Metallation of Hetero-Substituted Unsaturated Systems
This chapter deals with the generation of polar organometallic intermediates of the type , and in which X represents a group containing a heteroatom directly linked to the double-bond system. Practically all these polar metal derivatives are generated by direct metallation of the corresponding unsaturated systems , and or the isomeric systems and . The intermediates in which X is halogen (mostly chlorine) are stable only at very low temperatures .
KeywordsVinyl Ether Lithium Compound Ethyl Vinyl Ether Potassium Compound Vinyl Sulfide
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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© Springer-Verlag Berlin Heidelberg 1987