Abstract
Bombardment-induced compositional change, also termed preferential sputtering, tends to be of very wide occurrence. The causes are not clear in all cases, namely, whether a preferentially lost species is lighter, less tightly bound, larger, subject to an electronic interaction, or subject to some aspect of diffusion. Nevertheless, the loss of C from TaC [7.1],
is probably correctly taken as loss occurring because C is lighter. Loss of Pb from Pb-In [7.2],
is a reasonable example where some aspect of chemical bonding is involved.
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Kelly, R. (1984). Surface Compositional Changes by Particle Bombardment. In: Vanselow, R., Howe, R. (eds) Chemistry and Physics of Solid Surfaces V. Springer Series in Chemical Physics, vol 35. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-82253-7_7
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