J. Polymer Sci. C32, 123–148 (1971).

    Google Scholar 

  12. G. S. Y. Yeh: Polymer Prepr. 14/2, 718 (1973).

    Google Scholar 

  13. H. H. Kausch: Kolloid-Z. Z. Polymere 234, 1148–1149 (1969), 237, 251–266 (1970) and J. Polymer Sci. C32, 1–44 (1971).

    Google Scholar 

  14. H. F. Mark: p. xiii. b) H. Gleiter, R. Hornbogen, J. Petermann: p. 149. c) J. D. Ferry: p. 27. d) R. S. Rivlin: p. 71. e) R. F. Landel, R. F. Fedors: p. 1 31. f) W. Pechhold: p. 301. g) K. H. Anthony, E. Kröner: p. 429. Deformation and Fracture of Polymers: H. H. Kausch, J. A. Hassel, R. I. Jaffee, eds., New York/London: Plenum Press 1973.

    Google Scholar 

  15. E. W. Fischer: Z. Naturforsch. 12a, 753 (1957).

    Google Scholar 

  16. A. Keller: Phil. Mag. 2, 1171 (1957).

    Article  CAS  Google Scholar 

  17. P. H. Till: J. Polymer Sci. 24, 301 (1957).

    Article  CAS  Google Scholar 

  18. Courtesy of E. W. Fischer: Mainz 1974.

    Google Scholar 

  19. C. W. Bunn: Trans. Faraday Soc. 35, 482 (1939).

    Article  CAS  Google Scholar 

  20. T. Miyazawa, T. Kitagawa: J. Polymer Sci. B2 (1964).

    Google Scholar 

  21. J. Wristers: J. Polymer Sci., Polym. Physics Ed. 11, 1601–1617 (1973).

    Google Scholar 

  22. T. Komoto, M. Iguchi, H. Kanetsuna, T. Kawai: Makromol. Chem. 135, 145 (1975).

    Article  Google Scholar 

  23. K. C. Tsou, H. P. Geil: Int. J. Polym. Mater. 1, 223 (1972).

    Article  Google Scholar 

  24. T. Hattori, K. Tanaka, M. Matsuo: Polym. Eng. Sci. 12, 199 (1972).

    Article  CAS  Google Scholar 

  25. A. H. Abdel-Alim, A. E. Hamielec: J. Appl. Polym. Sci. 17, 3033–3047 (1973).

    Article  CAS  Google Scholar 

  26. A. H. Abdel-Alim: J. Appl. Polym. Sci. 19, 2179–2185 (1975).

    Article  Google Scholar 

  27. N. A. J. Platzer: Copolymers, Polyblends, and Composites, Adv. Chem. 142 (1975).

    Google Scholar 

  28. J. A. Manson, L. H. Sperling: Polymer Blends and Composites, New York and London: Plenum Press 1976.

    Google Scholar 

  29. Mehrphasensysteme, Spring Meeting of the German Chemical and Physical Societies, Bad Nauheim, March 29–April 2, 1976, papers published in Angew. Makromol. Chem. 58/59 and 60 /61 (1977).

    Google Scholar 

  30. G. Kámpf, M. Hoffmann, H. Krömer: Ber. Bunsen-Ges. 74, 851 (1970).

    Google Scholar 

  31. Courtesy to G. Kámpf: Uerdingen, 1976.

    Google Scholar 

  32. A. Keller: J. Polymer Sci. 15, 32–49 (1955).

    Google Scholar 

  33. A. J. Pennings, A. M. Kiel: Kolloid-Z. Z. Polymere 205, 160–162 (1965).

    Article  CAS  Google Scholar 

  34. T. Kawai, T. Matsumoto, M. Kato, H. Maeda: Kolloid-Z. Z. Polymere 222, 1–10 (1968).

    Article  CAS  Google Scholar 

  35. P. Tucker, W. George: Polym. Eng. Sci. 12, 364–377 (1972).

    Article  CAS  Google Scholar 

  36. P. Tucker, W. George: Text. Res. J. 44, 56–70 (1974).

    CAS  Google Scholar 

  37. A. Zwijnenburg, A. J. Pennings: Kolloid-Z. Z. Polymere 254, 868–881 (1976).

    CAS  Google Scholar 

  38. M. Takayanagi, In: Deformation and Fracture of High Polymers, H. H. Kausch, J. A. Hassel, R. I. Jaffee, eds., New York: Plenum Press 1973, p. 353–376.

    Google Scholar 

  39. J. M. Lupton, J. W. Regester: J. Appl. Polymer Sci. 18, 2407–2425 (1974).

    Article  CAS  Google Scholar 

  40. N. E. Weeks, R. S. Porter: J. Polymer Sci., Polymer Physics Ed. 12, 635–643 (1974).

    Google Scholar 

  41. N. J. Capiati, R. S. Porter: ibid. 13, 1177–1186 (1975).

    CAS  Google Scholar 

  42. R. B. Morris, D. C. Bassett: ibid. 13, 1501–1509 (1975).

    CAS  Google Scholar 

  43. N. E. Weeks, R. S. Porter: ibid. 13, 2031–2048 (1975).

    CAS  Google Scholar 

  44. N. E. Weeks, R. S. Porter: ibid. 13, 2049–2065 (1975).

    CAS  Google Scholar 

  45. F. R. Anderson: J. Polymer Sci. C3, 123 (1963).

    Google Scholar 

  46. E. S. Clark, C. A. Garber: Int. J. Polym. Mater. 1, 31 (1971).

    Article  Google Scholar 

  47. W. O. Statton: Report UTEC MSE 73–100, University of Utah, Salt Lake City, 1973.

    Google Scholar 

  48. H. D. Noether, W. Whitney: Kolloid-Z. Z. Polymere 251, 991 (1973).

    Article  CAS  Google Scholar 

  49. I. K. Park, H. D. Noether: Colloid and Polymer Sci. 253, 824–839 (1975).

    Google Scholar 

  50. D. Göritz: Colloid and Polymer Sci. 253, 844–851 (1975).

    Article  Google Scholar 

  51. B. Cayrol, J. Petermann: J. Polymer Sci., Polymer Phys. Ed. 12, 2169–2172 (1974).

    Google Scholar 

  52. R. S. Stein: J. Polymer Sci. C32, 45–68 (1971).

    Google Scholar 

  53. V. Petraccone, I. C. Sanchez, R. S. Stein: J. Polymer Sci.,,Polymer Phys. Ed. 13, 1991–2029 (1975).

    Google Scholar 

  54. B. Wunderlich, H. Baur: Adv. Polymer Sci. 7, 151–368 (1970).

    Article  CAS  Google Scholar 

  55. J. D. Ferry: Viscoelastic Properties of Polymers, New York: Wiley 1970.

    Google Scholar 

  56. J. A. Sauer, A. E. Woodward: Polymer Thermal Analysis, II. P. E. Slade, Jr., L. T. Jenkins, eds., New York: Dekker, Inc. 1970, p. 107.

    Google Scholar 

  57. J. A. Sauer, G. C. Richardson, D. R. Morrow: J. Macromol. Sci. - Revs. Macromol. Chem. C9 (2), 149–267 (1973).

    Google Scholar 

  58. H. D. Noether: personal communication.

    Google Scholar 

  59. L. R. G. Treloar: The Physics of Rubber Elasticity, London: Oxford Univ. Press 1958.

    Google Scholar 

  60. M. Maeda, S. Hibi, F. Itoh, S. Nomura, T. Kawaguchi, H. Kawai: J. Polymer Sci., A-2, 8, 1303–1322 (1970).

    CAS  Google Scholar 

  61. S. Nomura, A. Asanuma, S. Suehiro, H. Kawai: ibid. 9, 1991–2007 (1971). Rheo-Optical Studies of High Polymers, Onogi Laboratory, Kyoto University, Kyoto, Japan, 1971.

    Google Scholar 

  62. N. Kasai, M. Kakudo: J. Polymer Sci. A-2, 1955 (1964).

    Google Scholar 

  63. A. Peterlin: Adv. Polymer Science and Engineering, K. D. Pae, D. R. Morrow, and Yo Chen, eds., New York: Plenum Press 1972, p. 1.

    Chapter  Google Scholar 

  64. W. Voigt: Lehrbuch der Kristallphysik, B. G. Teubner Leipzig (1910).

    Google Scholar 

  65. A. Reuss: Z. angew. Math. Mech. 9, 49 (1929).

    Google Scholar 

  66. E. H. Kerner: Proc. Phys. Soc. B 69, 802 (1956), Proc. Phys. Soc. B 69, 808 (1956).

    Article  Google Scholar 

  67. Z. Hashin: J. Mech. Phys. Solids 10, 335 (1962). Z. Hashin, S. Shtrikman: J. Mech. Phys. Solids 10, 343 (1962).

    CAS  Google Scholar 

  68. C. van der Poel: Rheol. Acta 1, 198 (1958).

    Article  Google Scholar 

  69. H. Eilers: Kolloid-Z. 97, 313 (1941).

    Article  CAS  Google Scholar 

  70. E. Guth: J. Appl. Phys. 16, 20 (1954). E. Guth, O. Gold: Phys. Rev. 53, 322 (1938).

    CAS  Google Scholar 

  71. M. Mooney: J. Colloid Sci. 6, 162–170 (1951).

    Article  CAS  Google Scholar 

  72. M. Takayanagi, K. Imada, T. Kajiyama: J. Polymer Sci., C15, 263–281 (1966).

    CAS  Google Scholar 

  73. S. Uemura, M. Takayanagi: J. Appl. Polymer Sci. 10, 113 (1966).

    Article  CAS  Google Scholar 

  74. L. E. Nielsen: Mechanical Properties of Polymers and Composites, New York: Marcel Dekker, 1974, Vol. 2, p. 387 ff.

    Google Scholar 

  75. A. Einstein: Annalen Phys. 19, 289 (1906), Annalen Phys. 34, 591 (1911).

    Article  CAS  Google Scholar 

  76. R. A. Dickie, M. Cheung: J. Appl. Polymer Sci. 17, 79–94 (1973).

    Article  CAS  Google Scholar 

  77. H. H. Kausch: Angew. Makromol. Chem. 60/61, 139 (1977).

    Google Scholar 

  78. F. R. Schwarzl, H. W. Bree, C. J. Nederveen: Proc. IV. Int. Congr. Rheology (Providence 1963). E. H. Lee, ed., New York: Interscience, 1965, Vol. 3, p. 241–263.

    Google Scholar 

  79. W. Kuhn: Kolloid-Z. 87, 3 (1939). W. Kuhn, F. GrUn: Kolloid-Z. 1, 248 (1942).

    Google Scholar 

  80. K. Eiermann: Kunststoffe 51, 512 (1961). K. Eiermann, K. H. Hellwege: J. Polymer Sci. 1, 99 (1962).

    Google Scholar 

  81. J. Hennig: Kunststoffe 57, 385 (1967). J. Hennig: Kolloid-Z. Z. Polymere 202, 127 (1965).

    CAS  Google Scholar 

  82. W. Hellmuth, H. G. Kilian, F. H. MUller: Kolloid-Z. Z. Polymere 218, 10 (1967). F. H. Muller: J. Polymer Sci. C20, 61 (1967).

    Google Scholar 

  83. C C. Hsiao: J. Polymer Sci. 44, 71 (1960).

    Article  Google Scholar 

  84. J. Bishop, R. Hill: Ð Ä. Mag. 42, 414 and 1298 (1951).

    Google Scholar 

  85. I. M. Ward: Proc. Phys. Soc. 80, 1176 (1962).

    Article  CAS  Google Scholar 

  86. H. H. Kausch: J. Appl. Phys. 38, 4213 (1967).

    Article  Google Scholar 

  87. S. S. Sternstein, G. M. Lederle, In: Polymer Networks: Structure and Mechanical Properties, Newman and Chompff, eds., New York: Plenum Press, 1971.

    Google Scholar 

  88. C Halpin, J. C. Kardos: J. Appl. Phys. 43, 2235 (1972).

    Article  CAS  Google Scholar 

  89. E. H. Andrews: Pure Appl. Chem. 39, 179–194 (1974).

    Article  CAS  Google Scholar 

  90. D. W. Hadley, I. M. Ward: Rep. Progr. Physics, 38, 1143–1215 (1975).

    Article  CAS  Google Scholar 

  91. R. Bonart, R. Hosemann: Kolloid-Z. Z. Polymere 186, 16 (1962).

    Article  CAS  Google Scholar 

  92. J. Schelten, D. G. H. Ballard, G. D. Wignall, G. W. Longman, W. Schmatz: Polymer 17, 751 (1976).

    Article  CAS  Google Scholar 

  93. D. Y. Yoon, P. J. Flory: Polymer 18, 509–513 (1976).

    Article  Google Scholar 

  94. G. Capaccio, I. M. Ward: Polymer 16, 239 (1975).

    Article  CAS  Google Scholar 

  95. G. Capaccio, T. A. Crompton, I. M. Ward: J. Polymer Sci. A214, 1641 (1976).

    Google Scholar 

  96. G. Capaccio, T. J. Chapman, I. M. Ward: Polymer 16, 469 (1975).

    Article  CAS  Google Scholar 

  97. G. Capaccio, T. A. Crompton, I. M. Ward: Polymer 17, 645 (1976).

    Article  Google Scholar 

  98. I. M. Ward: Seminar on Ultra-High Polymers, St Margherita Ligure, May 1977.

    Google Scholar 

  99. G. Capaccio: Seminar on Ultra-High Polymers, St. Margherita Ligure, May 1977.

    Google Scholar 

  100. K. Anthony: Habilitationsschrift, Universitát Stuttgart, November 1974.

    Google Scholar 

  101. E. W. Fischer: Europhysics Conf. Abstracts 2E, 71–79 (1977).

    Google Scholar 

  102. Schelten, G. D. WignaH, D. G. H. Ballard, G. W. Longmann: Polymer 18/11, 1111 (1977).

    Google Scholar 

  103. H. Benoit, D. Decker, R. Duplessix, C. Picot, P. Rempp, J. P. Cotton, B. Farnoux, G. Jannink, R. Ober: J. Polym. Sci., Polym. Phys. Ed. 14, 2119–2128 (1976).

    Google Scholar 

  104. C. Picot, R. Duplessix, D. Decker, H. Benoit, F. Boue, J. P. Cotton, M. Daoud, B. Farnoux, G. Jannink, M. Nierlich, A. J. deVries, P. Pincus: Macromolecules 10, 436–442 (1977).

    Article  CAS  Google Scholar 

  105. Europhysics Conf. Abstracts 2F (1978).

    Google Scholar 

  106. S. L. Cannon, G. B. McKenna, W. O. Statton: J. Polymer Sci., Macromol. Rev. 11, 209–275 (1976).

    Article  CAS  Google Scholar 

  107. H. G. Kilian, M. Pietralla (Polymer 19, 664–672, 1978) derive from the anisotropy A of the thermal diffusivity α = c/pp of oriented polyethylenes that the intrinsic anisotropy Aj of the orienting, partly crystalline lamellar clusters increases with the degree of crystallinity (Ai = 7 to 26, linear extrapolation yields Ai = 2 for the fully amorphous and Ai = 50 for a completely crystalline cluster); the average degree of orientation of the lamellae, <cos2d>, as determined from thermal measurements agrees very well with X-ray data; the observed increase of orientation with draw ratio is more rapid than it would be in affine deformation.

    Google Scholar 

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  1. Laboratoire des Polymères, Département des Matériaux, École Polytechnique Fédérale de Lausanne, Suisse

    Professor Dr. rer. nat. Hans-Henning Kausch-Blecken von Schmeling

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  1. Professor Dr. rer. nat. Hans-Henning Kausch-Blecken von Schmeling
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Kausch-Blecken von Schmeling, HH. (1978). Structure and Deformation. In: Polymer Fracture. Polymers, vol 2. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-96460-2_2

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  • DOI: https://doi.org/10.1007/978-3-642-96460-2_2

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