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On the Connection between Effective Hamiltonians and Propagators

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Many-Body Methods in Quantum Chemistry

Part of the book series: Lecture Notes in Chemistry ((LNC,volume 52))

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Abstract

A purely algebraic approach to Green’s functions is presented. It allows the computation of Green’s functions by means of an eigenvalue problem as small as possible for a given accuracy. This is achieved by formulating a unitary transformation of the Hamiltonian matrix. The method is applied as an example to the particle-particle propagator. The case of a one-particle Hamiltonian is treated exactly for illustrative purposes and a unitary transformation is derived. A connection to effective Hamiltonian theory can be drawn. The general problem of a two-particle Hamiltonian is discussed as well and it is found that a quite straightforward generalization of the theory of one-particle Hamiltonians gives rise to systematic approximation schemes. The third order approximation scheme is derived and compared with the Algebraic Diagrammatic Construction approximation.

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© 1989 Springer-Verlag Berlin Heidelberg

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Tarantelli, A., Cederbaum, L.S. (1989). On the Connection between Effective Hamiltonians and Propagators. In: Kaldor, U. (eds) Many-Body Methods in Quantum Chemistry. Lecture Notes in Chemistry, vol 52. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-93424-7_11

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  • DOI: https://doi.org/10.1007/978-3-642-93424-7_11

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-51027-7

  • Online ISBN: 978-3-642-93424-7

  • eBook Packages: Springer Book Archive

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