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Chemistry of Humic Acids and Related Pigments

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Abstract

Humic acids and related pigments, collectively referred to as humic substances, are widely distributed in soils, natural waters, marine and lake sediments, peat bogs, carbonaceous shales, lignites, brown coals and other miscellaneous deposits [1–5]. In addition, trace amounts may be present in plants [6] and certain carbonaceous meteorites [7]. Szalay [8] concluded that the amount of organic carbon in the earth as humic acids (60 x 1011 tons) exceeds that which occurs in living organisms (7 x 1011 tons).

Appreciation is expressed to the National Science Foundation (Grants GP 1938 and GA 348) for support of research in organic geochemistry.

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References

  1. Felbeck, G. T., Jr.: Structural chemistry of soil humic substances. Advan. Agron. 17, 327–368 (1965).

    Article  Google Scholar 

  2. Dubach, P., and N. C. Mehta: The chemistry of soil humic substances. Soils Fertilizers 26, 293–300(1963).

    Google Scholar 

  3. Kononova, M. M.: Soil organic matter, 2nd ed. New York: Pergamon Press, Inc. 1966.

    Google Scholar 

  4. Scheffer, F., u. B. Ulrich: Humus und Humusdüngung, Bd. I. Stuttgart, Germany: Ferdinand Enke 1960.

    Google Scholar 

  5. Swain, F. M.: Geochemistry of humus. In: Organic geochemistry (I. A. Breger, ed.), p. 81–147. New York: Pergamon Press, Inc. 1963.

    Google Scholar 

  6. Raudnitz, H.: Occurrence of humic acid in leaves. Chem. Ind. (London) 1957, 1950–1951 (1957).

    Google Scholar 

  7. Nagy, B.: Investigations of the orgueil carbonaceous meteorite. Geol. Foren. Stockholm Forh. 88, 325–372(1966).

    Article  Google Scholar 

  8. Szalay, A.: Cation exchange properties of humic acids and their importance in the geochemical enrichment of UO2 ++ and other cations. Geochim. Cosmochim. Acta 28, 1605–1614 (1964).

    Article  Google Scholar 

  9. Stevenson, F. J.: Gross chemical fractionation of organic matter. In: Methods of Soil Analysis, part 2 (C. A. Black et al, eds.), p. 1409–1421. Madison, Wisconsin: American Society of Agronomy 1965.

    Google Scholar 

  10. Whitehead, D. C., and J. Tinsley: The biochemistry of humus formation. J. Sci. Food Agr. 12, 849–857(1963).

    Article  Google Scholar 

  11. Breger, I. A.: Chemical and structural relationship of lignin to humic substances. Fuel 30, 204–208(1951).

    Google Scholar 

  12. Flaig, W.: The chemistry of humic substances. In: The Use of Isotopes in Soil Organic Matter Studies, p. 103–127. New York: Pergamon Press, Inc. 1966.

    Google Scholar 

  13. Pauli, F. W.: Fluorochrome adsorption studies on decomposing plant residues. I. Decomposition studies. S. African J. Agr. Sci. 4, 123–134 (1961).

    Google Scholar 

  14. Swaby, R. J., and J. N. Ladd: Stability and origin of soil humus. In: The Use of Isotopes in Soil Organic Matter Studies, p. 153–159. New York: Pergamon Press, Inc. 1966.

    Google Scholar 

  15. Stevenson, F. J., and S. N. Tilo: Nitrogenous constituents of deep-sea sediments. Proc. 3rd. Intern. Meeting on Org. Geochem. (in press).

    Google Scholar 

  16. Avgushevich, I.V., and N. M. Karavayev: Determination of acid groups in humic acids and in some organic compounds. Soviet Soil Sci. (English Transl.) 1965, 416–422 (1965).

    Google Scholar 

  17. Schnitzer, M., and U. C. Gupta: Determination of acidity in soil organic matter. Soil Sci. Soc. Am. Proc. 29, 274–277 (1965).

    Article  Google Scholar 

  18. Wright, J. R., and M. Schnitzer: Oxygen-containing functional groups in the organic matter of the Ao and Bh horizons of a podzol. Trans. 7th Intern. Congr. Soil Sci. 2, 120–127 (1960).

    Google Scholar 

  19. Moschopedis, S. E.: Studies in humic acid chemistry. III — The reaction of humic acids with diazonium salts. Fuel 4, 425–435 (1962).

    Google Scholar 

  20. Wood, J. C., S. E. Moschopedis, and W. Den Hertog: Studies in humic acid chemistry. II – Humic anhydrides. Fuel 40, 491–502 (1961).

    Google Scholar 

  21. Blom, L., L. Edelhausen, and D.W. van Krevelen: Chemical structure and properties of coal. XVIII—Oxygen groups in coal and related products. Fuel. 36, 135–153 (1957).

    Google Scholar 

  22. Farmer, V.C., and R. I. Morrison: Chemical and infrared studies on phragmites peat and its humic acid. Sci. Proc. Roy. Dublin Soc., Ser. A, 1, 85–104 (1960).

    Google Scholar 

  23. Butler, J. H. A., and F. J. Stevenson: Functional groups of soil humic acids. Unpublished.

    Google Scholar 

  24. Dubach, P., N. C. Mehta, T. Jakab, F. Martin, and N. Roulet: Chemical investigations on soil humic substances. Geochim. Cosmochim. Acta 28, 1567–1578 (1964).

    Article  Google Scholar 

  25. Martin, F., P. Dubach, N. C. Mehta u. H. Deuel: Bestimmung der funktionellen Gruppen von Huminstoffen. Z. Pflanzenernaehr. Dueng. Bodenk. 103, 27–39 (1963).

    Article  Google Scholar 

  26. Jones, R., and S. Sternhell: Chemistry of brown coals. VII—Estimation of active hydrogen. Fuel 41, 457–469(1962).

    Google Scholar 

  27. Schnitzer, M., and J. G. Desjardins: Molecular and equivalent weights of the organic matter of a podzol. Soil Sci. Soc. Am. Proc. 26, 362–365 (1962).

    Article  Google Scholar 

  28. Wright, J. R., and M. Schnitzer: Oxygen-containing functional groups in the organic matter of a podzol soil. Nature 184, 1462–1463 (1959).

    Article  Google Scholar 

  29. Lynch, B. M., J. D. Brooks, R. A. Durie, and S. Sternhell: Chemistry of humic acids formed by alkali treatment of brown coals. Sci. Proc. Roy. Dublin Soc., Ser. A, 1, 123–131 (1960).

    Google Scholar 

  30. Schnitzer, M., and U. C. Gupta: Some chemical characteristics of the organic matter extracted from the O and B2 horizons of a gray wooded soil. Soil Sci. Soc. Am. Proc. 28, 374–377 (1964).

    Article  Google Scholar 

  31. Barton, D. H. R., and M. Schnitzer: A new experimental approach to the humic acid problem. Nature 198, 217–218(1963).

    Article  Google Scholar 

  32. Forsyth, W. G. C.: The characterization of the humic complexes of soil organic matter. J. Agr. Sci. 37, 132–138 (1947).

    Article  Google Scholar 

  33. Wagner, G. H., and F. J. Stevenson: Structural arrangement of functional groups in soil humic acid as revealed by infrared analyses. Soil Sci. Soc. Am. Proc. 29, 43–48 (1965).

    Article  Google Scholar 

  34. Schnitzer, M., and S. I. M. Skinner: The carbonyl group in a soil organic matter preparation. Soil Sci. Soc. Am. Proc. 29, 400–405 (1965).

    Article  Google Scholar 

  35. Friedman, S., M. L. Kaufman, W. A. Steiner, and I. Wender: Determination of hydroxyl content of vitrains by formation of trimethylsilyl ethers. Fuel 40, 33–36 (1961).

    Google Scholar 

  36. Schnitzer, M., and S. I. M. Skinner: A polarographic method for the determination of carbonyl groups in soil humic compounds. Soil Sci. 101, 120–124 (1966).

    Article  Google Scholar 

  37. Brooks, J. D., R. A. Durie, B.M. Lynch, and S. Sternhell: Infra-red spectral changes accompanying methylation of brown coals. Australian J. Chem. 13, 179–183 (1960).

    Google Scholar 

  38. Schnitzer, M.: The application of infrared spectroscopy to investigations on soil humic compounds. Can. Spect. 10, 121–127 (1965).

    Google Scholar 

  39. Durie, R. A., and S. Sternhell: Some quantitative infrared absorption studies of coals, pyrolysed coals, and their acetyl derivatives. Australian J. Chem. 12, 205–217 (1959).

    Article  Google Scholar 

  40. Cěh, M., and D. Hadži: Infra-red spectra of humic acids and their derivatives. Fuel 35, 77–83 (1956).

    Google Scholar 

  41. Theng, B. K., J. R. H. Wake, and A. M. Posner: The infrared spectrum of humic acid. Soil Sci. 102, 70–72(1966).

    Article  Google Scholar 

  42. Schwartz, D., and L. Asfeld: Solvation of the proton in humic acids. Nature 197, 177–178 (1963).

    Article  Google Scholar 

  43. Schwartz, D., and L. Asfeld and R. Green: The chemical nature of the carboxyl groups of humic acids and conversion of humic acids to ammonium nitrohumates. Fuel 44, 417–424 (1965).

    Google Scholar 

  44. Falk, M., and D. G. Smith: Structure of carboxyl groups in humic acids. Nature 200, 569–570 (1963).

    Article  Google Scholar 

  45. Fujii, S.: Infra-red spectra of coal: The absorption band at 1600 cm1. Fuel 42, 17–23, 341–343 (1963).

    Google Scholar 

  46. Brown, J. K., and W. F. Wyss: Oxygen groups in bright coals. Chem. Ind. (London) 1955, 1118 (1955).

    Google Scholar 

  47. Schnitzer, M., D. A. Shearer, and J. R. Wright: A study in the infrared of high-molecular weight organic matter extracted by various reagents from a podzolic B horizon. Soil Sci. 87, 252–257(1959).

    Article  Google Scholar 

  48. Moschopedis, S.W., S. C. Drivastava, J. C. Wood, and N. Berkowitz: Homogeneous liquid-phase halogenation of coal and humic acids. Fuel 42, 338–340 (1963).

    Google Scholar 

  49. Atherton, N. M., P. A. Cranwell, A. J. Floyd, and R. D. Haworth: Humic acid—I. ESR spectra of humic acids. Tetrahedron 23, 1653–1667 (1967).

    Article  Google Scholar 

  50. Steelink, C.: Free radical studies of lignin, lignin degradation products, and soil humic acids. Geochim. Cosmochim. Acta 28, 1615–1622 (1964).

    Article  Google Scholar 

  51. Steelink, C. and G. Tollin: Stable free radicals in soil humic acid. Biochim. Biophys. Acta 59, 25–34 (1962).

    Article  Google Scholar 

  52. Muhkerjee, P. N., and A. Lahiri: Polyelectrolytic behavior of humic acids. Fuel 37, 220–226 (1958).

    Google Scholar 

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Stevenson, F.J., Butler, J.H.A. (1969). Chemistry of Humic Acids and Related Pigments. In: Eglinton, G., Murphy, M.T.J. (eds) Organic Geochemistry. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-87734-6_28

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  • DOI: https://doi.org/10.1007/978-3-642-87734-6_28

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