Abstract
Irradiation of aryl aldoximes in a variety of solvents leads to the formation of amides [1] besides geometrical isomerization. Syn-benzaldehyde oxime (1), for instance, gives benzamide (2). It was suggested [1] that this Beckmann type rearrangement might involve oxaziridines as intermediates (see below).
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Schönberg, A. (1968). Photoisomerizations involving nitrogen compounds. In: Preparative Organic Photochemistry. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-87918-0_6
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DOI: https://doi.org/10.1007/978-3-642-87918-0_6
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