Skip to main content
SpringerLink
Log in

Adsorbate-Surface Interactions

  • Conference paper
Dynamical Processes and Ordering on Solid Surfaces

Part of the book series: Springer Series in Solid-State Sciences ((SSSOL,volume 59))

Abstract

Calculations of the adiabatic potential energy surface for atoms and molecules interacting with metal surfaces based on the effective medium theory are reviewed. For atomic chemisorption, the full potential energy surface has been calculated in a number of cases and the properties of the interaction potential can be related to the parameters describing the atom and surface in question. For molecular chemisorption and surface reactions, the effective medium theory can be used to make comparisons between binding energies and activation energies.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. J.R. Schrieffer, J. Vac. Sci. Technol. 13, 335 (1976)

    Article  CAS  Google Scholar 

  2. J.K. Nørskov, J. Vac. Sci. Technol. 18, 420 (1981)

    Article  Google Scholar 

  3. For a recent review, see e.g. Theory of the Inhomogeneous Electron Gas, ed. S. Lundqvist and N.H. March (Plenum Press, New York, 1983)

    Google Scholar 

  4. T.H. Upton and W.A. Goddard, Phys. Rev. Lett. 42, 472 (1979)

    Article  CAS  Google Scholar 

  5. P.J. Feibelman and D.R. Hamann, Sol. St. Commun. 34, 215 (1980)

    Article  CAS  Google Scholar 

  6. C. Umrigar and J.W. Wilkins, to be published.

    Google Scholar 

  7. N.D. Lang and A.R. Williams, Phys. Rev. B18, 616 (1978)

    Google Scholar 

  8. B.I. Lundqvist, O. Gunnarsson, H. Hjelmberg and J.K. Nørskov, Surf. Sci. 89, 196 (1979)

    Article  CAS  Google Scholar 

  9. J.K. Nørskov, A. Houmøller, P. Johansson and B.I. Lundqvist, Phys. Rev. Lett. 46, 257 (1981)

    Article  Google Scholar 

  10. J.K. Nørskov and N.D. Lang, Phys. Rev. B21, 2136 (1980);

    Google Scholar 

  11. M.J. Stott and E. Zaremba, Phys. Rev. B22, 1564 (1980)

    Google Scholar 

  12. J.K. Nørskov, Phys. Rev. B26, 2875 (1982)

    Google Scholar 

  13. O.K. Andersen, H.L. Skriver, H. Nohl and B. Johansson, Pure Appl. Chem. 52, 93 (1979);

    Article  Google Scholar 

  14. O.K. Andersen, in: The electronic structure of complex systems, NATO Advanced Study Institute, ed. W. Temmerman and P. Phariseau (Plenum Press, New York, 1982)

    Google Scholar 

  15. The most comprehensive calculations are those of M.J. Puska, R.M. Nieminen and M. Manninen, Phys. Rev. B24, 3037 (1980)

    Google Scholar 

  16. C. Umrigar, M. Manninen and J.K. Nørskov, to be published

    Google Scholar 

  17. P. Nordlander, S. Holloway and J.K. Nørskov, Surf. Sci. 136, 59 (1984)

    Article  CAS  Google Scholar 

  18. D.M. Newns, Phys. Rev. 178, 1123 (1969)

    Article  CAS  Google Scholar 

  19. B. Chakraborty, S. Holloway and J.K. Nørskov, to be published.

    Google Scholar 

  20. Close to the metal atoms there is a third contribution to the interaction energy, not included in (2), describing the interaction with the, metal cores [15]. This term can in some cases contribute to energy differences along the surface, in particular on top of a surface atom. In most other cases it is negligible [15,17]

    Google Scholar 

  21. R. DiFoggio and R. Gomer, Phys. Rev. B25, 3490 (1982)

    Google Scholar 

  22. M.J. Puska, R.M. Nieminen, M. Manninen, B. Chakraborty, S. Holloway and J.K. Nørskov, Phys. Rev. Lett. 51, 1081 (1983)

    Article  CAS  Google Scholar 

  23. See, for example, P.H. Holloway, J. Vac. Sci. Technol. 18, 653 (1981)

    Article  CAS  Google Scholar 

  24. J.K. Nørskov, S. Holloway and N.D. Lang, Surf. Sci. 137, 65 (1984)

    Article  Google Scholar 

  25. S. Holloway, B.I. Lundqvist and J.K. Nørskov, Proc. of the 8th Int. Congr. on Catalysis (Berlin, BRD, 1984)

    Google Scholar 

  26. See, for example, D.W. Goodman, R.D. Kelley, T.E. Madey and J.T. Yates, J. Catal. 63, 226 (1980);

    Article  CAS  Google Scholar 

  27. E.I. Ko and R.J. Madix, Surf. Sci. 109, 221 (1980)

    Article  Google Scholar 

  28. See, for example, G. Ertl, S.B. Lee and M. Weiss, Surf. Sci. 114, 527 (1982);

    Article  CAS  Google Scholar 

  29. G. Brodén, G. Gafner and H.P. Bonzel, Surf. Sci. 84, 295 (1979)

    Article  Google Scholar 

  30. D. Lachey, M. Surman and D.A. King, Vacuum 33, 867 (1983)

    Article  Google Scholar 

  31. M. Grunze, F. Bozo, G. Ertl and M. Weiss, Appl. Surf. Sci. 1, 241 (1978)

    Article  CAS  Google Scholar 

  32. N.D. Lang, S. Holloway and J.K. Nørskov, to be published

    Google Scholar 

  33. P.J. Feibelman and D.R. Hamann, Phys. Rev. Lett. 52, 61 (1984);

    Article  CAS  Google Scholar 

  34. R.W. Joyner, J.B. Pendry, D.K. Saldin and S.R. Tennison, Surf. Sci. 138, 84 (1984)

    Article  CAS  Google Scholar 

  35. S. Andersson, P.-A. Karlsson and M. Persson, Phys. Rev. Lett. 51, 2378 (1983), and private communication

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. NORDITA, Blegdamsvej 17, DK-2100, Copenhagen, Denmark

    J. K. Nørskov

Authors
  1. J. K. Nørskov
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Osaka University, Toyonaka, Osaka 560, Japan

    Akio Yoshimori (Faculty of Engineering Science) (Faculty of Engineering Science)

  2. Department of Physics, Faculty of Science, University of Tokyo, Hongo 7-3-1, Bunkyo-ku, Tokyo 113, Japan

    Masaru Tsukada

Rights and permissions

Reprints and permissions

Copyright information

© 1985 Springer-Verlag Berlin Heidelberg

About this paper

Cite this paper

Nørskov, J.K. (1985). Adsorbate-Surface Interactions. In: Yoshimori, A., Tsukada, M. (eds) Dynamical Processes and Ordering on Solid Surfaces. Springer Series in Solid-State Sciences, vol 59. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-82423-4_13

Download citation

  • DOI: https://doi.org/10.1007/978-3-642-82423-4_13

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-82425-8

  • Online ISBN: 978-3-642-82423-4

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation