Skip to main content
SpringerLink
Log in
Book cover

Time-Resolved Vibrational Spectroscopy V pp 32–35Cite as

Rapid Mixing Resonance Raman Spectroscopy of Peroxidase Intermediates

  • Conference paper

Part of the book series: Springer Proceedings in Physics ((SPPHY,volume 68))

Abstract

Peroxidases are heme enzymes which catalyze reactions of hydrogen peroxide and certain other oxidants. The physiological mechanisms of these enzymes involve two oxidized intermediates known as compounds I and II. Compound I is formed by a two-electron oxidation of the resting enzyme and contains an Fe(IV) porphyrin π-radical cation. A one-electron reduction of compound I forms the compound II intermediate which contains an Fe(IV) heme.

This is a preview of subscription content, log in via an institution.

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   84.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. J. Terner and D.E. Reed (1984) Biochim. Biophys. Acta 789, 80–86.

    Article  Google Scholar 

  2. J. Terner, A.J. Sitter, and C.M. Reczek (1985) Biochim. Biophys. Acta 828, 73–80.

    Article  Google Scholar 

  3. A.J. Sitter, C.M. Reczek, and J. Terner (1985) Biochim. Biophys. Acta 828, 229–235.

    Article  Google Scholar 

  4. A.J. Sitter, C.M. Reczek, and J. Terner (1985) J. Biol. Chem. 260, 7515–7522.

    Google Scholar 

  5. A.J. Sitter, C.M. Reczek and J. Terner (1986) J. Biol. Chem. 261, 8638–8642.

    Google Scholar 

  6. A.J. Sitter, J.R. Shifflett and J. Terner (1988) J. Biol. Chem. 263, 13032–13038

    Google Scholar 

  7. C.M. Reczek, A.J. Sitter and J. Terner (1989) J. Mol. Struct. 214, 27–41.

    Article  ADS  Google Scholar 

  8. V. Palaniappan and J. Terner (1989) J. Biol. Chem. 264, 16046–16053.

    Google Scholar 

  9. W.A. Oertling and G.T. Babcock (1988) Biochemistry 27, 3331–3338.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Virginia Commonwealth University, Richmond, VA, 23284-2006, USA

    V. Palaniappan, M. M. Fitzgerald, A. M. Sullivan, J. R. Shifflett & J. Terner

Authors
  1. V. Palaniappan
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. M. Fitzgerald
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. M. Sullivan
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. J. R. Shifflett
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. J. Terner
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Department of Chemistry, School of Science & Engineering, Waseda University, Tokyo 169, Japan

    Hiroaki Takahashi

Rights and permissions

Reprints and permissions

Copyright information

© 1992 Springer-Verlag Berlin Heidelberg

About this paper

Cite this paper

Palaniappan, V., Fitzgerald, M.M., Sullivan, A.M., Shifflett, J.R., Terner, J. (1992). Rapid Mixing Resonance Raman Spectroscopy of Peroxidase Intermediates. In: Takahashi, H. (eds) Time-Resolved Vibrational Spectroscopy V. Springer Proceedings in Physics, vol 68. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-84771-4_10

Download citation

  • DOI: https://doi.org/10.1007/978-3-642-84771-4_10

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-84773-8

  • Online ISBN: 978-3-642-84771-4

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation