Abstract
The multi-step and multi-photon excitation of the high-lying vibrational and electronic states of molecules using intense laser radiation open up many new possibilities in photochemistry. In Chaps.6 and 7 consideration was given to a rather obvious application of these methods, i.e., the separation and detection of atoms and molecules. We shall not discuss the more complex situation, in which intense laser light inateracts nonlinearly with complex molecules in the gas and liquid phase, in detail. But, in my opinion, it is in this region that the most promising and unexpected applications lie. This field of laser chemistry is still not clearly understood. Nevertheless, interesting results have been obtained in at least two directions which shall be discussed in this chapter.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
References
J.H. Clark, K.M. Leary, T.R. Loree, L.B. Harding: In [1.24] p.74
V.S. Letokhov: Phys. Today 30, 34 (1980)
S.L. Shapiro (ed.): Ultrashort Light Pulses, Topics Appl. Phys., Vol.18 (Springer, Berlin, Heidelberg, New York 1977)
R. Pratesi, S.A. Sacchi (eds.): Lasers in Photomedicine and Photobiology, Springer Ser. Opt. Sci., Vol.22 (Springer, Berlin, Heidelberg, New York 1980)
S.A. Rice: In [1.24] p.2
R. Hall, A. Kaldor: J. Chem. Phys. 4027 (1979)
A.H. Zewail: Phys. Today 30, 27 (1980)
Y.T. Lee, Y.R. Sher.: Phys. Today 52 (1980)
B.I. Vasilyev, N.A. Vishnyakov, V.T. Galochkin, A.Z. Grasiuk, A.P. Dyadkin, A.K. Zhigalkin, V.A. Kovalevsky, V.N. Kosinov, A.N. Orayevsky, A.N. Sukhanov, N.F. Starodubtsev: Pis’ma Zh. Eksp. Teor. Fiz. 30, 29 (1979) [in Russian]
D.M. Cox, R.V. Hall, T.A. Horsley, G.M. Kramer, P. Rabinowitz, A. Kaldor: Science 205, 390 (1979)
A. Kaldor, R.B. Hall, D.M. Cox, T.A. Horsley, P. Rabinowitz, G.M. Kramer: J. Am. Chem. Soc. 101(16), 4466 (1979)
G.I. Adushevshvili, O.N. Avatkov, V.I. Andrushchenko, V.N. Bagratashvili, A.B. Bakhtadze, V.M. Vetsko, V.S. Dolzhikov, G.G. Yesadze, V.S. Letokhov, E.A. Ryabov, G.I. Tkeshelashvili: Pis’ma Zh. Techn. Fiz. 5, 849 (1979) [in Russian]
V.N. Bagratashvili, V.N. Bourimov, L.E. Deyev, A.V. Zabolotnyk, V.S. Letokhov, G.I. Nazarenko, A.P. Sviridov, V.S. Shaidurov: Kvantovaya Elektron. 9, 425 (1982) [in Russian]
S.D. Rockwood, T.W. Hudson: Chem. Phys. Lett. 34, 542 (1975)
V.N. Bagratashvili, V.N. Bourimov, L.E. Deyev, V.S. Letokhov, A.P. Sviridov, V.S. Shaidurov: Kvantovaya Elektron. 9, 423 (1982) [in Russian]
R.C. Slater, J.H. Parks: Chem. Phys. Lett. 60, 275 (1979)
S.W. Bauer, E. Bar-Ziv, J.A. Haberman: IEEE J. QE-24, 237 (1978)
D.S. Bethune, J.R. Lankard, M.T. Loy, J. Ors, P.P. Sorokin: Chem. Phys. Lett. 57, 479 (1978)
R.A. Hill, G.A. Laguna: Opt. Commun. 32, 435 (1980)
A.N. Terenin: Photonics of Dye Molecules and Allied Organic Compounds (Nauka, Leningrad 1967) [in Russian]
G. Porter: In Research in Photobiology, ed. by A. Castellani (Plenum, New York 1977) p.11
A. Weller: ibid., p.25
A. Laubereau, W. Ka iser: In Chemical and Biochemical Applications of Lasers, Vol.2, ed. by C.B. Moore (Academic, New York 1977) p.87
A. Laubereau, A. Seilmeier, W. Kaiser: Chem. Phys. Lett. 36, 232 (1975)
P.G. Kryukov, V.S. Letokhov, Yu.A. Matveyets, D.N. Nikogosyan, A.V. Sharkov: Kvantovaya Elektron. 5, 2490 (1978) [in Russian]
J.P. Maier, A. Seilmeier, W. Kaiser: Chem. Phys. Lett. 70, 591 (1980)
A. Fendt, J.P. Maier, A. Seilmeier, W. Kaiser: In Picosecond Phenomena II, ed. by R.M. Hochstrasser, W. Kaiser, C.V. Shank, Springer Ser. Chem. Phys., Vol.14 (Springer, Berlin, Heidelberg, New York 1980) p.145
A. Laubereau, D. von der Linde, W. Kaiser: Phys. Rev. Lett. 28, 1162 (1972)
K.S. Bagdasaryan: Two-Quantum Photochemistry (Nauka, Moscow 1976) [in Russian]
A. Andreoni, R. Cubeddu, S. De Silvestri, P. Laporta, O. Svelto: Phys. Rev. Lett. 45, 431 (1980)
P.G. Kryukov, V.S. Letokhov, D.N. Nikogosyan, A.V. Borodavkin, E.I. Budovsky, N.A. Simukova: Chem. Phys. Lett. 61, 375 (1979)
D.A. Angelov, P.G. Kryukov, V.S. Letokhov, D.N. Nikogosyan, A.A. Orayevsky: Kvantovaya Elektron. 7, 1304 (1980) [in Russian]
D.A. Angelov, P.G. Kryukov, V.S. Letokhov, D.N. Nikogosyan, A.A. Orayevsky: In [8.4] p.207
D.A. Angelov, P.G. Kryukov, V.S. Letokhov, D.N. Nikogosyan, A.A. Orayevsky: Kvantovaya Elektron. 8, 595 (1981) [in Russian]
T.I. Karu, P.G. Kryukov, V.S. Letokhov, Yu.A. Matveyets, V.A. Semchishen: Appl. Phys. 24, 245 (1981)
V.S. Letokhov, Yu.A. Matveyets, V.A. Semchishen, E.V. Khoroshilova: Appl. Phys. B2S, 243 (1981)
K. Yokoyama, J. Nakamura, J. Kobayashi, S. Nagakura: Bull. Chem. Soc. Jpn. 53, 3474 (1980)
G.J. Fisher, H.E. Johns: In Photochemistry and Photobiology of Nucleic Acids, Vol.1, ed. by S.Y. Wang (Academic, New York 1976) p.180
D.N. Nikogosyan, A.V. Borodavkin, N.A. Simukova: In Picosecond Methods in Spectroscopy of Molecules Crystals and Biological Systems (UPS-78), Proceedinqs of the First Conference on Picosecond Phenomena in Spectroscopy, September 27 — October 1, 1978, Tallinn, USSR (Academy of Sciences, Tallinn 1979) p.188
N.A. Simukova, G.N. Menshonkova, E.I. Budovsky, L.B. Rubin: Dokl. Akad. Nauk SSSR 250, 1398 (1980) [in Russian]
D.N. Nikogosyan, D.A. Angelov: Dokl. Akad. Nauk SSSR 253, 733 (1980) [in Russian]
A.A. Belogurov, G.B. Zavilgelsky, D.A. Angelov, P.G. Kryukov, V.S. Letokhov, D.N. Nikogosyan: Stud. Biophys. 80, 45 (1980)
G.G. Gurzadyan, D.N. Nikogosyan, P.G. Kryukov, V.S. Letokhov, T.S. Balmukhanov, A.A. Belogurov, G.B. Zavilgelsky: Photochem. Photobiol. 33, 835 (1981)
T.I. Karu, G.S. Kalendo, V.S. Letokhov, Yu.A. Matveyets, V.A. Semchishen, N.G. Seriabriakov: Kvantovaya Elektron. 8, 2450 (1981) [in Russian]
J.K. Setlow: Radiat. Res. Suppl. 147 (1966)
H.S. Kaplan, L.E. Moses: Science 145, 21 (1964)
Additional Reading
Chapter 8
Budowsky, E.I., Nikogosyan, D.N., Oraevsky, A.A., Simukova, N.A., Yakovlev, D.Yu.: Direct and indirect action on thymine in aqueous solution by powerful laser UV radiation. Photobiochem. Photobiophys. 4, 233 (1982)
Gurzadyan, G.G., Nikogosyan, D.N., Balmukhanov, T.S., Zavilgelskii, G.B.: The study of formation of single-strand breaks in the DNA chain under picosecond laser UV irradiation. Photobiochem. Photobiophys. 4, 87 (1982)
Kuzmina, N.P., Letokhov, M.S., Matveetz, Yu.A., Khoroshi1 ova, E.V.: Nonlinear laser UV photochemistry of maleic acid in aqueous solution. Appl. Phys. B (submi tted)
Letokhov, M.S., Khoroshilova, E.V., Kuzmina, N.P., Letokhov, M.S., Matveetz, Yu.A., Shibanov, A.N., Egorov, S.E.: “Multiple Photon Processes in Molecules Induced by Picosecond UV Laser Pulses”, in Picosecond Phenomena III, ed. by K.B. Eisenthal, R.M. Hochstrasser, W. Kaiser, A. Laubereau, Springer Ser. Chem. Phys., Vol.23 (Springer, Berlin, Heidelberg, New York 1982) p.310
Nikogosyan, D.N., Angelov, D.A., Oraevsky, A.A.: Determination of parameters of excited states of DNA and RNA bases by laser UV photolysis. Photochem. Photobiol. 35, 627 (1982)
Author information
Authors and Affiliations
Rights and permissions
Copyright information
© 1983 Springer-Verlag Berlin Heidelberg
About this paper
Cite this paper
Letokhov, V.S. (1983). Laser Photochemistry and Photobiochemistry. In: Nonlinear Laser Chemistry. Springer Series in Chemical Physics, vol 22. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-87646-2_8
Download citation
DOI: https://doi.org/10.1007/978-3-642-87646-2_8
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-87648-6
Online ISBN: 978-3-642-87646-2
eBook Packages: Springer Book Archive