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Magnetic Resonance in Surface Science

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Chemistry and Physics of Solid Surfaces V

Part of the book series: Springer Series in Chemical Physics ((CHEMICAL,volume 35))

Abstract

The spectroscopic techniques of nuclear magnetic resonance (NMR) and electron paramagnetic resonance (EPR or ESR) have been known for more than 30 years. Only in the past 15 years, however, have they been widely applied in the field of surface science. In principle EPR spectroscopy is limited to observation of surface species containing unpaired electrons. These may include adsorbed radicals, molecules containing unpaired electrons (e.g., NO), transitional metal ions and surface defects of various types. Furthermore, EPR is a highly sensitive technique, able to detect (in favourable cases) as few as 1011 spins. NMR spectroscopy, on the other hand, is much broader in scope, since there are many different nuclei possessing non-zero nuclear spins. As a surface technique however, NMR suffers the disadvantage of having a relatively low sensitivity. Both EPR and NMR provide information about the structure and environment of the species being observed, in a completely nondestructive manner.

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Authors
  1. R. F. Howe
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Editors and Affiliations

  1. Department of Chemistry and Laboratory for Surface Studies, The University of Wisconsin-Milwaukee, 53201, Milwaukee, WI, USA

    Ralf Vanselow

  2. Department of Chemistry, University of Auckland, Private Bag, Auckland, New Zealand

    Russell Howe

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© 1984 Springer-Verlag Berlin Heidelberg

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Howe, R.F. (1984). Magnetic Resonance in Surface Science. In: Vanselow, R., Howe, R. (eds) Chemistry and Physics of Solid Surfaces V. Springer Series in Chemical Physics, vol 35. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-82253-7_3

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  • DOI: https://doi.org/10.1007/978-3-642-82253-7_3

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-82255-1

  • Online ISBN: 978-3-642-82253-7

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