Stärke, Dextrine, Kohlehydrate der Inulingruppe, Cellulosen usw

  • Géza Zemplén

Zusammenfassung

Nach den wahrsclieinlichsten Annahmen stellt man sich Stärke heute als Ketten von Maltosegruppen vor, die nach den α-l, 4-Glykosylresten aufgebaut sind. Dies führt zu der Vorstellung von einem prinzipiell ähnlichen Bau wie bei der Cellulose (s. dort), nämlich einer Anordnung der Glykosereste nach einer diagonalen Schraubung. Die Maltoseketten der Stärke sind zum Unterschied von den Cellobioseketten der Cellulose zickzackförmig2 Weitere Arbeiten, die sich mit der Konstitution der Stärke befassen3. - Malfitano und Catoire4 glauben, daß die Stärkemycellen Komplexe verschiedener Ordnung der Amylose- phosphate imd der Amylosesilicate von ErdalkaHen sind. Die Komplexe sind im Werner sehen Sinne zu verstehen. Das Zentralradikal ist PO4 oder SiO2; es ist von polymeren Stärkemolekülen umgeben; an der Peripherie liegen austauschbare Metallionen.

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