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Origin of 2p Core-Level XPS Satellites in the Late 3d Transition Metal Dihalides

  • S.-J. Oh
Part of the Springer Series in Solid-State Sciences book series (SSSOL, volume 81)

Abstract

The origin of satellite structures in the 2p core level photoemission spectra of the late 3d transition metal dihalides is studied. It is found that the charge-transfer model of Larsson [1] and Sawatzky et al [2,3] accounts for the positions and intensities of main and satellite peaks very well in these compounds. The parameter values in this model are reasonable, and show the expected trends along the ligand series from fluorine to bromine as well as along the transition metal series from copper to manganese. This shows that the screening response is important in the presence of a core-hole even for insulators.

Keywords

Satellite Structure Core Hole Charge Transfer Energy Valence Electronic Structure Initial Ground State 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer-Verlag Berlin Heidelberg 1988

Authors and Affiliations

  • S.-J. Oh
    • 1
  1. 1.Department of PhysicsSeoul National UniversitySeoul 151Korea

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