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Catalysis pp 159–218Cite as

Surface Structural Chemistry

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Part of the book series: Catalysis ((CATALYSIS,volume 7))

Abstract

The atomic geometry and electronic structure of surface atoms are responsible for the chemical and electronic properties of surfaces. The atomic and electronic structures are rarely separable. However, the experimental techniques used to study these two structural features are different, and therefore they are often separately investigated and discussed. In this review we shall give an overview of what we know about the atomic structure of surfaces and adsorbed monolayers, the methods used to obtain this information, and point out the importance and relation of surface structure to chemical bonding and heterogeneous catalysis.

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References

  1. Wood, E. A.: J. Appl. Phys. 35, 1306 (1964)

    Article  CAS  Google Scholar 

  2. Somorjai, G. A., Van Hove, M. A.: Adsorbed Monolayers on Solid Surfaces, Structure and Bonding, Vol. 38. Berlin, Heidelberg, New York: Springer 1979

    Google Scholar 

  3. Ertl, G., Küppers. J.: Low Energy Electrons and Surface Chemistry. Weinheim: Verlag Chemie 1974

    Google Scholar 

  4. Heugier, M.: Surf. Sci. 19, 159 (1970)

    Article  Google Scholar 

  5. Laramore, G. E., Houston, J. E., Park, R. L.: J. Vac. Sci. Technol. 10, 196 (1973)

    Article  CAS  Google Scholar 

  6. Jagodzinski, H., Moritz. W., Wolf, D.: Surf. Sci. 77, 233 (1978)

    Article  CAS  Google Scholar 

  7. Ertl, G., Schillinger, D.: J. Chem. Phys. 66, 2569 (1977)

    Article  CAS  Google Scholar 

  8. Pendry, J. B.: Low Energy Electron Diffraction. New York —London: Academic Press 1974

    Google Scholar 

  9. Van Hove, M. A., Tong, S. Y.: Surface Crystallography by LEED. In: Springer Ser. Chem. Phys. 2. Berlin, Heidelberg, New York: Springer 1979

    Google Scholar 

  10. Tong, S. Y.: A Review of Surface Crystallography by Low-Energy Electron Diffraction. In: Electron Diffraction 1927–1977. Dobson, P. J., Pendry, J. B., Humphreys, C. J. (eds.). London: The Institute of Physics, Bristol 1978, pp. 270–280

    Google Scholar 

  11. Van Hove, M. A.: Surface Crystallography and Bonding. In: The Nature of the Surface Chemical Bond. Rhodin, T. N., Ertl, G. (eds.). Amsterdam—New York—Oxford: North Holland 1979, pp. 275–312

    Google Scholar 

  12. Heinz, K., Muller, K.: LEED Intensities-Experimental Progress and New Possibilities of Surface Structure Determination. In: Structural Studies of Surfaces, Springer Tracts in Modern Physics, Vol. 91. Berlin, Heidelberg, New York: Springer Verlag 1982, pp. 1–53

    Google Scholar 

  13. Ibach, H., Mills, D. L.: Electron Energy Loss Spectroscopy and Surface Vibrations. New York: Academic Press 1982

    Google Scholar 

  14. Sexton, B.: Appl. Phys. A26, 1 (1981)

    Google Scholar 

  15. Thiry, P. A.: J. Electron Spectrosc. Relat. Phenom. 30, 261 (1983)

    Article  CAS  Google Scholar 

  16. Froitzheim, H., Ibach, H., Lehwald, S.: Rev. Sci. Instrum. 46, 1325 (1975)

    Article  CAS  Google Scholar 

  17. Evans, E., Mills, D. L.: Phys. Rev. B5, 4126 (1972)

    Article  Google Scholar 

  18. Ibach, H.: Surf. Sci. 66, 56 (1977)

    Article  CAS  Google Scholar 

  19. Evans, E., Mills, D. L.: Phys. Rev. B5, 4126 (1971)

    Google Scholar 

  20. Newns, D. M.: Phys. Lett. 60A, 461 (1977)

    Article  Google Scholar 

  21. Persson, B. N. J.: Solid State Commun. 24, 573 (1977)

    Article  CAS  Google Scholar 

  22. Ibach, H., Bruchmann, D.: Phys. Rev. Lett. 44, 36 (1980)

    Article  CAS  Google Scholar 

  23. Froitzheim, H., Ibach, H., Lehwald, S.: Phys. Rev. Lett. 36, 1549 (1976)

    Article  CAS  Google Scholar 

  24. Katz, J. E., Davies, P. W., Crowell, J. E., Somorjai, G. A.: Rev. Sci. Instrum. 53, 785 (1982)

    Article  CAS  Google Scholar 

  25. Cabrera, A. L., Spencer, N. D., Kozak, E., Davies, P. W., Somorjai, G. A.: Rev. Sci. Instrum. 53, 20 (1982)

    Article  Google Scholar 

  26. Menadue, J. F.: Acta Cryst. A28, 1 (1972)

    CAS  Google Scholar 

  27. Maserd, N., Kinniburgh, C. G., Pendry, J. B.: J. Phys. C10, 1 (1977)

    Article  Google Scholar 

  28. Aberdam, D.: Electron Diffraction in the Medium-Energy Range. In: Electron Diffraction 1927–1977. Dobson, P. J., Pendry, J. B., Humphreys, C. J. (eds.). London: The Institute of Physics, Bristol 1978, pp. 239–253

    Google Scholar 

  29. Smith, N. V.: Angular Dependent Photoemission. In: Photoemission in Solids I, Topics in Applied Physics, Vol. 26. Cardona, M., Ley, L. (eds.). Berlin, Heidelberg, New York: Springer 1978. p. 237

    Google Scholar 

  30. Feuerbacher, B., Fitton, B., Willis, R. F. (eds.): Photoemission and the Electronic Properties of Surfaces. New York: John Wiley & Sons 1978

    Google Scholar 

  31. Rosenblatt, D. H., Kevan, S. D., Tobin, J. G., Davis, R. F., Mason, M. G., Denley, D. R., Shirley, D. A., Huang, Y., Tong, S. Y.: Phys. Rev. B26, 1812 (1982)

    CAS  Google Scholar 

  32. Barton, J. J., Bahr, C. C., Hussain, Z., Robey, S-W., Tobin, J. G., Klebanoff, L. E., Shirley, D. A.: Phys. Rev. Lett., 51, 272 (1983)

    Article  CAS  Google Scholar 

  33. Wilch, H.: Atomic and Molecular Scattering from Surfaces — Elastic Scattering. In: Topics in Surface Chemistry. Kay, E., Bagus, P. S. (eds.). New York: Plenum 1978, p. 135

    Chapter  Google Scholar 

  34. Engel, T., Rieder, K. H.: Structural Studies of Surfaces with Atomic and Molecular Beam Diffraction. In: Structural Studies of Surfaces, Springer Tracts in Modern Physics, Vol. 91. Berlin, Heidelberg, New York: Springer-Verlag 1982, pp. 55–180

    Google Scholar 

  35. Savis, F. W., Van der Veen, J. F.: Analysis of Surface Structure and Composition by Ion-Scattering Spectroscopy. In: Proc. 7th Intern. Vac. Congr. & 3rd Intern. Conf. Solid Surfaces, Vienna, 1977, p. 2503

    Google Scholar 

  36. Feldman, L. C., Kauffman, R. L., Silverman, P. J., Zuhr, R. A., Barrett, J. H.: Phys. Rev. Lett. 39, 38 (1978)

    Article  Google Scholar 

  37. Heiland, W., Taglauer, E.: Surf. Sci. 68, 96 (1977)

    Article  CAS  Google Scholar 

  38. Bell, A. T., Hair, M. L. (eds.): Vibrational Spectroscopies for Adsorbed Species. Washington, D.C.: American Chemical Society 1980

    Google Scholar 

  39. Haller. G. T.: Catal. Rev. Sci. Eng. 23. 477 (1981)

    Article  CAS  Google Scholar 

  40. Caudano. R., Gilles, J. M.. Lucas. A. A. (eds.): Vibrations at Surfaces. New York: Plenum 1982

    Google Scholar 

  41. Brundle. C. R.. Morawitz. H.: Vibrations at Surfaces. Amsterdam -Oxford-New York: Elsevier 1983

    Google Scholar 

  42. Dubois, L. H., Hansma, P. K., Somorjai. G. A.: Appl. Surf. Sci. 6. 173 (1980)

    Article  CAS  Google Scholar 

  43. Yates, J. T., Jr.. Duncan. T. M.. Worley, S. D.. Vaughn, R. W.: J. Chem. Phys. 70, 1219 (1979)

    Article  CAS  Google Scholar 

  44. Kroeker, R. M., Kasha. W. C., Hansma, P. K.: J. Catal. 61, 87 (1980)

    Article  CAS  Google Scholar 

  45. Chiang, S., Tobin. R. G.. Richards, P. L.: J. Electron Spectrosc. Relat. Phenom. 29, 113 (1983)

    Article  CAS  Google Scholar 

  46. Chang, R. K., Furtak, T. E. (eds.): Surface Enhanced Raman Scattering. New York: Plenum 1981

    Google Scholar 

  47. Campion, A.: J. Electron Spectrosc. Relat. Phenom. 29, 397 (1983)

    Article  CAS  Google Scholar 

  48. Hall, P. G., Wright, C. J.: Chemical Physics of Solids and Their Surfaces 7, 89 (1978)

    Article  Google Scholar 

  49. Kroeker, R. M., Hansma, P. K.: Catal. Rev.-Sci. Eng. 23. 553 (1981)

    Article  CAS  Google Scholar 

  50. Low, M. J. D., Parodi, G. A.: Applied Spectrosc. 34, 76 (1980)

    Article  CAS  Google Scholar 

  51. Madey, T. E., Yates, J. T., Jr.: Surf. Sci. 63, 203 (1977)

    Article  CAS  Google Scholar 

  52. Knotek, M. L., Jones, V. D., Rehn, V.: Phys. Rev. Lett. 43, 300 (1979)

    Article  CAS  Google Scholar 

  53. Winograd. N., Garrison, B. J.: Acc. Chem. Res. 13. 406 (1980)

    Article  CAS  Google Scholar 

  54. Madey, T. E.. Netzer. F. P., Houston, J. E., Hanson, D. M., Stockbauer. R.: The Determination of Molecular Structure at Surfaces Using Angle Resolved Electron and Photon Stimulated Desorption. In: Proceedings of DIET-1 Workshop, Williamsburg, 1982. New York: Springer Verlag (1983)

    Google Scholar 

  55. Bradshaw, A. M., Cederbaum. L. S., Domcke, W.: Ultraviolet Photoelectron Spectroscopy of Gases Adsorbed on Metal Surfaces. Structure and Bonding, Vol. 24. Berlin, Heidelberg, New York: Springer 1975, pp. 133–169

    Google Scholar 

  56. Gustafsson, T.: Valence Photoemission from Adsorbates. In: Photoemission and the Electronic Properties of Surfaces. Feuerbacher, B., Fitton, B., Willis. R. F. (eds.). London: Wiley 1978, p. 353–380

    Google Scholar 

  57. Rye, R. R.. Madey, T. E., Houston, J. E., Holloway, P. H.: J. Chem. Phvs. 69, 1504 (1978)

    Article  CAS  Google Scholar 

  58. Fuggle, J. C.: High Resolution Auger Spectroscopy of Solids and Surfaces. In: Electron Spectroscopy: Theory, Techniques and Applications, Vol. 4. Brundle, C. R., Baker, A. D. (eds.). New York: Academic Press (1981), pp. 85–152

    Google Scholar 

  59. Hagstrum, H. D.: Studies of Adsorbate Electronic Structure Using Ion Neutralization and Photoemission Spectroscopies. In: Electron and Ion Spectroscopies of Solids. Fiermans, L., Vennik, J., Dekeyser, W. (eds.). New York: Plenum 1978, pp. 273–323

    Google Scholar 

  60. Johnson, P. D.. Delchar. T. A.: Surf. Sci. 77, 400 (1978)

    Article  CAS  Google Scholar 

  61. Conrad, H., Ertl, G., Küppers, J.. Wang, S. W., Gerard, K., Haberland, H.: Phys. Rev. Lett. 42. 1682 (1979)

    Article  Google Scholar 

  62. Boiziau. C.: Scanning Electron Microsc. 1982, 949

    Google Scholar 

  63. Citrin, P. H., Eisenberger, P.. Hewitt. R. C: J. Vac. Sci. Technol. 15. 449 (1978)

    Article  Google Scholar 

  64. Stohr, J., Jaeger, R., Brennan, S.: Surf. Sci. 117, 503 (1982)

    Article  Google Scholar 

  65. Stern, E. A., Sayers, D. E., Lytle, F. W.: Phys. Rev. B11, 4836 (1975)

    Article  CAS  Google Scholar 

  66. Stohr, J., Jaeger, R.: Phys. Rev. B26, 4111 (1982)

    Article  CAS  Google Scholar 

  67. den Boer, M. L., Einstein, T. L., Elam. W. T., Park, R. L.. Roelofs, L. D.: J. Vac. Sci. Technol. 17. 59 (1980)

    Article  Google Scholar 

  68. Cowley, J. M.: Diffraction Physics. Amsterdam: North Holland 1975

    Google Scholar 

  69. Isaacson. M. S., Langmore. J.. Parker, N. W., Kopf, D., Utlaut, M.: Ultramicroscopy 1. (1976)

    Google Scholar 

  70. Yagi, K., Takajanagi, K., Kobayashi, K., Osakabe, N., Tanishiro, Y., Honjo, G.: Electron Micrsocopy. 1978, Vol. I (Proc. 9th Intern. Congr. on Ed. Micr., Toronto, 1978 ). Sturgess, J. M. (ed.). Toronto: Microscopical Society of Canada 1978

    Google Scholar 

  71. Yates, J. T., Jr.: The Thermal Desorption of Adsorbed Species. In: Methods of Experimental Physics, Vol. 22, Park, R. L. (ed.). New York: Academic Press (1985), pp. 425 - 464

    Google Scholar 

  72. Holzl, J., Schulte, F. K., Wagner, H.: Work Function of Metals. In: Springer Tracts Mod. Phys. 85, 1 (1979)

    Article  Google Scholar 

  73. Van Hove, M. A., Koestner, R. J., Stair, P. C., Biberian, J. P., Kesmodel, L. L., Bartos, I., Somorjai, G. A.: Surf. Sci. 103, 189 (1981); 103, 218 (1981)

    Article  Google Scholar 

  74. Adams, D. L., Nielson, H. B., Van Hove, M. A., Ignatiev, A.: Surf. Sci. 104, 47 (1981)

    Article  CAS  Google Scholar 

  75. King, D. A.: Physica Scripta T4, 34 (1983)

    Article  Google Scholar 

  76. Tong, S. Y., Maldonado, A. L.: Surf. Sci. 78, 459 (1978)

    Article  CAS  Google Scholar 

  77. Duke, C. B.: Appl. Surf. Sci. 11/12, 1 (1982)

    Article  Google Scholar 

  78. Chadi, D. J.: Phys. Rev. Lett. 41, 1062 (1978)

    Article  CAS  Google Scholar 

  79. Northrup, J. E., Cohen, M. L.: Phys. Rev. Lett. 49, 1349 (1982)

    Article  CAS  Google Scholar 

  80. Eastman, D. E.: J. Vac. Sci. Technol. 17, 492 (1980)

    Article  CAS  Google Scholar 

  81. Legg, K. O., Jona, F., Jepsen, D. W., Marcus, P. M.: Phys. Rev. B16, 5271 (1977)

    Article  CAS  Google Scholar 

  82. Shih, H. D., Jona, F., Jepsen, D. W., Marcus, P. M.: Phys. Rev. Lett. 46, 731 (1981)

    Article  CAS  Google Scholar 

  83. Shih, H. D., Jona, F., Jepsen, D. W., Marcus, P. M.: Surf. Sci. 60, 445 (1976)

    Article  CAS  Google Scholar 

  84. Strong, R. L., Firey, B., de Wette, F. W., Erskine, J. L.: J. Electron Spectrosc. Relat. Phenom. 29, 187 (1983)

    Article  CAS  Google Scholar 

  85. Behm, R. J., Penka, V., Cattania, M.-G., Kristmann, K., Ertl, G.: J. Chem. Phys. 78, 7486 (1983)

    Article  CAS  Google Scholar 

  86. Sachtler, J. W. A., Van Hove, M. A., Biberian, J. P., Somorjai, G. A.: Surf. Sci. 110, 19 (1981)

    Article  CAS  Google Scholar 

  87. Somorjai, G. A.: Chemistry in Two Dimensions, Surfaces. Ithaca and London: Cornell University Press (1981)

    Google Scholar 

  88. Yates, J. T., Jr., Madey, T. E., Campuzano, J. C. In: The Physics and Chemistry of Solid Surfaces and Heterogeneous Catalysis. King, D. A., Woodruff, D. P. (eds.), in press

    Google Scholar 

  89. Kesmodel, L. L., Baetzold, R., Somorjai, G. A.: Surf. Sci. 66, 299 (1977)

    Article  CAS  Google Scholar 

  90. Casalone, G., Cattania, M. G., Simonetta, M.: Surf. Sci. 103, L121 (1981)

    Article  CAS  Google Scholar 

  91. Casalone, G., Cattania, M. G., Merati, F., Simonetta, M.: Surf. Sci. 120, 171 (1982)

    Article  CAS  Google Scholar 

  92. Felter, T., Weinberg, W. H.: Surf. Sci. 103, 265 (1981)

    Article  CAS  Google Scholar 

  93. Lloyd, D. R., Quinn, C. M., Richardson, N. V.: Angle-Resolved Ultraviolet Electron Spectroscopy of Clean Surfaces and Surfaces with Adsorbed Layers. In: Surface and Defect Properties of Solids, Vol. VI. Roberts, M. W., Thomas, J. M. (ed.). London: Chemical Society (1976), pp. 179–217

    Google Scholar 

  94. Nyberg, G. L., Richardson, N. V.: Surf. Sci. 85, 335 (1979)

    Article  CAS  Google Scholar 

  95. Dubois, L. H., Somorjai, G. A.: Surf. Sci. 91, 514 (1980)

    Article  CAS  Google Scholar 

  96. Crowell, J. E., Somorjai, G. A.: Appl. Surf. Sci. 19, 73 (1984)

    Article  CAS  Google Scholar 

  97. Yang, A. C, Garland, C. W.: J. Phys. Chem. 61, 1504 (1957)

    Article  Google Scholar 

  98. Koestner, R. J., Van Hove, M. A., Somorjai, G. A.: Surf. Sci. 107, 439 (1981)

    Article  CAS  Google Scholar 

  99. Van Hove, M. A., Koestner, R. J., Frost, J. C., Somorjai, G. A.: Phys. Rev. Lett. 50, 903 (1983)

    Article  Google Scholar 

  100. Chini, P., Longoni, V., Albano, V. G.: Adv. Organomet. Chem. 14, 285 (1976)

    Article  CAS  Google Scholar 

  101. Castner, D. G., Sexton, B. A., Somorjai, G. A.: Surf. Sci. 71, 519 (1978)

    Article  CAS  Google Scholar 

  102. Thiel, P. A., Williams, E. D., Yates, J. T., Jr., Weinberg, W. H.: Surf. Sci. 84, 54 (1979)

    Article  CAS  Google Scholar 

  103. Koel, B. E., Somorjai. G. A.: J. Electron Spectrosc. Relat. Phenom. 29, 287 (1983)

    Article  CAS  Google Scholar 

  104. Lin, R. F., Koestner, R. J., Van Hove, M. A., Somorjai, G. A.: Surf. Sci., 134, 161 (1983)

    Article  CAS  Google Scholar 

  105. Van Hove, M. A., Lin, R. F., Koestner, R. J., Koel, B. E., Mate, M., Crowell, J. E., Somorjai, G. A.: LEED and HREELS Studies of Benzene Adsorbed on Rh(l 11). Proceed. Interdisc. Surf. Sci. Conf. (ISSC-6) April, 1983. University of Warwick, UK, in press

    Google Scholar 

  106. Van Hove, M. A., Lin, R. F., Somorjai, G. A.: Phys. Rev. Lett., 51, 778 (1983)

    Article  Google Scholar 

  107. Koel, B. E., Crowell, J. E., Mate, C. M., Somorjai, G. A.: J. Phys. Chem. 88, 1988 (1984)

    Article  CAS  Google Scholar 

  108. Lehwald. S.. Ibach, H., Demuth, J. E.: Surf. Sci. 78, 577 (1978)

    Article  CAS  Google Scholar 

  109. Nieuwenhuys, B. E., Hagen, D. I., Rovida, G., Somorjai, G. A.: Surf. Sci. 59, 155 (1976)

    Article  CAS  Google Scholar 

  110. Stair. P. C., Somorjai, G. A.: J. Chem. Phys. 67, 4361 (1977)

    Article  CAS  Google Scholar 

  111. Koestner, R. J.. Van Hove, M. A., Somorjai. G. A.: J. Phys. Chem. 87. 203 (1983)

    Article  CAS  Google Scholar 

  112. Kesmodel, L. L., Dubois, L. H., Somorjai, G. A.: J. Chem. Phys. 70, 2180 (1979)

    Article  CAS  Google Scholar 

  113. Koestner, R. J., Van Hove, M. A., Somorjai, G. A.: Surf. Sci. 121, 321 (1982)

    Article  CAS  Google Scholar 

  114. Skinner, P., Howard, M. W., Oxton, I. A., Kettle, S. F. A., Powell, D. B., Sheppard, N.: J. Chem. Soc., Faraday Trans. 2, 77. 1203 (1981)

    Article  CAS  Google Scholar 

  115. Dubois. L. H., Castner, D. G., Somorjai, G. A.: J. Chem. Phys. 72, 5234 (1980)

    Article  CAS  Google Scholar 

  116. Koel, B. E., Crowell, J. E., Bent, B. E., Mate, C. M., Somorjai, G. A.: J. Phys. Chem., to be published

    Google Scholar 

  117. Ibach, H., Mills, D. L.: Electron Energy Loss Spectroscopy and Surface Vibrations. New York: Academic Press (1982), p. 326

    Google Scholar 

  118. Gates, J. A., Kesmodel, L. L.: Surf. Sci. 124, 68 (1983)

    Article  CAS  Google Scholar 

  119. Minot, C, Van Hove, M. A., Somorjai, G. A.: Surf. Sci. 127, 441 (1982)

    Article  Google Scholar 

  120. Avery. N.: to be published and private communication

    Google Scholar 

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Authors and Affiliations

  1. Cooperative Institute for Research in Environmental Sciences, Department of Chemistry, University of Colorado, Boulder, Colorado, 80309, USA

    B. E. Koel

  2. Materials and Molecular Research Division Lawrence Berkeley Laboratory, Department of Chemistry, University of California, Berkeley, California, 94720, USA

    G. A. Somorjai

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  1. B. E. Koel
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  2. G. A. Somorjai
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Editors and Affiliations

  1. CSIRO Division of Materials Science Catalysis and Surface Science Laboratory, University of Melbourne, Victoria, Australia

    John R. Anderson

  2. Dept. of Chemical Engineering, Stanford University, 94305, Stanford, CA, USA

    Michel Boudart

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Koel, B.E., Somorjai, G.A. (1985). Surface Structural Chemistry. In: Anderson, J.R., Boudart, M. (eds) Catalysis. Catalysis, vol 7. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-93281-6_3

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  • DOI: https://doi.org/10.1007/978-3-642-93281-6_3

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