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Electronic Properties of Lattice Solutions for the Continuum Model of Conducting Polymers

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Part of the book series: Springer Series in Solid-State Sciences ((SSSOL,volume 107))

Abstract

The continuum version [1] of the Su-Schrieffer-Heeger model [2] may be generalized to include an external bond [3] and/or site dimerization [5] in order to describe the physical properties of non-degenerate ground state and/or diatomic polymers. We have derived the selfconsistent Bloch eigenfunctions and the ground state energy of the soliton and bipolaron lattice solutions for these models to investigate the thermodynamic stability and to calculate the wave number dependent electronic dielectric function ε(q,ω) in random phase approximation. After Kramers-Kronig transformation the loss function and the plasmon dispersion were determined and compared with results of electron energy loss experiments [4].

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© 1992 Springer-Verlag Berlin Heidelberg

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Streitwolf, H.W., Puff, H. (1992). Electronic Properties of Lattice Solutions for the Continuum Model of Conducting Polymers. In: Kuzmany, H., Mehring, M., Roth, S. (eds) Electronic Properties of Polymers. Springer Series in Solid-State Sciences, vol 107. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-84705-9_6

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  • DOI: https://doi.org/10.1007/978-3-642-84705-9_6

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-84707-3

  • Online ISBN: 978-3-642-84705-9

  • eBook Packages: Springer Book Archive

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