Polymeric, Electrically Conducting μ-(p-Diisocyanobenzene)-2, 3-naphthalocyaninatoiron(II)

  • S. Deger
  • M. Hanack
Part of the Springer Series in Solid-State Sciences book series (SSSOL, volume 63)

Abstract

We have reported [1] earlier on the synthesis and properties of one-dimensional conductors based on phthalocyaninato (Pc)-metal or tetrabenzoporphyrinato (TBP)-metal compounds linked together with ligands. The polymers, [PcML]n, where M = Fe, Co, L = pyrazine (pyz), p-diisocyanobenzene (dib), CN, M = Ru, L = pyz, dib, M = Rh, L = CN and [TBPML]n, where M = Fe, L = pyz, dib, M = Go, L = CN, show a high electrical conductivity when compared to the corresponding PcM, TBPM or the monomers PcML2 and TBPML2.

Keywords

Acetone Benzene Chloroform Iodine Oligomer 

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Copyright information

© Springer-Verlag Berlin Heidelberg 1985

Authors and Affiliations

  • S. Deger
    • 1
  • M. Hanack
    • 1
  1. 1.Lehrstuhl für Organische Chemie II, Institut für Organische ChemieUniversität TübingenTübingenFed. Rep. of Germany

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